Biomimetic Approaches to "Transparent" Photovoltaics: Current and Future Applications.

There has been a surge in the interest for (semi)transparent photovoltaics (sTPVs) in recent years, since the more traditional, opaque, devices are not ideally suited for a variety of innovative applications spanning from smart and self-powered windows for buildings to those for vehicle integration. Additional requirements for these photovoltaic applications are a high conversion efficiency (despite the necessary compromise to achieve a degree of transparency) and an aesthetically pleasing design. One potential realm to explore in the attempt to meet such challenges is the biological world, where evolution has led to highly efficient and fascinating light-management structures. In this mini-review, we explore some of the biomimetic approaches that can be used to improve both transparent and semi-transparent photovoltaic cells, such as moth-eye inspired structures for improved performance and stability or tunable, coloured, and semi-transparent devices inspired by beetles' cuticles. Lastly, we briefly discuss possible future developments for bio-inspired and potentially bio-compatible sTPVs.

Assembly of graphene nanoflake-quantum dot hybrids in aqueous solution and their performance in light-harvesting applications.

Graphene nanoflakes and CdSe/ZnS quantum dots were covalently linked in environmentally friendly aqueous solution. Raman spectroscopy and photoluminescence studies, both in solution and on surfaces at the single nanohybrid level, showed evidence of charge transfer between the two nanostructures. The nanohybrids were further incorporated into solar cell devices, demonstrating their potential as light harvesting assemblies.