Oyster shell for drinking water filtration compared with granular activated carbon: advantages and limitations.

Deliberate media selection can be conducted to achieve targeted objective in filters. In this study, three biofilters (BFs) packed with calcinated oyster shell (COS), granular activated carbon (GAC), and COS + GAC (Mix) were set up in parallel following a rough filter packed with natural oyster shell to compare the performance for treating micro-polluted source water. Different media showed selective removal effects for different pollutants. GAC outperformed COS in terms of TOC and UV254. COS achieved higher reduction in turbidity than GAC. Due to the removal of total bacteria, the absolute and relative abundance of antibiotic resistance genes (ARGs) both decreased much in rough filter treated water (1.16 × 1014 to 1.40 × 1013 copies L-1 and 81.6 to 36.9%, respectively). The highest diverse and rich bacterial community was found in the biofilms on the COS filler, so microbial leakage gave rise to high bacterial content, leading to the highest absolute abundance of ARGs in COS BF effluent (2.11 × 1013 copies L-1). The highest relative abundance of ARGs (41.2%) was found in GAC BF effluent. SourceTracker and biomarker analysis both suggested that treatment process played a more important role in shaping the bacterial community structure in Mix BF effluent than single media BFs, which contributed to the lowest absolute (8.69 × 1012 copies L-1) and relative abundance (25.2%) of ARGs in Mix BF effluent among the three BFs. Our results suggested that mix COS + GAC can not only give full play to their respective advantages for traditional pollutants, but also achieve highest reduction in ARGs.

Reutilization of waste oyster shell as filler for filter for drinking water pretreatment: Feasibility and implication.

Oyster shell (OS) is a kind of reusable resource that can serve as carbon source, biofilms carrier and basifying agent, suggesting it is an attractive filler option for biofiltration, but studies on its application in drinking water treatment are limited. In this study, one pilot-scale up-flow filter filled with OS media were designed to pretreat surface source water. Filter performance and biological functions were investigated to determine its application scope. The results showed that effluent pH increased and was stable around 7.5 due to the alkalinity provided by OS and its buffering capacity. High and stable removal efficiencies of turbidity (mostly >60%) were achieved. The removal efficiencies of NH4+-N changed in a wide range (mostly <30%). TOC and UV254 removal rate was low (<10%). The biofilms formation period took about 45 days. During this period, this filter mainly removed pollutants through adsorption by OS. High-throughput sequencing results showed that functional taxa did not play a key role after adsorption saturation in early operation period. Functional microbial taxa formed on the OS surface after long-term operation and NH4+-N removal rate increased to some extent. Our results suggested that unburned OS filter can be used as rough filter for turbidity removal instead of coagulation and sedimentation process. Preoxidation, calcination of OS, mixed with other filler and are recommended to improve the performance if it would be used for biofiltration. This study provides an insight for the reuse of OS in drinking water treatment.