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1.
Environ Res ; 222: 115332, 2023 04 01.
Artigo em Inglês | MEDLINE | ID: mdl-36709874

RESUMO

The oil contamination in aquatic system is considered as most serious environmental issues and identifying a suitable ecofriendly solution for this oil pollution management is critical. Hence, this research was designed to evaluate the oils (petrol, diesel, engine oil, and crude oil) adsorptive features through raw lemon grass adsorbent, physically/chemically treated adsorbents. Initially, such raw and treated adsorbents were characterized by Scanning Electron Microscope (SEM), Fourier transform infrared spectroscopy (FTIR), and Energy-Dispersive X-ray Spectroscopy (EDS) analysis. These characterization techniques revealed that the lemon grass adsorbent had considerable level of pollutant adsorption potentials owing to porous morphological structure, active functional groups and pollutants interaction with chemical elements. The physically treated adsorbent exhibited better adsorption characteristics than others. Accordingly, the petrol adsorption potential of raw adsorbent, physically treated and chemically treated ones was discovered as their weight incremented up to 2.0, 3.0, and 1.5 times their initial weight, respectively. Similarly, the weight of raw form, physically and chemically treated ones on diesel had increased significantly, up to 2.5 times, 4.0 times, and 2.0 times, respectively. It was evaluated that the weight of these tested adsorbents on engine oil incremented by 3.5, 5.0, and 3.0 times their initial weight, while on crude oil these incremented by 4.0, 6.0, and 4.0 times their initial weight respectively. When the media are compared, it's indeed evident about absorption which is preferred as follows: Crude oil, engine oil, diesel, and petrol. The physically treated lemon grass adsorbent showed maximum adsorption and retention potential than others. The kinetic study reveals that the pseudo second order kinetics is the best fit for the adsorption of oil with R2 value of 0.99.


Assuntos
Cymbopogon , Petróleo , Poluentes Químicos da Água , Adsorção , Gasolina , Óleos , Cinética , Poluentes Químicos da Água/química , Espectroscopia de Infravermelho com Transformada de Fourier , Concentração de Íons de Hidrogênio
2.
Environ Sci Pollut Res Int ; 30(11): 28889-28902, 2023 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-36401699

RESUMO

Technology advancement, industrialisation, and globalisation have been significant reasons for air pollution outdoors and indoors. It may surprise us that we spend about 80% of our time indoors breathing toxic, stale, polluted air, making us sluggish and fretful. In contrast to outdoor air, indoor air does not recycle consistently. It traps and builds pollutants from wood and coal stoves, furniture and building materials, paints and solvents, cigarette smoke, and cleaning supplies. The prolonged exposure to these hidden pollutants can prompt respiratory disorders such as lung disease, pneumonitis, asthma, pulmonary hypertension, and chronic obstructive pulmonary disease (COPD). It is enduring and is not curable, which has been a threat to humanity for ages. COPD's major cause is airborne particulate matter and other toxic compounds emitted from indoor and outdoor sources. Outdoor air pollution can be controlled only by acquiring changes in the vast population, wherein for indoor, every individual may create a major impact on improving air purity, thereby promoting health. The proposed design model for monitoring indoor air quality was tested in a normal and stimulating environment where we live. Parameters tested included temperature, humidity, amount of PM2.5, and the concentration of CO, CO2, and NH3. These parameters were monitored for five to 6 h per day for 8 days. Results indicate that the total air quality lies in the moderate range. Further study will be helpful to utilise this module as an effective Indoor air quality (IAQ) monitoring system. HIGHLIGHTS: • A simple, effective, inexpensive integrated gas sensor module (IGSM) has been proposed in this study to monitor the indoor air quality index (IAQI). • Indoor air quality was tested in a normal and stimulating environment for 8 days. • The integrated gas sensor module (IGSM) was composed of sensors in series, and the outputs for the respective parameter were measured easily. • Among the parameters tested, CO and PM2.5 lie in the moderate range, while other pollutants within the normal range reveal that the tested air quality is moderate.


Assuntos
Poluentes Atmosféricos , Poluição do Ar em Ambientes Fechados , Doença Pulmonar Obstrutiva Crônica , Humanos , Poluição do Ar em Ambientes Fechados/análise , Poluentes Atmosféricos/análise , Monitoramento Ambiental/métodos , Material Particulado/análise , Gases
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