Dispersion pattern of 226Ra and 235U using the ERICA Tool in the coastal mining area, Ierissos Gulf, Greece.

Natural radionuclides, present in mining materials, can exhibit elevated values, thus it is of great interest to study their dispersion in mining areas. Radionuclide spatial variations were determined in coastal surface sediments near the mining area of Ierissos Gulf in northern Greece. 226Ra and 235U measured concentrations were compared with the estimations of ERICA Tool, the dispersion patterns were derived and the affected region around the load-out pier area was calculated to be approximately 21 km2.

Radioactivity and metal concentrations in marine sediments associated with mining activities in Ierissos Gulf, North Aegean Sea, Greece.

Marine sediment samples were collected from Ierissos Gulf, N Aegean Sea, close to the coastal mining facilities. Measurements of radionuclide and metal concentrations, mineral composition and grain size distribution were performed. The concentrations of (226)Ra, (235)U and trace metals showed enhanced values in the port of Stratoni compared with those obtained near to Ierissos port. The dose rates received by marine biota were also calculated by the ERICA Assessment Tool and the results indicated no significant radiological risk.

Time lag between the tropopause height and 7Be activity concentrations on surface air.

A strong positive correlation between the seasonal changes of the tropopause height and the concentration of (7)Be in the surface air (R = 0.94, p < 0.0001) was observed at 40°N. Moreover, a strong positive correlation was revealed between the activity concentrations of (7)Be and the temperature T (°C) (R = 0.97, p < 0.001), confirming that the increased rate of vertical transport within the troposphere, especially during warmer months, has as a result the descent to the surface of air masses enriched in (7)Be. The results of the present work suggest that the temperature and the tropopause height are good indicators for transport time of air masses enriched in (7)Be to the surface. Higher values of temperature or tropopause height seem to result to shorter transport times. This is attributed to atmospheric convection which provides an effective mechanism for vertical transport of air masses. Increasing tropospheric temperature has generally as a result that convection penetrates more deeply which in turn leads to an increase in tropopause height. But, the atmospheric procedures do not occur immediately after the fluctuations of correlated factors. Thus, a time lag is expected between the tropopause height and (7)Be activity concentrations on surface air that might be from hours to days or weeks. The result suggests that (7)Be concentrations fully respond within three days after the changes in the tropopause height.

Post-Chernobyl 137Cs in the atmosphere of Thessaloniki: a consequence of the financial crisis in Greece.

The background radiation level of (137)Cs at the urban atmosphere of Thessaloniki has been increased during the recent decade only due to the Fukushima accident fallout. Since then, no other signal of (137)Cs was observed until the winter period of 2013, when slightly elevated (137)Cs concentrations were measured. The (137)Cs signals observed were up to 12 µBq m(-3), mainly during holidays and weekends followed by lower or even non-detectable activities in the next working days. Those episodes are attributed to the increase of biomass products combustion for residential heating as this year the tax of oil for heating was drastically raised as a consequence of the financial crisis. A preliminary survey of various wood products as well as of bottom ashes from different domestic burning devices is presented. (137)Cs concentrations up to 11 Bq kg(-1) were measured in wood products and up to 500 Bq kg(-1) in ash samples.

Environmental measurements and inspections on imported foods and feedstuffs in Greece after the Fukushima accident.

The radionuclides released during the accident at the Fukushima Daichii nuclear power plant following the Tohoku earthquake and tsunami on 11 March 2011 were dispersed in the whole north hemisphere. Traces of (131)I, (134)Cs and (137)Cs reached Greece and were detected in air, grass, sheep milk, ground deposition, rainwater and drainage water. Members of Six Greek laboratories of the national network for environmental radioactivity monitoring have collaborated with the Greek Atomic Energy Commission (GAEC) and carried out measurements during the time period between 11 March 2011 and 10 May 2011 and reported their results to GAEC. These laboratories are sited in three Greek cities, Athens, Thessaloniki and Ioannina, covering a large part of the Greek territory. The concentrations of the radionuclides were studied as a function of time. The first indication for the arrival of the radionuclides in Greece originating from Fukushima accident took place on 24 March 2011. After 28 April 2011', concentrations of all the radionuclides were below the minimum detectable activities (<10 µBq m(-3) for (131)I). The range of concentration values in aerosol particles was 10-520 µBq m(-3) for (131)I, 10-200 µBq m(-3) for (134)Cs and 10-200 µBq m(-3) for (137)Cs and was 10-2200 µBq m(-3) for (131)I in gaseous phase. The ratios of (131)I/(137)Cs and (134)Cs/(137)Cs concentrations are also presented. For (131)I, the maximum concentration detected in grass was 2.2 Bq kg(-1). In the case of sheep milk, the maximum concentration detected for (131)I was 2 Bq l(-1). Furthermore, more than 200 samples of imported foodstuff have been measured in Greece, following the EC directives on the inspection of food and feeding stuffs.

Structural, microchemistry, and hydrogenation properties of TiMn0.4Fe0.2V0.4, TiMn0.1Fe0.2V0.7 and Ti0.4Zr0.6Mn0.4Fe0.2V0.4 metal hydrides.

In this work, TiFe-based alloys have been developed according to the stoichiometry Ti1-xAx Fe1-yBy (A [triple bond] Zr; B [triple bond] Mn, V). The hydrogen solubility properties have been investigated to develop dynamic hydrides of Ti-based alloys for hydrogen storage applications. The hydrogenation behavior of these alloys has been studied, and their hydrogen storage capacities and kinetics have been evaluated. Several activation modes, including activation at high temperatures under hydrogen pressure, have been attempted for the as-milled powders. In order to clarify the structural/microstructural characteristics, and chemical composition before and after hydrogenation, X-Ray Diffraction (XRD), EDAX-Mapping Analysis and Scanning Electron Microscopy (SEM), have been carried out for the samples. Modeling of the isotherms has been performed by using MATLAB programming. The maximum gravimetric density of 4.3 wt%, has been obtained on the sample with the BCC main phase. The calculated enthalpy of reaction (deltaH) is found to be about 4 kJ/mol.

Tracking of airborne radionuclides from the damaged Fukushima Dai-ichi nuclear reactors by European networks.

Radioactive emissions into the atmosphere from the damaged reactors of the Fukushima Dai-ichi nuclear power plant (NPP) started on March 12th, 2011. Among the various radionuclides released, iodine-131 ((131)I) and cesium isotopes ((137)Cs and (134)Cs) were transported across the Pacific toward the North American continent and reached Europe despite dispersion and washout along the route of the contaminated air masses. In Europe, the first signs of the releases were detected 7 days later while the first peak of activity level was observed between March 28th and March 30th. Time variations over a 20-day period and spatial variations across more than 150 sampling locations in Europe made it possible to characterize the contaminated air masses. After the Chernobyl accident, only a few measurements of the gaseous (131)I fraction were conducted compared to the number of measurements for the particulate fraction. Several studies had already pointed out the importance of the gaseous (131)I and the large underestimation of the total (131)I airborne activity level, and subsequent calculations of inhalation dose, if neglected. The measurements made across Europe following the releases from the Fukushima NPP reactors have provided a significant amount of new data on the ratio of the gaseous (131)I fraction to total (131)I, both on a spatial scale and its temporal variation. It can be pointed out that during the Fukushima event, the (134)Cs to (137)Cs ratio proved to be different from that observed after the Chernobyl accident. The data set provided in this paper is the most comprehensive survey of the main relevant airborne radionuclides from the Fukushima reactors, measured across Europe. A rough estimate of the total (131)I inventory that has passed over Europe during this period was <1% of the released amount. According to the measurements, airborne activity levels remain of no concern for public health in Europe.

Radioiodine and radiocesium in Thessaloniki, Northern Greece due to the Fukushima nuclear accident.

Radioiodine ((131)I) in air and rainwater as high as 497 µBq m(-3) and 0.7 Bq L(-1), respectively, as well as (137)Cs and (134)Cs in air as high as 145 µBq m(-3) and 126 µBq m(-3), respectively were recorded in Thessaloniki, Northern Greece (40°38'N, 22°58'E) from March 24, 2011 through April 09, 2011, after a nuclear accident occurred at Fukushima, Japan (37°45'N, 140°28'E) on March 11, 2011.

The application of phosphogypsum in agriculture and the radiological impact.

Radium-226 in phosphogypsum produced in a phosphate industry, SICNG operating at Thessaloniki, Northern Greece since May 1966, varied from 261 to 688 Bq kg(-1) (mean value 508 Bq kg(-1)). This radionuclide in soil tilled with phosphogypsum used for agricultural purposes varied from 50 to 479 Bq kg(-1) (average 205 Bq kg(-1)), while in the regular soil of cultivated fields it varied from 37 to 54 Bq kg(-1) (average 48 Bq kg(-1)). Radium-226 in rice originated from cultivated fields tilled with phosphogypsum or not varied from 0.36 to 1.98 Bq kg(-1) (average 1.53 Bq kg(-1)) with the higher values observed in samples originated from cultivated fields tilled with phosphogypsum. Radium-226 transfer factors, TF, from soil tilled with phosphogypsum to plants for the case of rice varied from 6.5 x 10(-3) to 2.0 x 10(-2) (geometric mean: 1.1 x 10(-2)). A mean (226)Ra content in rice 1.53 Bq kg(-1) results in a daily intake of (226)Ra by humans in Greece 0.0084 Bq day(-1) leading to an annual effective dose for adults 0.86 microSv y(-1) which is much less in contributing to the average exposure to natural radiation sources (2.4 mSv y(-1)) and particularly to the part due to ingestion (0.29 mSv y(-1)). It is necessary to continuously control (monitoring) (226)Ra in phosphogypsum before any use for agricultural purposes.

Precipitation scavenging of 7Be and 137Cs radionuclides in air.

Atmospheric depositional fluxes of the naturally occurring 7Be of cosmogenic origin and 137Cs from fallout of the Chernobyl accident were measured over a 6-year period (January 1987-December 1992) at Thessaloniki, Greece (40 degrees 38'N, 22 degrees 58'E). Total precipitation accumulation during 1987-1992 varied between 33.7 cm and 65.2 cm, reflecting a relatively dry (precipitation-free) climate. The activity concentrations of 7Be and 137Cs in rainwater depended on the precipitation rate, being higher for low precipitation rates and lesser for high precipitation rates. 137Cs was removed by rain and snow more efficiently than 7Be. Snowfall was more efficient than rainfall in removing the radionuclides from the atmosphere. The annual bulk depositional fluxes of 7Be varied between 477 and 1133 Bq m(-2) y(-1) and this variability was attributed to the amount of precipitation and the variations of the atmospheric concentrations of 7Be. The annual bulk depositional fluxes of 137Cs showed a significant decrease over time from 1987 to 1992, resulting in a removal half-life of 1.33 years. The presence of 137Cs in air, and therefore in rainwater and snow, long after the Chernobyl accident (26 April 1986) was mainly due to the resuspension process. The normalized depositional fluxes of both radionuclides showed maximal values during the spring season where the maximum amount of precipitation occurred. The relatively high positive correlation between 7Be and 137Cs normalized depositional fluxes indicates that the scavenging process of local precipitation controlled the fluxes of both radionuclides. The dry depositional flux of 7Be was less than 9.37% of total (wet and dry) depositional flux. The fraction of dry-to-total depositional flux of 137Cs was much higher than that of 7Be, due to the resuspended soil.

Cesium-137 in grass from Chernobyl fallout.

Grass ecosystem was monitored for 137Cs, a relatively long-lived radionuclide, for about 16 years since the Chernobyl reactor accident occurred on April 26, 1986. Cesium-137 in grass gramineae or poaceae the species, ranged from 122.9 Bq kg(-1) (September 4, 1986) to 5.8 mBq kg(-1) (October 16, 2001) that is a range of five orders of magnitude. It was observed that there was a trend of decreasing 137Cs with time reflecting a removal half-time of 40 months (3 1/3 years), which is the ecological half-life, T(ec) of 137Cs in grassland.

Temporal changes of 7 Be and 210 Pb concentrations in surface air at temperate latitudes 40 degrees N.

Atmospheric concentrations of (7)Be and (210)Pb were measured for 15 years (1987--2001) in ground-level air at Thessaloniki, Northern Greece (40 degrees 38'N, 22 degrees 58'E). Mean activity concentrations of (7)Be and (210)Pb were 5.02 mBqm(-3) and 664 microBqm(-3), respectively, characteristic of the latitude of 40 degrees N. Monthly atmospheric concentrations of (7)Be showed a strong seasonal trend with the highest values being observed in the summer and the lowest in the winter period. Multiple regression analysis of the data of (7)Be concentrations and a number of meteorological parameters revealed that the sunspot number and temperature are the most significant parameters affecting the concentrations of (7)Be in surface air. The observed strong positive correlation between the mean monthly concentrations of (7)Be and the temperature confirms that the increased rate of vertical transport within the troposphere, especially during the warm months, has as a result to carry down to the surface layer air masses enriched in (7)Be. Highest values of the mean monthly atmospheric concentrations of (210)Pb were observed in the autumn and lowest in the spring period. The positive correlation that was observed between (210)Pb and (7)Be concentrations during the summer months suggests that these two radionuclides could be used together as tracers of environmental processes.

Beryllium-7 and solar activity.

A very low concentration of (7)Be in air at Thessaloniki, Northern Greece (40 degrees 38'N, 22 degrees 58'E) was recorded on November 9, 2003 following a strong event of solar wind that occurred on October 29, 2003.

Coloured rain dust from Sahara Desert is still radioactive.

A coloured rain event originating from the Sahara Desert occurred on April 9, 2000 at Thessaloniki, Northern Greece (40 degrees 38'N, 22 degrees 58'E). The radioactive nuclides that were determined in a coloured rain dust sample were 137Cs of Chernobyl origin, 7Be of cosmogenic origin and 40K of terrestrial origin. Cesium-137 still remained 14 years after the Chernobyl accident, reaching 26.6 Bq kg-1 in the coloured rain dust.

Atmospheric deposition of cosmogenic 7Be and 137Cs from fallout of the Chernobyl accident.

Atmospheric (tropospheric) depositional fluxes of the naturally occurring 7Be of cosmogenic origin and 137Cs from fallout of the Chernobyl accident were measured over a 7-year period (January 1987-December 1993) at Thessaloniki, Greece (40 degrees 38' N, 22 degrees 58' E). The annual total deposition fluxes of 7Be varied between 854 Bq/m2 (1987) and 1242 Bq/m2 (1992), showing a minimum in the years 1988-89. The annual total deposition fluxes of 137Cs varied between 183 Bq/m2 (1987) and 16.4 Bq/m2 (1992), showing a significant decrease as expected for natural removal and radioactive decay and no new releases from nuclear facilities or weapons testing. The annual average total deposition velocity for 7Be was from 0.3 cm/s (1988) up to 0.8 cm/s (1991), while for 137Cs the corresponding values were much higher, hence 137Cs was associated with larger atmospheric particles. High 7Be concentrations in air were related to the very little solar activity (1987-88 and 1993-94), while low 7Be concentrations in air related to the high solar activity (1989-91). Maximum 137Cs concentrations in air were registered during the spring 1991 and 1992, reflecting some stratospheric inputs. An unusual highly elevated value of 137Cs concentration in air, reaching 0.25 mBq/m3, was observed during the summer 1990.

Indoor radon concentrations in Greek apartment dwellings.

Radon concentrations indoors were determined in 24 typical occupied apartments in the city of Thessaloniki, North Greece (40 degrees 38'N, 22 degrees 58'E), by means of 12 surveys, each 2 mo long, over a 2-y period starting October 1989. The ratio of the winter and summer averages for the first year of measurements was 1.8 +/- 0.78, and for the second year of measurements was 1.6 +/- 0.61. The indoor radon concentration in the summer (1990) period ranged between 8 and 81 Bq m-3, while in the winter (1989-1990) it ranged between 20 and 143 Bq m-3 for the first year of measurements or between 8 and 92 Bq m-3 in the summer (1991) period and between 12 and 119 Bq m-3 in the winter (1990-1991) for the second year of measurements. These results were obtained by type CN-85 alpha track detectors. Some parameters that influenced the concentrations, such as precipitation rates and use of fly ash in building materials, are discussed.

Seasonal variations of 137Cs content of milk after the Chernobyl accident.

Results are presented on monthly measurements of 137Cs content in cows' milk over a 3-y period after the Chernobyl reactor accident. It was observed that, in an annual cycle of measurements, the 137Cs concentration of milk increased between December and August, peaking in April each year, due to the dependency of the 137Cs content of cattle feed on the fallout activity of 137Cs. There was a consistent correlation between the 137Cs concentration of milk and surface air.

Time-dependent radioactive concentrations of fallout following the Chernobyl reactor accident.

The levels of Chernobyl-derived 137Cs, 134Cs, 106Ru and 103Ru were measured at Thessaloniki, Greece, in air, rain, soil, grass and milk samples for more than 2 years after the accident. The data were analysed in conjunction with 7Be (produced in the atmosphere by cosmic rays) measurements and show that significant variations were observed, particularly in the spring and in the autumn measurements. In interpreting these variations we took into consideration the tropospheric, or possibly stratospheric, fallout injections into the atmosphere due to the Chernobyl accident, nuclear weapons testing or other releases from nuclear reactors operating world-wide. Useful information can be derived for determining the periodicity of global circulation of the fallout radionuclides.