Dynamics of runoff quality associated with an urban park and WSUD treatment train in a tropical climate.

A combination of discrete sampling using autosamplers triggered by area-velocity metres and continuous water quality monitoring using YSI datasondes enabled us to evaluate the dynamics of both stormwater runoff and dry weather water quality associated with an urban park and WSUD treatment train in Singapore. The WSUD treatment train consisted of a raingarden and sedimentation ponds. A first flush phenomenon was observed for total suspended solids (TSS) in three of four discrete-sampled events, but there was a less pronounced first flush characteristic for nutrients. Mean TN concentrations associated with runoff from the park (upstream of the WSUD treatment train) were in the range that would be associated with eutrophic conditions, while mean TP levels were in the mesotrophic/eutrophic boundary range. The raingarden reduced nutrient and TSS levels by 7-62% and loads by 65-93%, although nitrate levels were higher in the effluent compared to the influent. The sedimentation ponds successfully reduced sediment levels by 56%, based on continuous turbidity measurements. The dissolved oxygen levels in the sedimentation ponds were lower during drought periods, which has implications for aquatic organisms. The WSUD treatment train generally improved runoff quality from the park and such features can be easily integrated into the park design.

Radiation and energy budget dynamics associated with a floating photovoltaic system.

Shortwave radiation, longwave radiation, photovoltaic (PV) panel, air and near-surface water temperature data were measured for a floating PV system installed in a shallow tropical reservoir. Similar air and water temperature measurements were conducted in open water (ambient condition) for comparison. The data indicate that shortwave radiation is reduced significantly under the PV panels while the longwave radiation increased, and in fact became higher than the shortwave radiation as compared to open water conditions. The air temperature and the water temperature under the PV panels are higher than in open water. A numerical model was developed to predict the PV panel temperature, air and water temperatures beneath the panels and to investigate the heat balance at the reservoir surface, beneath the panels. The modelled air and PV panel temperatures were in good agreement with the field data. The modelled surface water temperature also replicated field measurements showing an increase of about 0.5 °C as compared to the open water temperature. Heat budget analysis showed that the thermal dynamics under the PV panels is mainly controlled by the longwave radiation from the PV panels and reduction in latent heat flux. The altered flux conditions beneath the panels result in a higher equilibrium temperature near the water surface, compared to open water conditions.

Odonata larvae as a bioindicator of metal contamination in aquatic environments: application to ecologically important wetlands in Iran.

The objectives of this study were twofold: (i) assess the bioaccumulation characteristics of a suite of metals associated with several different species of Odonata and (ii) examine Odonata species richness as a reflection of ecosystem health in two ecologically important wetlands of southwestern Iran, the Shadegan and Hawr Al Azim wetlands. Levels of arsenic (As), cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), iron (Fe), mercury (Hg), manganese (Mn), lead (Pb), and zinc (Zn) were determined using inductively coupled plasma optical emission spectrometry (ICP-OES) in nine different Odonata larva species. Based on these data, biota-sediment accumulation factors (BSAFs) were calculated and generally, it was found that Cr, Cu, Mn, and Zn were being taken up by the Odonata (BSAFs >1). Because of its prevalence in the wetland and its observed ability to take up metals, it is suggested that Ischnura ramburii is an appropriate indicator of ecosystem health for these wetlands with respect to metal contamination. Odonata species richness across all sites was 49, while for the individual sites, the greatest species richness was 26 and the lowest species richness was 13. The species richness value across all sites is quite healthy, given the arid climate of the region.

Modeling washoff of total suspended solids in the tropics.

Washoff behavior in the tropics is expected to behave differently from temperate areas due to differences in rainfall characteristics. In this study, rainfall, runoff and total suspended solids (TSS) were monitored from 9 catchments distinguished by different types of land use, in Singapore. The catchments ranged in size from 5.7ha to 85.2ha. Over 120 rain events were studied and more than 1000 storm samples were collected and analyzed. Monte Carlo analysis was applied to obtain the best fit values of the washoff model parameters consisting the washoff coefficient c3, washoff exponent c4 and initial mass on surface Bini. The exponent c4 was found to be approximately unity for all the events monitored, in agreement with other studies. The values of c3 and Bini were found to vary between events. Among all the rainfall and runoff characteristics studied, rainfall depth of the current event (d) was found to be the single parameter that significantly influenced the values of c3 and Bini. Contrary to expectations, Bini did not correlate well with antecedent dry period or with rainfall depth of the prior storm event. The results show that the common modeling practice where Bini is assumed to vary with antecedent dry period and previous rainfall depth should be reassessed when applied to catchments in the tropics. ANCOVA analysis showed that land use was not significant, but rather the variation of c3 and Bini with d was found to correlate well with the catchment area.

Assessment of bed sediment metal contamination in the Shadegan and Hawr Al Azim wetlands, Iran.

The Shadegan and Hawr Al Azim wetlands are important natural resources in southwestern Iran, yet relatively little work has been done to assess ecosystem health of the wetlands. Bed sediment from both wetlands was sampled in individual months between October, 2011 and December, 2012 and analyzed for As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Pb, and Zn using inductively coupled plasma optical emission spectrometry (ICP-OES). The metals data were evaluated using a combination of sediment quality guidelines from the Ontario Ministry of Energy and Environment (MOEE, Canada), enrichment factors (EFs), and a geo-accumulation index (Igeo) approach. The sediments exceeded MOEE Lowest Effect Levels (LELs) consistently for Cr and Cu and a small proportion of samples (5%) for Hg. Levels of As, Cd, Fe, Pb, and Zn did not exceed LELs and none of the samples exceeded the Severe Effect Levels (SELs). In addition to the sediment guidelines, both the EF and Igeo calculations suggested levels of Mn and Fe were severely enriched, while the EF indicated Cd was slightly enriched. Metal levels in the Shadegan wetland exhibited both spatial and seasonal trends. Metal levels were greater near input areas from agricultural, urban, and industrial discharges and runoff as compared to the more remote and quiescent central part of the wetland. Except for Fe, the metal levels were greater in the wet season as compared to the dry season, perhaps due to greater stormwater runoff and sediment loads. This study provides baseline data which can be used to support development of appropriate contaminant source management strategies to help ensure conservation of these valuable wetland resources.

Continuous monitoring of conventional parameters to assess receiving water quality in support of combined sewer overflow abatement plans.

As part of its long-term control plan for combined sewer overflow (CSO) abatement, the city of Buffalo, New York, maintained a network of Hydrolab Datasondes (Hydrolab-Hach Company, Loveland, Colorado) to assess receiving water-quality effects by continuously logging dissolved oxygen, pH, temperature, conductivity, and turbidity. Although the effect of individual CSOs could be visualized, turbidity levels entering the Buffalo River from the upper watershed often were greater than from CSO discharges. Turbidity data showed that the Buffalo River was a net-sediment sink. Low dissolved oxygen levels were observed in the summer during dry weather, baseflow, and watershed-wide storms and CSO events. Some CSOs did not produce dissolved oxygen sags in the receiving waters, but others did. This information, together with the sampling done for organic and inorganic contaminants, can aid the decisionmaking process when prioritizing outfalls for abatement work and provides a baseline against which receiving water-quality improvements can be measured.

Flocculation/aggregation of cohesive sediments in the urban continuum: implications for stormwater management.

The urban continuum, as it applies to sediments and associated contaminants, represents the area over/through which sediments are conveyed from a depositional or eroded surface to a treatment system and/or receiving water body. This study has focused on the changing physical characteristics of the sediment, with an emphasis on flocculation/aggregation, as it progresses through the urban continuum. The sediments of the urban continuum are found to change from an unflocculated state on the street, to a flocculated state in the surface runoff to a very large floc form in the sewer system. The high organic content in the sewers contributes to the large floc size. The structure of the flocs and the flow regime of the receiving water will dictate the fate of the sediment following a combined sewer overflow. Probability distributions fitted to the distributions of each sediment type (compartment) confirmed significant differences in the sediment population sizes. Bulk and individual particle settling velocity experiments also revealed substantial differences between compartments. Sewer flocs were found to be of low density, with high porosity, water and organic content and with settling velocities which increase with floc size.

Coping with change: the small experiment as a strategic approach to environmental sustainability.

The patterns of living, planning, and resource utilization as practiced in Western countries for decades are not sustainable; change of some sort is essential. But what changes are appropriate, and, perhaps more important, will people accept them? The small experiment framework provides a strategy for meeting the challenge of change. By encouraging participation, limiting the scale of initial change, and incorporating some aspects of the familiar, many of the difficulties that make change so problematic can be mitigated or even eliminated. An exploration, from a psychological perspective, of the characteristic difficulties surrounding potential change provides the context for a discussion of the components of the small experiment and an analysis of how these elements address these characteristic challenges. A comparison to adaptive management is drawn, and several concrete examples illustrate how the strategy has been used successfully to address a variety of environmental problems.

Distribution of selected PCB congeners in the Babcock Street sewer district: a multimedia approach to identify PCB sources in combined sewer overflows (CSOs) discharging to the Buffalo River, New York.

To evaluate sources of PCBs in combined sewer overflows (CSOs) to the Buffalo River, New York, combined sewage, sanitary flow, atmospheric wet and dry depositions, and street dust samples were collected from the Babcock Street sewer district and analyzed. Total PCB concentrations (sum of the PCB congeners quantitated) in particulate and dissolved phases of sanitary flow were 101-269 ng g-1 dry weight and <0.2 ng L-1, respectively. PCBs in the atmospheric dry and wet deposition samples were close to the method detection limit (a few pg/cm2 day-1 and <0.2 ng L-1, respectively). Average concentrations of total PCBs were noticeable in both dissolved (64 ng/l-1) and particulate (907 ng g-1 dry weight) phases in CSOs. Total PCBs in aggregates of street dust samples were between 53 and 1,700 ng g-1 dry weight, with the highest concentrations at sites nearest an industrial area that was previously remediated for PCB contamination. PCB congeners 153, 138, 101, 118, and 180 contributed >50% of the total PCB load in street dust samples. PCB congener composition in the particulate phase of CSOs reflects the congener pattern of the street dusts. In this context, it can be suggested that the local contaminated street dusts are one of the potential sources of PCBs in CSOs, which is a source of PCBs to the Buffalo River.

A nursing approach to the management of type IIA hyperlipidemia: case study of a young adult.

This case study illustrates the chronic nature of hyperlipidemia type IIa and the important contribution of the nurse in helping the client adjust life style, manage complex health regimes, and cope with the uncertainty of disease progression and its associated risks.

Temporal variability of the elemental composition in urban street dust.

Urban Street dust is recognized as a source of urban air and runoff degradation. This paper takes a preliminary step toward a better understanding of temporal variability in street dust chemistry and of the controlling mechanisms. Street dust samples, collected over four seasons in the city of Hamilton, Canada, show a variability dependent on element and source-anthropogenic sources exhibiting the greatest temporal variability. In addition, elements attributed to common sources exhibit similar temporal patterns. The use of 'generic' or even one-time samples may seriously misrepresent the elemental make-up of urban street dust. Based on the samples collected in this study, a number of questions/insights are posed to further the study of street dust temporal variability.