Boundary layer versus free tropospheric submicron particle formation: A case study from NASA DC-8 observations in the Asian continental outflow during the KORUS-AQ campaign.

In this study, we contrasted major secondary inorganic species and processes responsible for submicron particle formation (SPF) events in the boundary layer (BL) and free troposphere (FT) over the Korean Peninsula during Korea-United States Air Quality (KORUS-AQ) campaign (May-June, 2016) using aircraft observations. The number concentration of ultrafine particles with diameters between 3 nm and 10 nm (NCN3-10) during the entire KORUS-AQ period reached a peak (7,606 ± 12,003 cm -3) at below 1 km altitude, implying that the particle formation around the Korean Peninsula primarily occurred in the daytime BL. During the BL SPF case (7 May, 2016), the SPF over Seoul metropolitan area was more attributable to oxidation of NO2 rather than SO2-to-sulfate conversion. From the analysis of the relationship between nitrogen oxidation ratio (NOR) and temperature or relative humidity (RH), NOR showed a positive correlation only with temperature. This suggests that homogeneous gas-phase reactions of NO2 with OH or O3 contributed to nitrate formation. From the relationship between NCN3-10 (> 10,000 cm-3) and the NOR (or sulfur oxidation ratio) at Olympic Park in Seoul during the entire KORUS-AQ period, it was regarded that the relative importance of nitrogen oxidation was grown as the NCN3-10 increased. During the FT SPF case (31 May, 2016) over the yellow sea, the SO2-to-sulfate conversion seemed to influence SPF highly. The sulfate/CO ratio had a positive correlation with both the temperature and RH, suggesting that aqueous-phase pathways as well as gas-phase reactions might be attributable to sulfate formation in the FT. In particular, FT SPF event on 31 May was possibly caused by the direct transport of SO2 precursors from the continent above the shallow marine boundary layer under favorable conditions for FT SPF events, such as decreased aerosol surface area and increased solar radiation.

Direct measurements of the convective recycling of the upper troposphere.

We present a statistical representation of the aggregate effects of deep convection on the chemistry and dynamics of the upper troposphere (UT) based on direct aircraft observations of the chemical composition of the UT over the eastern United States and Canada during summer. These measurements provide unique observational constraints on the chemistry occurring downwind of convection and the rate at which air in the UT is recycled. These results provide quantitative measures that can be used to evaluate global climate and chemistry models.

Telemetric system for hydrology and water quality monitoring in watersheds of northern New Mexico, USA.

This study utilized telemetric systems to sample microbes and pathogens in forest, burned forest, rangeland, and urban watersheds to assess surface water quality in northern New Mexico. Four sites included remote mountainous watersheds, prairie rangelands, and a small urban area. The telemetric system was linked to dataloggers with automated event monitoring equipment to monitor discharge, turbidity, electrical conductivity, water temperature, and rainfall during base flow and storm events. Site data stored in dataloggers was uploaded to one of three types of telemetry: 1) radio in rangeland and urban settings; 2) a conventional phone/modem system with a modem positioned at the urban/forest interface; and 3) a satellite system used in a remote mountainous burned forest watershed. The major variables affecting selection of each system were site access, distance, technology, and cost. The systems were compared based on operation and cost. Utilization of telecommunications systems in this varied geographic area facilitated the gathering of hydrologic and water quality data on a timely basis.