Evidence for the Presence of the Fulde-Ferrell-Larkin-Ovchinnikov State in CeCu_{2}Si_{2} Revealed Using

Nuclear magnetic resonance measurements were performed on CeCu_{2}Si_{2} in the presence of a magnetic field close to the upper critical field µ_{0}H_{c2} in order to investigate its superconducting (SC) properties near pair-breaking fields. In lower fields, the Knight shift and nuclear spin-lattice relaxation rate divided by temperature 1/T_{1}T abruptly decreased below the SC transition temperature T_{c}(H), a phenomenon understood within the framework of conventional spin-singlet superconductivity. In contrast, 1/T_{1}T was enhanced just below T_{c}(H) and exhibited a broad maximum when magnetic fields close to µ_{0}H_{c2}(0) were applied parallel or perpendicular to the c axis; although the Knight shift decreased just below T_{c}(H). This enhancement of 1/T_{1}T, which was recently observed in the organic superconductor κ-(BEDT-TTF)_{2}Cu(NCS)_{2}, suggests the presence of high-density Andreev bound states in the inhomogeneous SC region, a hallmark of the Fulde-Ferrell-Larkin-Ovchinnikov phase.

Persistent Detwinning of Iron-Pnictide EuFe_{2}As_{2} Crystals by Small External Magnetic Fields.

Our comprehensive study on EuFe_{2}As_{2} reveals a dramatic reduction of magnetic detwinning fields compared to other AFe_{2}As_{2} (A=Ba, Sr, Ca) iron pnictides by indirect magnetoelastic coupling of the Eu^{2+} ions. We find that only ∼0.1 T are sufficient for persistent detwinning below the local Eu^{2+} ordering; above T_{Eu}=19 K, higher fields are necessary. Even after the field is switched off, a significant imbalance of twin domains remains constant up to the structural and electronic phase transition (190 K). This persistent detwinning provides the unique possibility to study the low temperature electronic in-plane anisotropy of iron pnictides without applying any symmetry-breaking external force.

Coherent excitations and electron-phonon coupling in Ba/EuFe2As2 compounds investigated by femtosecond time- and angle-resolved photoemission spectroscopy.

We employed femtosecond time- and angle-resolved photoelectron spectroscopy to analyze the response of the electronic structure of the 122 Fe-pnictide parent compounds Ba/EuFe(2)As(2) and optimally doped BaFe(1.85)Co(0.15)As(2) near the Γ point to optical excitation by an infrared femtosecond laser pulse. We identify pronounced changes of the electron population within several 100 meV above and below the Fermi level, which we explain as a combination of (i) coherent lattice vibrations, (ii) a hot electron and hole distribution, and (iii) transient modifications of the chemical potential. The responses of the three different materials are very similar. In the coherent response we identify three modes at 5.6, 3.3, and 2.6 THz. While the highest frequency mode is safely assigned to the A(1g) mode, the other two modes require a discussion in comparison to the literature. Employing a transient three temperature model we deduce from the transient evolution of the electron distribution a rather weak, momentum-averaged electron-phonon coupling quantified by values for λ<ω(2)> between 30 and 70 meV(2). The chemical potential is found to present pronounced transient changes reaching a maximum of 15 meV about 0.6 ps after optical excitation and is modulated by the coherent phonons. This change in the chemical potential is particularly strong in a multiband system like the 122 Fe-pnictide compounds investigated here due to the pronounced variation of the electron density of states close to the equilibrium chemical potential.

Thermopower as a sensitive probe of electronic nematicity in iron pnictides.

We study the in-plane anisotropy of the thermoelectric power and electrical resistivity on detwinned single crystals of isovalent substituted EuFe(2)(As(1-x)P(x))(2). Compared to the resistivity anisotropy, the thermopower anisotropy is more pronounced and clearly visible already at temperatures much above the structural and magnetic phase transitions. Most remarkably, the thermopower anisotropy changes sign below the structural transition. This is associated with the interplay of two contributions due to anisotropic scattering and orbital polarization, which dominate at high and low temperatures, respectively.

Far-infrared optical conductivity of CeCu2Si2.

We investigated the optical reflectivity of the heavy-fermion metal CeCu(2)Si(2) in the energy range 3 meV-30 eV for temperatures between 4 and 300 K. The results for the charge dynamics indicate a behavior that is expected for the formation of a coherent heavy quasiparticle state: upon cooling the spectra of the optical conductivity indicate a narrowing of the coherent response. Below temperatures of 30 K a considerable suppression of conductivity evolves below a peak structure at 13 meV. We assign this gap-like feature to strong electron correlations due to the 4f-conduction electron hybridization.

EuFe2(As(1-x)P(x))2: reentrant spin glass and superconductivity.

By systematic investigations of the magnetic, transport, and thermodynamic properties of single crystals of EuFe(2)(As(1-x)P(x))(2) (0≤x≤1), we explore the complex interplay of superconductivity and Eu(2+) magnetism. Below 30 K, two magnetic transitions are observed for all P substituted crystals, suggesting a revision of the phase diagram. In addition to the canted A-type antiferromagnetic order of Eu(2+) at ∼20 K, a spin glass transition is discovered at lower temperatures. Most remarkably, the reentrant spin glass state of EuFe(2)(As(1-x)P(x))(2) coexists with superconductivity around x≈0.2.

Ultrafast momentum-dependent response of electrons in antiferromagnetic EuFe2As2 driven by optical excitation.

Employing the momentum sensitivity of time- and angle-resolved photoemission spectroscopy we demonstrate the analysis of ultrafast single- and many-particle dynamics in antiferromagnetic EuFe(2)As(2). Their separation is based on a temperature-dependent difference of photoexcited hole and electron relaxation times probing the single-particle band and the spin density wave gap, respectively. Reformation of the magnetic order occurs at 800 fs, which is 4 times slower compared to electron-phonon equilibration due to a smaller spin-dependent relaxation phase space.

Magnetism and superconductivity in Eu0.2Sr0.8(Fe0.86Co0.14)2As2 probed by 75As NMR.

We report bulk superconductivity (SC) in Eu(0.2)Sr(0.8)(Fe(0.86)Co(0.14))(2)As(2) single crystals by means of electrical resistivity, magnetic susceptibility and specific heat measurements with T(c) is approximately equal to 20 K and an antiferromagnetic (AFM) ordering of Eu(2+) moments at T(N) is approximately equal to 2.0 K in zero field. (75)As NMR experiments have been performed in the two external field directions (H is parallel to ab) and (H is parallel to c). (75)As-NMR spectra are analysed in terms of first-order quadrupolar interaction. Spin-lattice relaxation rates (1/T(1)) follow a T(3) law in the temperature range 4.2-15 K. There is no signature of a Hebel-Slichter coherence peak just below the SC transition, indicating a non-s-wave or s(±) type of superconductivity. In the temperature range 160-18 K 1/T(1)T follows the C/(T+θ) law reflecting 2D AFM spin fluctuations.

Pressure tuning of the interplay of magnetism and superconductivity in CeCu2Si2.

We carried out specific-heat and ac-susceptibility experiments under hydrostatic pressure to investigate the interplay of spin-density-wave antiferromagnetism (A) and superconductivity (S) in single-crystalline AS-type CeCu(2)Si(2). We find evidence for a line of magnetic-field- and pressure-tuned quantum critical points in the normal state in the zero-temperature magnetic field-pressure plane. Our analysis suggests an extension of this line into the superconducting state and corroborates the close connection of the underlying mechanisms leading to the formation of the antiferromagnetic and the superconducting states in AS-type CeCu(2)Si(2).

Determination of gap symmetry from angle-dependent H(c2) measurements on CeCu2Si2.

The tetragonal heavy-fermion compound CeCu2Si2 exhibits a superconducting ground state (S type, T(c) = 0.67 K) close to a magnetic instability. Here, we present angle-resolved resistivity measurements of the upper critical field H(c2). In-plane rotation of S-type CeCu2Si2 single crystals reveals a fourfold oscillation of H(c2). An extended weak-coupling BCS model for a d-wave symmetry including strong Pauli-limiting effects confirms the aforementioned angular dependence and points towards d(xy) symmetry of the order parameter.

Suppression of quadrupolar order on Si doping in YbRu(2)(Ge(1 - x)Si(x))(2).

We have investigated the magnetic properties of polycrystalline Y bRu(2)(Ge(1 - x)Si(x))(2) samples using magnetic susceptibility, electrical resistivity, and specific heat measurements. All the results indicate that the Yb ions in Y bRu(2)(Ge(1 - x)Si(x))(2) are in a stable trivalent state. The antiferromagnetic ordering shifts to lower temperature with increasing Si concentration (x). The weak Kondo-like resistivity minimum observed in the resistivity data for x = 0 shifts toward lower temperature with an increase in the Si content and finally disappears. The most dramatic observation is the complete suppression of the quadrupolar ordering in Y bRu(2)Ge(2) (T(Q) = 10 K) even for 2% Si doping.

YbNiB(4): a Kondo lattice with low-dimensional antiferromagnetic fluctuations.

We have grown single crystals of YbNiB(4) using a Ni(60)B(40) flux and determined the magnetic properties of this compound by means of magnetic susceptibility, specific heat and electrical resistivity measurement. Yb ions in YbNiB(4) are in a trivalent state and present a transition from a paramagnetic state to an antiferromagnetic (AF) state at T(N1) = 5.4 K and a further transition towards a second AF state at T(N2) = 4.0 K. Kondo type behavior in the resistivity and an enhanced Sommerfeld coefficient γ = 100 mJ mol(-1) K(-2) provide evidence for a significant Kondo interaction. A broad maximum in χ(T) at around 8 K, well above T(N1), suggests low-dimensional antiferromagnetic correlations. Both mechanisms lead to strong fluctuation in an extended temperature range above T(N1), up to the characteristic energy of this system, which was estimated to be T(4f) = 16 K from an analysis of the entropy.

Superconductivity and magnetism in K-doped EuFe(2)As(2).

Superconductivity is found in 50% K-doped EuFe(2)As(2) samples below 33 K. Our results from electrical resistivity, magnetic susceptibility and (57)Fe and (151)Eu Mössbauer spectroscopy provide clear evidence that the ordering of the Fe moments observed at 190 K in undoped EuFe(2)As(2) is completely suppressed in our 50% K-doped sample; thus there is no coexistence of the Fe magnetic order and the superconducting state. However, short range ordering of the Eu moments coexists with the superconducting state below 15 K. A bump in the susceptibility well below T(c) as well as the broadening of the Fe Mössbauer line below 27 K evidence an interplay between the Eu magnetism and the superconducting state.

Nature of the A phase in CeCu2Si2.

Neutron diffraction experiments have been performed on a magnetically ordered CeCu2Si2 single crystal exhibiting A-phase anomalies in specific heat and thermal expansion. Below T(N) approximately 0.8 K antiferromagnetic superstructure peaks have been detected. The propagation vector of the magnetic order appears to be determined by the topology of the Fermi surface of heavy quasiparticles as indicated by renormalized band-structure calculations. The observation of long-range incommensurate antiferromagnetic order as the nature of the A phase in CeCu2Si2 suggests that a spin-density-wave instability is the origin of the quantum critical point in CeCu2Si2.