1.
Spectrochim Acta A Mol Biomol Spectrosc
; 58(7): 1443-51, 2002 May.
Artigo
em Inglês
| MEDLINE
| ID: mdl-12083667
RESUMO
Spectroscopic properties of a new family of acridinedione dyes are reported. The absorption and fluorescence spectra of the different substituted acridinediones have been recorded in different solvents and the difference in the dipole moment between ground and excited state has been obtained by solvatochromic shift method. The value of the Onsager cavity radius was calculated from the total surface area using software PCMODEL. Fluorescence quantum yield and fluorescence lifetime were determined. Radiative and non-radiative constants have been calculated. The triplet-triplet absorption maxima and triplet lifetime show variation depending on the substitution.