Pulp waste extracted reinforced powder incorporated biodegradable chitosan composite film for enhancing red grape shelf-life.

Chitosan (CS) is widely used as a natural biopolymer due to its semi-crystalline structure, good film-forming properties, and easy availability. CS-based composite films are widely used in industry, particularly in the food sector as active food packaging. Despite all of these advantages, their wide range of applications are constrained by poor mechanical properties. Therefore, this work introduced refined bamboo cellulose powder (RBCP), a reinforcing material that is extracted from waste bamboo pulp and applied to CS composite films to enhance their mechanical and physicochemical properties. The chemical composition and crystallinity properties of CS composite films with RBCP addition were observed by ATR-FTIR and XRD. The homogeneous and heterogeneous surfaces of the RBCP incorporated films before biodegradation and after biodegradation (20 days) were observed by scanning electron microscopy (SEM). The increase in reinforcing RBCP materials from 0.00 to 5.00 % resulted in an increase in tensile strength for CS/RBCP films from 2.9 to 8.3 MPa. The application of the CS/RBCP/5 composite film as red grapefruit storage was also investigated, which performed much better than commercial plastic and control CS films with 92.8 and 88.6 % viability of S. aureus and E. coli bacteria. Overall achieved properties demonstrated strong potential for usage as active packaging materials to preserve and lengthen the shelf life of red grapefruits.

Homo-hetero/core-shell structure design strategy of NaYF4 nanocrystals for superior upconversion luminescence.

A comprehensive strategy has been developed to construct nano-sized homogeneous and heterogeneous core/shell structures of NaYF4 host. Synthesis conditions of cubic phase/α-NaYF4 and hexagonal phase/ß-NaYF4 are discussed. Pure cubic NaYF4:Yb,Er nanocrystals were synthesized with different average sizes extending from 7 nm to 15 nm by varying the reaction time. Temperature and time thresholds of hexagonal nucleation were determined and utilized for controlled core/shell structures of different phases. α-NaYF4:Yb,Er@α-NaYF4, α-NaYF4:Yb,Er@ß-NaYF4, ß-NaYF4:Yb,Er@α-NaYF4, and ß-NaYF4:Yb,Er@ß-NaYF4 core/shell structures were prepared by adopting the required conditions to achieve the desired phase. Excess sodium was used to grow hexagonal shell over metastable cubic core under controlled conditions of reaction time and temperature to prevent the structural transition of the core. Upconversion emission spectra have also been obtained. UCL integrated intensities demonstrated about 5-fold enhancement for α-shell over α-core as compared to the core alone and 22-fold enhancement with ß-shell. On the other hand, α-shell over ß-core exhibited 5-fold enhancement and ß-shell over ß-core exhibited 6-fold enhancement.

Microstructural Origin of the Double Yield Points of the Metallocene Linear Low-Density Polyethylene (mLLDPE) Precursor Film under Uniaxial Tensile Deformation.

The microstructural origin of the double yield points of metallocene linear low-density polyethylene (mLLDPE) precursor films has been studied with the assistance of the synchrotron radiation small- and wide-angle X-ray scattering (SAXS/WAXS). It has been shown that the microstructural origin of the double yield points is highly related to the initial orientation of the original precursor film. For less oriented mLLDPE precursor films, the rearrangement of lamellae and the appearance of the monoclinic phase are the microstructural origins of the first yield point. In comparison, for the highly-oriented mLLDPE precursor film, only the orthorhombic-monoclinic phase transition appears at the first yield point. The melting-recrystallization and the formation of the fibrillary structure happen beyond the second yield point for all studied mLLDPE precursor films. Finally, the detailed microstructural evolution roadmaps of mLLDPE precursor films under uniaxial tensile deformation have been established, which might serve as a guide for processing high-performance polymer films by post-stretching.