1.
Acta Crystallogr E Crystallogr Commun
; 73(Pt 9): 1336-1340, 2017 Sep 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-28932469
RESUMO
In the title mol-ecule, C12H13FN2O3, the central pyrrole ring makes a dihedral angle of 9.2â (3)° with the eth-oxy carbonyl moiety whereas the fluoro-phenyl ring is rotated by 67.6â (2)° from the pyrrole ring. Supra-molecular aggregation is due to off-centric π-π stacking inter-actions involving screw-related pairs of mol-ecules, which are further connected by N-Hâ¯O and C-Hâ¯O inter-actions, forming a sinusoidal pattern along the [001] direction on the bc plane. Three-dimensional Hirshfeld surface analysis and two-dimensional fingerprint plots confirm the contributions of these inter-actions.