Spatial and temporal distribution characteristics and geographic contexts of civilized villages in China.

Rural civilization is the soul of rural revitalization strategies. As a booster of rural civilization, the civilized village is an indispensable force to promote the modernization of rural areas, in the meanwhile, the study of its spatial distribution has important theoretical significance and practical value in deepening the theory of rural geography, promoting the development of rural civilization, and helping rural revitalization. Considering civilized villages as the study topic, the spatial and temporal distribution characteristics and geographic context were discussed using spatial analysis methods. The number of civilized villages in the country has shown a clear upward trend since 2005. The spatial distribution pattern of civilized villages in China shows unbalanced patterns with a higher concentration in the east and south. Civilized villages in China present significant patterns of clustering with an increasing degree of spatial clustering, showing a multi-core spatial distribution pattern. Civilized villages in China demonstrate clear spatiotemporal clustering characteristics. A spatiotemporal hot spot cluster formed in the northwestern region from 2005 to 2011, and a spatiotemporal cold spot cluster formed in the southeastern region from 2005 to 2008. The spatial distribution of civilized villages in China has obvious geographical differentiation laws, and factors such as topography, climate, economy, transportation, and policy significantly affect their spatial distribution.

Confining Co1.11Te2 nanoparticles within mesoporous hollow carbon combination sphere for fast and ultralong sodium storage.

Co1.11Te2 nanoparticles are in-situ uniformly grown within mesoporous hollow carbon combination sphere (MHCCS@Co1.11Te2) using a hard-template and spray drying process, solution impregnation and pyrolysis tellurization. Material characterizations reveal that Co1.11Te2, with a diameter of âˆ¼ 20 nm, is attached to the internal walls of the unit spheres or embedded in the mesopore shells of the unit spheres, presenting a distinctive "ships-in-combination-bottles" nanoencapsulation structure. In sodium-ion half-cells, MHCCS@Co1.11Te2 exhibits excellent cycling stability, achieving reversible capacities of 257 mAh/g at 0.5 A/g after 250 cycles, 235 mAh/g at 1.0 A/g after 300 cycles and 161 mAh/g at 10.0 A/g after 1900 cycles. Electrochemical kinetic analyses and ex-situ characterizations reveal rapid electron/Na+ transport kinetics, prominent surface pseudocapacitive behavior, robust nanocomposite structure, and multi-step conversion reactions of sodium polytellurides. In sodium-ion full-cells, MHCCS@Co1.11Te2 still demonstrates stable cycling performance at 1.0 and 5.0 A/g and excellent rate capability. The superior electrochemical performance is associated with the nanoencapsulation structure based on mesoporous hollow carbon combination spheres, which promotes electron conduction and Na+ transport. The space-confined effect maintains the high electrochemical activity and cycling stability of Co1.11Te2.