1.
Chem Commun (Camb)
; 54(88): 12523-12526, 2018 Nov 14.
Artigo
em Inglês
| MEDLINE
| ID: mdl-30345452
RESUMO
The new phase Co2ScSbO6 and Ni2-xCoxScSbO6 solid solutions adopt the polar Ni3TeO6-type structure and order magnetically below 60 K. A series of long-period lock-in [0 0 1/3n] spin structures with n = 5, 6, 8 and 10 is discovered, coexisting with a ferrimagnetic [0 0 0] phase at high Co-contents. The presence of electrical polarisation and spontaneous magnetisations offers possibilities for multiferroic properties.