Innovative Green Chemistry Approach to Synthesis of Sn2+-Metal Complex and Design of Polymer Composites with Small Optical Band Gaps.

In this work, the green method was used to synthesize Sn2+-metal complex by polyphenols (PPHs) of black tea (BT). The formation of Sn2+-PPHs metal complex was confirmed through UV-Vis and FTIR methods. The FTIR method shows that BT contains NH and OH functional groups, conjugated double bonds, and PPHs which are important to create the Sn2+-metal complexes. The synthesized Sn2+-PPHs metal complex was used successfully to decrease the optical energy band gap of PVA polymer. XRD method showed that the amorphous phase increased with increasing the metal complexes. The FTIR and XRD analysis show the complex formation between Sn2+-PPHs metal complex and PVA polymer. The enhancement in the optical properties of PVA was evidenced via UV-visible spectroscopy method. When Sn2+-PPHs metal complex was loaded to PVA, the refractive index and dielectric constant were improved. In addition, the absorption edge was also decreased to lower photon. The optical energy band gap decreases from 6.4 to 1.8 eV for PVAloaded with 30% (v/v) Sn2+-PPHs metal complex. The variations of dielectric constant versus wavelength of photon are examined to measure localized charge density (N/m*) and high frequency dielectric constant. By increasing Sn2+-PPHs metal complex, the N/m* are improved from 3.65 × 1055 to 13.38 × 1055 m-3 Kg-1. The oscillator dispersion energy (Ed) and average oscillator energy (Eo) are measured. The electronic transition natures in composite films are determined based on the Tauc's method, whereas close examinations of the dielectric loss parameter are also held to measure the energy band gap.

Characteristics of PEO Incorporated with CaTiO3 Nanoparticles: Structural and Optical Properties.

In this research, direct band gap polymer composites with amorphous phase, which are imperative for optoelectronic devices applications were synthesized. The solution cast technique was used to produce polyethylene oxide (PEO)/calcium titanate (CaTiO3) nanocomposite (NC) films. The X-ray diffraction (XRD) confirms the growth of amorphous nature within PEO with CaTiO3 addition. The optical band gaps of pure PEO and PEO/CaTiO3 NC films were calculated using analysis of ultraviolet-visible (UV-Vis) spectra. The change in absorption edge toward lower photon energy is evidence of polymer modification. The dispersion behavior of the refractive index of PEO was manipulated to a higher wavelength upon doping with CaTiO3. Upon adding CaTiO3 to the pure PEO polymer, the dielectric constant and refractive index were considerably modified. The band gap shifts from 4.90 eV to 4.19 eV for the PEO incorporated with an optimum portion of 8 wt. % of CaTiO3. The types of the electronic transition in composite samples were specified, based on the Taucs model and the optical dielectric loss. The alteration of UV/Vis absorption spectra of the NC film was considered a suitable candidate to be applied in nanotechnology-based devices. The spherulites ascribed to the crystalline phase were distinguished through the optical microscopy (OM) study.

Polymer Composites with 0.98 Transparencies and Small Optical Energy Band Gap Using a Promising Green Methodology: Structural and Optical Properties.

In this work, a green approach was implemented to prepare polymer composites using polyvinyl alcohol polymer and the extract of black tea leaves (polyphenols) in a complex form with Co2+ ions. A range of techniques was used to characterize the Co2+ complex and polymer composite, such as Ultraviolet-visible (UV-Visible) spectroscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). The optical parameters of absorption edge, refractive index (n), dielectric properties including real and imaginary parts (εr, and εi) were also investigated. The FRIR and XRD spectra were used to examine the compatibility between the PVA polymer and Co2+-polyphenol complex. The extent of interaction was evidenced from the shifts and change in the intensity of the peaks. The relatively wide amorphous phase in PVA polymer increased upon insertion of the Co2+-polyphenol complex. The amorphous character of the Co2+ complex was emphasized with the appearance of a hump in the XRD pattern. From UV-Visible spectroscopy, the optical properties, such as absorption edge, refractive index (n), (εr), (εi), and bandgap energy (Eg) of parent PVA and composite films were specified. The Eg of PVA was lowered from 5.8 to 1.82 eV upon addition of 45 mL of Co2+-polyphenol complex. The N/m* was calculated from the optical dielectric function. Ultimately, various types of electronic transitions within the polymer composites were specified using Tauc's method. The direct bandgap (DBG) treatment of polymer composites with a developed amorphous phase is fundamental for commercialization in optoelectronic devices.

Characteristics of Poly(vinyl Alcohol) (PVA) Based Composites Integrated with Green Synthesized Al3+-Metal Complex: Structural, Optical, and Localized Density of State Analysis.

The influence of dispersing Al-metal complex on the optical properties of PVA was investigated using UV-visible spectroscopy. Polymer composite films with various Al3+-complex amounts in the PVA matrix were arranged by solution casting technique by means of distilled water as a widespread solvent. The formation of Al3+-metal complex was verified through Ultraviolet-visible (UV-Vis) and Fourier-transform infrared spectroscopy (FTIR) examinations. The addition of Al-complex into the polymer matrix led to the recovery of the optical parameters such as dielectric constant (εr and εi) and refractive index (n). The variations of real and imaginary parts of complex dielectric constant as a function of photon wavelength were studied to calculate localized charge density values (N/m*), high-frequency dielectric constant, relaxation time, optical mobility, optical resistivity, and plasma angular frequency (ωp) of electrons. In proportion with Al3+-complex content, the N/m* values were amplified from 3.68 × 1055 kg-1 m-3 to 109 × 1055 kg-1 m-3. The study of optical parameters may find applications within optical instrument manufacturing. The optical band gap was determined from Tauc's equation, and the type of electronic transition was specified. A remarkable drop in the optical band gap was observed. The dispersion of static refractive index (no) of the prepared composites was analyzed using the theoretical Wemple-DiDomenico single oscillator model. The average oscillator energy (Eo) and oscillator dispersion energy (Ed) parameters were estimated.

Steps Toward the Band Gap Identification in Polystyrene Based Solid Polymer Nanocomposites Integrated with Tin Titanate Nanoparticles.

In the current study, the film fabrication of polystyrene (PS) based polymer nanocomposites (NCs) with tuned refractive index and absorption edge was carried out using the solution cast method. X-ray diffraction (XRD) and ultraviolet-visible (UV-Vis) light characterization techniques were performed. The structural and optical properties of the prepared films were specified. The hump of PS decreased significantly when SnTiO3 nanoparticles (NPs) were introduced. Sharp and high intense peaks of SnTiO3 NPs at a high filler ratio were observed. The crystalline size was determined for SnTiO3 NPs from the sharp crystalline peaks using Debye-Scherrer's equation and was found to be 25.179 nm, which is close enough to that described by the supplier. Several optical parameters, such as absorption coefficient (α), refractive index (n), and optical dielectric properties, were investigated. The absorption spectra were tuned with increasing SnTiO3NPs. Upon the addition of the NPs to the PS host polymer, the absorption edge undergoes shifting to lesser photon energy sides. The optical dielectric constant (ε') was correlated to the refractive index. The study of the optical band gap was conducted in detail using both Tauc's model and the optical dielectric loss (ε″) parameter. The results showed that the ε″ parameter is noteworthy to be measured in the optical band gap study of materials.

A Comprehensive Review on Optical Properties of Polymer Electrolytes and Composites.

Polymer electrolytes and composites have prevailed in the high performance and mobile marketplace during recent years. Polymer-based solid electrolytes possess the benefits of low flammability, excellent flexibility, good thermal stability, as well as higher safety. Several researchers have paid attention to the optical properties of polymer electrolytes and their composites. In the present review paper, first, the characteristics, fundamentals, advantages and principles of various types of polymer electrolytes were discussed. Afterward, the characteristics and performance of various polymer hosts on the basis of specific essential and newly published works were described. New developments in various approaches to investigate the optical properties of polymer electrolytes were emphasized. The last part of the review devoted to the optical band gap study using two methods: Tauc's model and optical dielectric loss parameter. Based on recently published literature sufficient quantum mechanical backgrounds were provided to support the applicability of the optical dielectric loss parameter for the band gap study. In this review paper, it was demonstrated that both Tauc's model and optical dielectric loss should be studied to specify the type of electron transition and estimate the optical band gap accurately. Other parameters such as absorption coefficient, refractive index and optical dielectric constant were also explored.

From Insulating PMMA Polymer to Conjugated Double Bond Behavior: Green Chemistry as a Novel Approach to Fabricate Small Band Gap Polymers.

Dye-doped polymer films of Poly(methyl methacrylate) PMMA have been prepared with the use of the conventional solution cast technique. Natural dye has been extracted from environmentally friendly material of green tea (GT) leaves. Obvious Fourier transform infrared (FTIR) spectra for the GT extract were observed, showing absorption bands at 3401 cm-1, 1628 cm-1, and 1029 cm-1, corresponding to O⁻H/N⁻H, C=O, and C⁻O groups, respectively. The shift and decrease in the intensity of the FTIR bands in the doped PMMA sample have been investigated to confirm the complex formation between the GT dye and PMMA polymer. Different types of electronic transition could be seen in the absorption spectra of the dye-doped samples. For the PMMA sample incorporated with 28 mL of GT dye, distinguishable intense peak around 670 nm appeared, which opens new frontiers in the green chemistry field that are particularly suitable for laser technology and optoelectronic applications. The main result of this study showed that the doping of the PMMA polymer with green tea dye exhibited a strong absorption peak around 670 nm in the visible range. The absorption edge was found to be shifted towards the lower photon energy for the doped samples. Optical dielectric loss and Tauc's model were used to estimate the optical band gaps of the samples and to specify the transition types between the valence band (VB) and conduction band (CB), respectively. A small band gap of around 2.6 eV for the dye-doped PMMA films was observed. From the scientific and engineering viewpoints, this topic has been found to be very important and relevant. The amorphous nature of the doped samples was found and ascribed to the increase of Urbach energy. The Urbach energy has been correlated to the analysis of X-ray diffraction (XRD) to display the structure-properties relationships.