1.
Org Biomol Chem
; 21(4): 754-760, 2023 Jan 25.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36598776
RESUMO
A Cu/hydrazone catalyst has been applied in the coupling reactions of anilines for the synthesis of diarylamines and azobenzenes. The copper complex that is formed in situ plays a double duty by harnessing photon energy as a photocatalyst and then by catalysing organometallic elementary steps as a transition metal catalyst. By the selection of hydrazones and bases, the reaction selectivity of aniline can be tuned between homo-coupling and its cross-coupling with arylboronic acid, exhibiting the great potential of such hydrazones in organic synthesis.