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1.
Appl Radiat Isot ; 194: 110666, 2023 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-36701881

RESUMO

Precise radon measurements are a requirement for various applications, ranging from radiation protection over environmental studies to material screening campaigns for rare-event searches. All of them ultimately depend on the availability of calibration sources with a known and stable radon emanation rate. A new approach to produce clean and dry radon sources by implantation of 226Ra ions into stainless steel has been investigated. In a proof of principle study, two stainless steel plates have been implanted in collaboration with the ISOLDE facility located at CERN. We present results from a complete characterization of the sources. Each sample provides a radon emanation rate of about 2 Bq, which has been measured using electrostatic radon monitors as well as miniaturized proportional counters. Additional measurements using HPGe and alpha spectrometry as well as measurements of the radon emanation rate at low temperatures were carried out.

2.
Rev Sci Instrum ; 93(11): 113302, 2022 Nov 01.
Artigo em Inglês | MEDLINE | ID: mdl-36461423

RESUMO

Understanding liquid xenon scintillation and ionization processes is of great interest to improve analysis methods in current and future detectors. In this paper, we investigate the dynamics of the scintillation process for excitation by O(10 keV) electrons from a 83mKr source and O(6 MeV) α-particles from a 222Rn source, both mixed with the xenon target. The single photon sampling method is used to record photon arrival times in order to obtain the corresponding time distributions for different applied electric fields between about 0.8 V cm-1 to 1.2 kV cm-1. Energy and field dependencies of the signals, which are observed in the results, are discussed.

3.
Chem Commun (Camb) ; 58(83): 11661-11664, 2022 Oct 18.
Artigo em Inglês | MEDLINE | ID: mdl-36169286

RESUMO

Dissolution dynamic nuclear polarization (dDNP) is a versatile hyperpolarization technique to boost signal intensities in nuclear magnetic resonance (NMR) spectroscopy. The possibility to dissolve biomolecules in a hyperpolarized aqueous buffer under mild conditions has recently widened the scope of NMR by dDNP. The water-to-target hyperpolarization transfer mechanisms remain yet unclear, not least due to an often-encountered dilemma of dDNP experiments: The strongly enhanced signal intensities are accompanied by limited structural information as data acquisition is restricted to short time series of only one-dimensional spectra or a single correlation spectrum. Tackling this challenge, we combine dDNP with molecular dynamics (MD) simulations and predictions of cross-relaxation rates to unravel the spin dynamics of magnetization flow in hyperpolarized solutions.


Assuntos
Imageamento por Ressonância Magnética , Água , 2-Naftilamina/análogos & derivados , Acrilonitrila/análogos & derivados , Imageamento por Ressonância Magnética/métodos , Espectroscopia de Ressonância Magnética/métodos , Simulação de Dinâmica Molecular , Água/química
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