RESUMO
In this study, concentrations of 9 heavy metals (Cr, Fe, Co, Ni, Cu, Zn, As, Cd, and Pb) in water and sediments of the Kaptai Lake were determined by neutron activation analysis and atomic absorption spectrometry techniques to study their distribution and contamination in the lake. Average concentrations of Cr and Co in sediments, and Fe and Pb in water were higher than those of some international guideline values. Different environmental pollution indexes (individual and synergistic) suggested that the sediments of Kaptai Lake are minorly enriched by As and Zn, and have low severity of contamination at most of the sampling sites. For residential receptors exposed to the heavy metals in lake water, both non-carcinogenic and carcinogenic hazards were assessed which indicated that there is no carcinogenic risk for As while Cr shows a slightly carcinogenic risk. Moreover, estimated potential ecological risks and different SQGs suggested low ecotoxicological risks in the sediments of Kaptai Lake. Multivariate statistical analyses revealed the correlation among the studied heavy metals and indicated that the origin of most of the metals is mainly lithogenic and a small number of metals (Cu and Pb) from anthropogenic sources. The results of this study will be helpful in developing a pollution control strategy for the lake.
Assuntos
Sedimentos Geológicos , Lagos , Metais Pesados , Poluentes Químicos da Água , Metais Pesados/análise , Medição de Risco , Sedimentos Geológicos/análise , Poluentes Químicos da Água/análise , Bangladesh , Humanos , Monitoramento Ambiental/métodos , Espectrofotometria AtômicaRESUMO
This study reports the mass fractions of Al, Cr, Mn, Fe, Co, Zn, As, Ni, Cu, Cd, Hg, and Pb in water and sediments of the Halda river, Bangladesh, and studies the distribution, contamination, and potential ecological risks of the metals and metalloid. The average mass fractions of As, Cd, and Pb are relatively higher in sediments compared to those in background values, whereas Al, Fe, Mn, and Pb concentration fractions in water are higher than the international guideline values. The results of the different contamination indices indicate that Halda river sediments are minorly contaminated by As and Pb and moderately to considerably contaminated by Cd. The ecological risk assessments indicate considerable to high ecological risk due to Cd. Multivariate statistical analysis reveals the origin of the contaminants in the river, and indicate that Cr, Zn, Pb, and Cd are from anthropogenic activities while the other metals originate from natural lithogenic actions.