1.
Dalton Trans
; 50(32): 11243-11248, 2021 Aug 28.
Artigo
em Inglês
| MEDLINE
| ID: mdl-34341808
RESUMO
[Co(5tpybNOH)2](BPh4)2 (1; 5tpybNOH = 5,5''-bis(N-tert-butyl hydroxylamino)-2,2':6',2''-terpyridine) has a two-dimensional (2D) structure through a hydrogen bond between the NOH sites, as revealed by X-ray crystallography. The crystal solvents were desorbed above 300 K as shown by thermal analyses and powder X-ray crystallography. The removal of the crystal solvents allowed irreversible structural changes and a spin transition of the Co centre from S = 1/2 to 3/2.