Environmental fate of naproxen, carbamazepine and triclosan in wastewater, surface water and wastewater irrigated soil - Results of laboratory scale experiments.

Lab-scale photolysis, biodegradation and transport experiments were carried out for naproxen, carbamazepine and triclosan in soil, wastewater and surface water from a region where untreated wastewater is used for agricultural irrigation. Results showed that both photolysis and biodegradation occurred for the three emerging pollutants in the tested matrices as follows: triclosan>naproxen>carbamazepine. The highest photolysis rate for the three pollutants was obtained in experiments using surface water, while biodegradation rates were higher in wastewater and soil than in surface water. Carbamazepine showed to be recalcitrant to biodegradation both in soil and water; although photolysis occurred at a higher level than biodegradation, this compound was poorly degraded by natural processes. Transport experiments showed that naproxen was the most mobile compound through the first 30cm of the soil profile; conversely, the mobility of carbamazepine and triclosan through the soil was delayed. Biodegradation of target pollutants occurred within soil columns during transport experiments. Triclosan was not detected either in leachates or the soil in columns, suggesting its complete biodegradation. Data of these experiments can be used to develop more reliable fate-on-the-field and environmental risk assessment studies.

Retention of Escherichia coli, Giardia lamblia cysts and Ascaris lumbricoides eggs in agricultural soils irrigated by untreated wastewater.

In central Mexico, agricultural irrigation reusing Mexico City's municipal wastewater has been occurring for the last century, resulting in the recharge of the local aquifer. However, groundwater of this zone is of good quality, indicating that the microorganisms contained in wastewater are retained by soil after infiltration. This study aims to assess the capacity of three agricultural soils to retain three microorganisms frequently found in wastewater, namely Escherichia coli (E. coli), Giardia lamblia (G. lamblia) cysts and Ascaris lumbricoides (A. lumbricoides) eggs, through batch sorption-desorption assays. The tested soils were: an organic-clayey soil (C-OM), a clayey soil (C-om) and a sandy soil (c-om). For the three soils, sorption equilibrium of E. coli was reached before 1 h, while for G. lamblia cysts and A. lumbricoides eggs, sorption equilibrium took 2.5 h. Sorption of E. coli was better described by the Freundlich model than by the Langmuir one. Higher retention of bacteria was observed in the C-om soil (KF = 4340) than in the C-OM and c-om ones (KF = 1821 and 0.01, respectively). Regarding G. lamblia cysts and A. lumbricoides eggs, data could not be fitted to the tested sorption models. For both organisms, retention was lower in the C-OM soil than in the C-om and c-om ones. In the desorption tests, a sudden liberation of E. coli from soils was observed, probably due to bacterial re-growth. Desorption of G. lamblia was higher in the sandy soil than in the clayey ones; desorption was not increased when a surfactant was applied to the soil, suggesting that hydrophobic interactions are not necessarily responsible for retention of the cysts onto the tested soils. For A. lumbricoides eggs, desorption using NaOCl solution suggested that retention was caused by interactions between the mineral fraction of the soil and the external walls of eggs. This study showed that the three target microorganisms are retained by the tested soils and that mineral domain of soil has an important role in such retention.

Adding silver and copper to hydrogen peroxide and peracetic acid in the disinfection of an advanced primary treatment effluent.

This paper evaluates the efficacy of hydrogen peroxide (HP) and peracetic acid (PAA) in the disinfection of an Advanced Primary Treatment (APT) effluent, and how said disinfection capacities can be enhanced by combining the oxidants with copper (Cu2+) and silver (Ag). The treatment sequence consisted of APT (adding chemicals to water to remove suspended solids by coagulation and flocculation), followed by disinfection with various doses of HP, HP+Cu2+, HP+Ag, PAA and PAA+Ag. Microbiological quality was determined by monitoring concentrations of fecal coliforms (FC), pathogenic bacteria (PB) and helminth eggs (HE) throughout the sequence. The results revealed that APT effluent still contains very high levels of bacteria as the treatment only removes 1-2 log of FC and PB, but the reduction in the number of viable helminth eggs was 83%. Subsequent disinfection stages demonstrated that both HP+Cu2+ and HP+Ag have a marked disinfection capacity for bacteria (3.9 and 3.4 log-inactivation, respectively). Peracetic acid on its own was already extremely efficient at disinfecting for bacteria, and the effect was enhanced when combining PAA with silver (PAA+Ag). The best result for HE removal was achieved by combining PAA with silver (PAA+Ag) at doses of 20 + 2.0 mg l(-1), respectively. The study concluded that the PAA+Ag and HP+Ag combinations were good alternatives for APT effluent disinfection, because the disinfected effluents met the standards in NOM-001-SEMARNAT-1996, Mexico's regulation governing the microbiological quality required in treated wastewater destined for unrestricted reuse in agricultural irrigation (< or =1 helminths per litre). Combining either of these disinfection treatments with a primary method such as APT, therefore, offers an effective and practical way of reducing the health risks normally associated with the reuse of wastewaters.

Climbing the ladder: a step by step approach to international guidelines for water recycling.

Given the pressures on the world's freshwater resources, recycled water is a valuable resource. Recycled water can increase the reliability of water supply because it is an independent source of water. Water recycling requires effective measures to protect public health and the environment. In the absence of comprehensive international guidelines, different countries have developed different approaches to managing water recycling depending on the understanding of the health risks, their individual economic circumstances, and affordability. Approaches vary between high technology/high cost/low risk and low technology/low cost/controlled risk. Furthermore, differences occur between countries and within individual countries. Inconsistencies can often be traced to lack of a unified scientific position on health effects. These inconsistencies increase public concerns about health risks and may give rise to conservative controls on responses to water recycling projects that some countries may be unable to afford. In this paper, an international panel of authors discusses how the different water recycling approaches might be linked together into international water recycling guidelines. These guidelines would incorporate a uniform approach to assessing hazards and risks while providing flexibility for individual countries to vary requirements to suit local circumstances of affordability and risk. The authors propose a framework of guidelines in which individual countries can progressively improve recycled water quality as lower risk levels become more affordable. The authors argue that a uniform international approach will result in a number of benefits including a better focus on risk management, better targeted research and development efforts and greater public confidence in water recycling. The authors invite discussion on the concepts put forward in the paper.

The elimination of helminth ova, faecal coliforms, Salmonella and protozoan cysts by various physicochemical processes in wastewater and sludge.

The removal of helminth ova, faecal coliforms, Salmonella and protozoan cysts by the application of physicochemical treatment processes to municipal wastewater and sludge was studied. In the first case, the advanced primary treatment (APT) process was studied, as well as filtration of the APT effluent. The APT sludge was treated with either lime or acid. The initial values of helminth ova, faecal coliforms, Salmonella and protozoan cysts in the wastewater were 23-27 eggs/L, 7.8 x 10(7)-6.5 x 10(8) MPN/100 mL, 4.5 x 10(5)-2.4 x 10(6) MPN/100 mL, and 1,007-1,814 cysts/L respectively. After APT treatment, 96% of the helminth ova, 1 log of faecal coliforms and Salmonella, and 67% of the protozoan cysts were eliminated. To reduce the concentration of helminth ova from values > 1.2 ova/L to < 1 ova/L an additional filtration step was required. In the sludge, the initial values of helminth ova, faecal coliforms and Salmonella were 65-120 ova/g TS, 8.3 x 10(7)-1.4 x 10(11) MPN/g TS and 3.6 x 10(6)-2.4 x 10(10) MPN/g TS respectively. A 97% reduction of the helminth and an 8.5 log reduction of faecal coliforms and Salmonella was achieved by alkaline stabilisation, compared with a 98% and 4.5 log reduction by acid treatment.

Heavy metal removal with Mexican clinoptilolite: multi-component ionic exchange.

This paper describes the interactions of Pb(II), Cd(II), and Cr(VI) competing for ion-exchange sites in naturally occurring clinoptilolite. Dissolved Pb and Cd were effectively removed within 18 h in batch reactors, with higher removal efficiencies (> 95%) in the acidic pH range. The presence of Cr(VI), which can interact with these metals to form anionic complexes, significantly diminished the Pb and Cd removal efficiencies. A decrease in the efficiency of clinoptilolite to remove Pb was also observed in the high (> or = 10) pH range. This was attributed to the formation of anionic hydroxo-complexes with little affinity for cationic ion exchange sites. Pb outcompeted Cd for ion exchange sites in a flow-through column packed with clinoptilolite (contact time = 10 s). The preferential removal of Pb in column, but not in batch reactors, reflects that competitive retention can be affected by contact time because diffusion kinetics may influence the removal efficiency to a greater extent than equilibrium partitioning. Phenol, which was tested as a representative organic co-contaminant, slightly hindered heavy metal removal in batch reactors. This was attributed to the formation of organometallic complexes that cannot penetrate the zeolite exchange channels. Altogether, these results show that natural zeolites hold great potential to remove cationic heavy metal species from industrial wastewater. Nevertheless, process efficiency can be hindered by the presence of ligands that form complexes with reduced accessibility and/or affinity for ion exchange.