RESUMO
Tin selenide (SnSe) has attracted much attention in the field of thermoelectrics since the discovery of the record figure of merit (zT) of 2.6 ± 0.3. While there have been many publications on p-type SnSe, to manufacture efficient SnSe thermoelectric generators, ann-type is also required. Publications on n-type SnSe, however, are limited. This paper reports a pseudo-3D-printing technique to fabricate bulk n-type SnSe elements, by utilizing Bi as a dopant. Various Bi doping levels are investigated and characterized over a wide range of temperatures and through multiple thermal cycles. Stable n-type SnSe elements are then combined with printed p-type SnSe elements to fabricate a fully printed alternating n- and p-type thermoelectric generator, which is shown to produce 145 µW at 774 K.
RESUMO
There has been much interest in tin selenide (SnSe) in the thermoelectric community since the discovery of the record zT in the material in 2014. Manufacturing techniques used to produce SnSe are largely energy-intensive (e.g., spark plasma sintering); however, recently, in previous work, SnSe has been shown to be produced via a low embodied energy printing technique, resulting in 3D samples with high zT values (up to 1.7). Due to the additive manufacturing technique, the manufacturing time required was substantial. In this work, 3D samples were printed using the inorganic binder sodium metasilicate and reusable molds. This facilitated a single-step printing process that substantially reduced the manufacturing time. The printed samples were thermally stable through multiple thermal cycles, and a peak zT of 0.751 at 823 K was observed with the optimum binder concentration. A proof-of-concept thermoelectric generator produced the highest power output of any reported printed Se-based TEG to date.
RESUMO
The looming impact of climate change and the diminishing supply of fossil fuels both highlight the need for a transition to more sustainable energy sources. While solar and wind can produce much of the energy needed, to meet all our energy demands there is a need for a diverse sustainable energy generation mix. Thermoelectrics can play a vital role in this, by harvesting otherwise wasted heat energy and converting it into useful electrical energy. While efficient thermoelectric materials have been known since the 1950s, thermoelectrics have not been utilized beyond a few niche applications. This can in part be attributed to the high cost of manufacturing and the geometrical restraints of current commercial manufacturing techniques. Printing offers a potential route to manufacture thermoelectric materials at a lower price point and allows for the fabrication of generators that are custom built to meet the waste heat source requirements. This review details the significant progress that has been made in recent years in printing of thermoelectric materials in all thermoelectric material groups and printing methods, and highlights very recent publications that show printing can now offer comparable performance to commercially manufactured thermoelectric materials.
