Ecological and health risk assessment of heavy metals: a case study of residential waste sites in Umuahia, South-East Nigeria.

This study assessed the human health hazards and ecological risks of heavy metals from waste sites in residential vicinity. The heavy metals analyzed were Cr, Pb, Cd, Ni, Cu, and Zn. A total of 40 soil samples were collected from waste sites in two residential estates located in the urban and suburb areas of Umuahia, Abia state. Results revealed a trend in concentrations of the heavy metals for both sites in the following order: Cu > Ni > Zn > Cr > Cd > Pb. The concentrations of heavy metals were higher in rural soils than in urban soil. The contamination factor (CF) indices for Pb, Cr, Cu, Ni, and Zn were less than 1 for both sites, signifying a low contamination scenario. The contamination factor for Cd (6 > CF) for both sites indicated a very high contamination status. The estimated degree of contamination (Cdeg) was less than the lower threshold of 8.0, denoting a low degree of contamination. Cd was the highest contributor to ecological risk with Er index value of 184.2 among measured heavy metals. The overall potential ecological risk index for urban and rural sites are 187.1 and 196.1 respectively, classifying the sites as moderate risk. The overall non-carcinogenic hazard index values (HI) for adults and children in urban and rural soils are 0.00248, 0.0198 and 0.0028, 0.0223 respectively, which are below the acceptable limit (HI < 1), indicating that the exposed residents are unlikely to experience any apparent adverse health hazards. However, children are more susceptible to non-carcinogenic hazards than adults in the study areas.

Nanomaterials application in greenhouse structures, crop processing machinery, packaging materials and agro-biomass conversion.

The discovery of nanomaterials has flagged off crucial research and innovations in science and engineering. Its unique properties and diverse applications present it as the material for the future. The aim of this study is to presents the relative applications of nanomaterial in some aspects of agriculture production. The study discussed nanotechnology applicability in climate control and photosynthesis in the greenhouse farming, hydroponic systems, solar drying, fabrication of crop processing machine components, oxygen scavengers in crop packaging, and micro-organism stimulant in anaerobic digestion for agro biomass conversion. Some highlights from the review revealed that Nanotechnology can be applied to increase water surface area to volume ratio and heat transfer in the air moving into a greenhouse farming. Water cluster can be changed when treated with nanoparticles through ultraviolet absorption spectrum and nuclear magnetic resonance (NMR) spectroscopy resulting in lower micelles to manipulate water delivery in green house farming. Nano-fluids or Nano-composites can be used to recombine the reactive parts of thermal storage materials after broken at elevated temperature to recover the stored heat for drying purpose during the off-sunshine periods in solar drying of crops. Nanomaterials can be a source of electroluminescence light in hydroponic system and act as coatings and surface hardener in crop processing machinery for post-harvest machines. The reviewed work showed that nanotechnologies has good prospect in adding value in agricultural production in the aspects discussed.