Pre-selection of monitoring stations for marine water quality using affinity propagation: A case study of Xincun Lagoon, hainan, China.

The development, protection, and restoration of bays require works in scientific research and applications, and the success of which depends on a well deployment of monitoring stations for marine water quality. However, for bays without historical data, it is difficult to carry out related research on deployment of the monitoring stations, resulting in very few research works. This paper has introduced the affinity propagation (AP) clustering algorithm and achieved good results by correcting the preferences. The results show that under the given preference, that is, when the value of M is -6800, the number of monitoring stations in the Xincun lagoon area is 24. Simultaneous the sensitivity analysis of preferences shows that the number of exemplars decreases with lower preferences, that is, when M decreased from -4000 to -12000, the number also decreased from 70 to 36. However, some exemplars remain unchanged or being changed to adjacent positioning. This shows the stability of computation results and the rationality of AP. The research results can be well applied to other bays, even open waters.

Direct extraction and detection of malachite green from marine sediments by magnetic nano-sized imprinted polymer coupled with spectrophotometric analysis.

This research describes the application of magnetic molecularly imprinted nano-sized polymers (MMIPs) for the selective extraction and fast detection of malachite green (MG) from marine sediment samples followed by UV-Vis spectrophotometry. The novel material was prepared by surface imprinting using methacrylic acid as the functional monomer for fixing the template molecules. The polymers obtained at each step were thoroughly studied by transmission electron microscopy, FTIR spectroscopy and thermogravimetric analysis. Simultaneously, the adsorption performances of the resulting nanoparticles were analysed in detail and an excellent affinity with the MG was revealed. Further, the main parameters of magnetic molecular imprinted solid-phase extraction (MMIP-SPE) were screened via multivariate optimization methods. The magnetic nanoparticles were used as special adsorbents to directly extract MG from crude marine sediment extracts. The developed method exhibits satisfactory recoveries from the spiked samples, ranging from 80.40 to 92.96% with an RSD of less than 5.18% (n = 3).