Computational Fluid Dynamics Simulations of Aerosol Behavior in a High Speed (Heubach) Rotating Drum Dustiness Tester.

Potential exposure from hazardous dusts may be assessed by evaluating the dustiness of the powders being handled. Dustiness is the tendency of a powder to aerosolize with a given input of energy. We have previously used computational fluid dynamics (CFD) to numerically investigate the flow inside the European Standard (EN15051) Rotating Drum dustiness tester during its operation. The present work extends those CFD studies to the widely used Heubach Rotating Drum. Air flow characteristics are investigated within the Abe-Kondoh-Nagano k-epsilon turbulence model; the aerosol is incorporated via a Euler-Lagrangian multiphase approach. The air flow inside these drums consists of a well-defined axial jet penetrating relatively quiescent air. The spreading of the Heubach jet results in a fraction of the jet recirculating as back-flow along the drum walls; at high rotation rates, the axial jet becomes unstable. This flow behavior qualitatively differs from the stable EN15051 flow pattern. The aerodynamic instability promotes efficient mixing within the Heubach drum, resulting in higher particle capture efficiencies for particle sizes d < 80 µm.

Investigation of thermoluminescence response and trapping parameters of natural barite samples from Dongargaon mine, India.

Dosimetry is a technique that quantitatively measures the ionizing radiation absorbed by matter. The present study was conducted on the barites from a mine at Dongargaon in Central India. Morphological and structural analysis of proposed sample was carried out using X-ray diffraction and standard error of the mean. Thermal analysis and chemical composition of the proposed sample were carried out using thermogravimetric analysis and differential thermal analysis, and electron probe microanalysis. Thermoluminescence (TL) studies on a natural barite sample were performed using a Nucleonix TL1009I TL reader following sample irradiation with γ-rays generated from a 60 Co irradiation source. A broad TL glow curve was observed after TL study that was then deconvoluted using TLanal deconvolution software. Trapping parameters from the sample such as activation energy (E), order of kinetics (b), and frequency factor (s) were calculated using Chen's peak shape method, the initial rise method, and Ilich's method. The results indicated that the natural barite sample could be used in high-dose TL dosimetric applications in various fields.

Preliminary results on the photoluminescence and optically stimulated luminescence in Cu-doped and Ag-doped ZnB2 X4 (B = Li, Na, K: X = Cl, Br) compounds.

Photoluminescence, and optically stimulated luminescence in ZnB2 X4 (B; Li,Na,K: X; Cl,Br) compounds doped with Cu+ or Ag+ were studied. Double humped emission bands attributable to the activators were observed in all the samples. The observed photoluminescence of Cu+ and Ag+ could be identified with 3d9 4s1 ↔3d10 and 4d9 5s1 ↔5d10 transitions respectively. The longer wavelength band (400-500 nm range) could be attributed to the Cu+ or Ag+ ion replacing alkali ion at the octahedral alkali site whereas short wavelength band (340-400 nm range) is attributed to a Cu or Ag ion at tetrahedral zinc site. The short wavelength band was found to be intense compared with long wavelength and gave an indication that most of the Cu or Ag ions prefered a tetrahedral Zn site compared with the octahedral alkali site. All the samples exhibit optically stimulated luminescence (OSL). The sensitivity was found to be lattice dependent. The lowest sensitivity of about 1% compared with Al2 O3 :C was observed in lithium lattices whereas highest the sensitivity of about 290% was observed in the case of Cu-doped ZnNa2 Br4 .

PHOTOLUMINESCENCE, THERMOLUMINESCENCE AND OPTICALLY STIMULATED LUMINESCENCE STUDIES IN ZINC-BASED FLUOROPERVOSKITES.

The optically stimulated luminescence, thermoluminescence and photoluminescence in various Cu and Ag doped zinc based fluoropervoskites are studied. In all the samples, photoluminescence of Cu+ and Ag+ is observed which could be attributed to 3d94 s1←→3d10 and 4d95 s1←→5d10 transitions, respectively. The observed emission is double humped and the main emission band shifts to the lower wavelength side with increasing ionic size of the alkali ion. All the studied fluoropervoskites show reasonable OSL sensitivity. Highest sensitivity is observed for Cu doped ZnNaF3 and is 25% compared to commercial Al2O3:C. Weak thermoluminescence is observed in all samples. In all Ag doped samples the TL peak is observed at 200°C whereas for Cu doped samples peak is observed at 150°C, and correlated with the OSL. The samples show good linear dose response in the 10 mGy-1.2 Gy range and show good reusability characteristics. This study will lead to the development of zinc-based fluoropervoskite phosphors for the radiation dosimetry using OSL.

Surfactant-induced modification of low weber number droplet impact dynamics.

The effect of surfactant molecular mass transport on the normal impact and spreading of a droplet of its aqueous solution on dry horizontal substrates is investigated experimentally for a range of Weber numbers (20-100). The postimpact dynamics of film spreading and its recoil behavior are captured using high-speed real-time digital imaging. Hydrophilic (glass) and hydrophobic (Teflon) substrates were used with water and aqueous solutions of three different surfactants of varying diffusion rates and ionic characteristics: SDS (anionic), CTAB (cationic), and Triton X-100 (nonionic). Their solutions facilitate larger spread and weaker surface oscillations compared to a pure water drop colliding at the same Weber number. On a hydrophobic surface, the drop rebound and column fracture are inhibited by the presence of the surface-active agent. Besides reagent bulk properties, dynamic surface tension, surface wettability, and droplet Weber number govern the transient impact-spreading-recoil phenomena. The role of dynamic surface tension is evident in comparisons of impact dynamics of droplets of different surfactant solutions with identical equilibrium surface tension and same Weber number. It was observed that higher diffusion and interfacial adsorption rate (low molecular weight) surfactants promote higher drop spreading factors and weaker oscillations compared to low diffusion/adsorption rate (high molecular weight) surfactants.

Developing pulsatile flow in a deployed coronary stent.

A major consequence of stent implantation is restenosis that occurs due to neointimal formation. This patho-physiologic process of tissue growth may not be completely eliminated. Recent evidence suggests that there are several factors such as geometry and size of vessel, and stent design that alter hemodynamic parameters, including local wall shear stress distributions, all of which influence the restenosis process. The present three-dimensional analysis of developing pulsatile flow in a deployed coronary stent quantifies hemodynamic parameters and illustrates the changes in local wall shear stress distributions and their impact on restenosis. The present model evaluates the effect of entrance flow, where the stent is placed at the entrance region of a branched coronary artery. Stent geometry showed a complex three-dimensional variation of wall shear stress distributions within the stented region. Higher order of magnitude of wall shear stress of 530 dyn/cm2 is observed on the surface of cross-link intersections at the entrance of the stent. A low positive wall shear stress of 10 dyn/cm2 and a negative wall shear stress of -10 dyn/cm2 are seen at the immediate upstream and downstream regions of strut intersections, respectively. Modified oscillatory shear index is calculated which showed persistent recirculation at the downstream region of each strut intersection. The portions of the vessel where there is low and negative wall shear stress may represent locations of thrombus formation and platelet accumulation. The present results indicate that the immediate downstream regions of strut intersections are areas highly susceptible to restenosis, whereas a high shear stress at the strut intersection may cause platelet activation and free emboli formation.