Oxidized sulfur-rich arc magmas formed porphyry Cu deposits by 1.88 Ga.

Most known porphyry Cu deposits formed in the Phanerozoic and are exclusively associated with moderately oxidized, sulfur-rich, hydrous arc-related magmas derived from partial melting of the asthenospheric mantle metasomatized by slab-derived fluids. Yet, whether similar metallogenic processes also operated in the Precambrian remains obscure. Here we address the issue by investigating the origin, fO2, and S contents of calc-alkaline plutonic rocks associated with the Haib porphyry Cu deposit in the Paleoproterozoic Richtersveld Magmatic Arc (southern Namibia), an interpreted mature island-arc setting. We show that the ca. 1886-1881 Ma ore-forming magmas, originated from a mantle-dominated source with minor crustal contributions, were relatively oxidized (1‒2 log units above the fayalite-magnetite-quartz redox buffer) and sulfur-rich. These results indicate that moderately oxidized, sulfur-rich arc magma associated with porphyry Cu mineralization already existed in the late Paleoproterozoic, probably as a result of recycling of sulfate-rich seawater or sediments from the subducted oceanic lithosphere at that time.

Chromite chemistry of a massive chromitite seam in the northern limb of the Bushveld Igneous Complex, South Africa: correlation with the UG-2 in the eastern and western limbs and evidence of variable assimilation of footwall rocks.

The Bushveld Igneous Complex (BIC) is known for its laterally extensive platinum group element-bearing layers, the most famous being the Merensky Reef and the UG-2 chromitite in the eastern and western limbs of the complex. In the northern limb, the Platreef mineralization and a thick chromitite seam below it (referred to as the "UG-2 equivalent" or UG-2E) have been proposed to be the stratigraphic equivalents of the Merensky Reef and the UG-2, respectively. In this study, we compare a suite of UG-2E samples from the Turfspruit project with a UG-2 reference suite from the western limb using petrography, electron probe microanalysis, laser ablation-inductively coupled plasma-mass spectrometry, and Mössbauer spectroscopy. The results show that (a) in Mg# vs. Cr# diagrams, UG-2E chromites have a distinct compositional field; however, when samples of similar chromite modal abundance (≥ 80%) are used, the UG-2E chromites overlap the field that characterizes UG-2 chromites; (b) the UG-2E is more variable in chromite modal abundance than the UG-2; and (c) variations in Mg# and Fe3+/ΣFe in the UG-2E indicate contamination of the magma by metasedimentary rocks of the Duitschland Formation (Transvaal Supergroup) during emplacement, followed by partial re-equilibration of chromite grains with a trapped melt. Thus, we conclude that for chromite modes higher than 80%, the chromite composition retains enough information to allow correlation and that the UG-2E in the northern limb is very likely the UG-2 chromitite.

Strontium isotope stratigraphy through the Flatreef PGE-Ni-Cu mineralization at Turfspruit, northern limb of the Bushveld Igneous Complex: evidence of correlation with the Merensky Unit of the eastern and western limbs.

The origin of PGE-Ni-Cu mineralization in the Platreef, northern limb of the Bushveld Igneous Complex (BIC), and the possible correlation with the Merensky Reef in the eastern and western limbs has been long debated. The Platreef and Merensky Reef share the same stratigraphic position in the uppermost part of the Upper Critical Zone (UCZ), near the transition to the overlaying Main Zone (MZ). However, discrepancies in interpretations have been difficult to resolve due to the effects of intense magma-country rock interaction throughout most of the northern limb succession. To address this problem, we generated a detailed stratigraphic profile of the initial strontium isotopic ratio [Sri = (87Sr/86Sr)i] in plagioclase across a Flatreef interval lacking macroscopic evidence of country rock assimilation. The in situ Sr isotopic ratios in plagioclase were determined using LA-MC-ICP-MS analysis on 37 samples from a drill core (UMT094) at the Turfspruit project. Strontium isotope stratigraphy is useful because of a well-documented shift in Sri near the base of the Merensky Unit in the eastern and western limbs. The results show the existence of a significant shift (from Sri = 0.7060 to Sri = 0.7090) that matches the isotopic shift documented through the Merensky Unit in the eastern and western limbs. Thus, this new Sr isotope data indicates that the main mineralized interval of the Flatreef can be stratigraphically correlated to the Merensky Reef in the remainder of the BIC. In addition, we interpret these results as compelling evidence to suggest that the main mineralization processes in the Flatreef were likely similar to those operating in the eastern and western limbs and that interaction with local country rocks was not a necessary condition.