Juçara Fruit (Euterpe Edulis Martius) Valorization Combining Emergent Extraction Technologies and Aqueous Solutions of Alkanediols.

Anthocyanins from juçara fruits were extracted by pressurized liquid extraction (PLE) or ultrasound-assisted extraction (UAE), using aqueous solutions of 1,2-alkanediols and glycerol ethers as biobased solvents. The PLE (100 bar, 13 min, 1 mL/min flow rate) in the optimal extraction conditions originated 23.1 mganthocyanins·gdry biomass-1. On the other hand, the UAE was 10 min long, and the optimal conditions using 1,2-propanediol were 42.6 wt%, 160 W, and pH 7.0, leading to 50 mganthocyanins·gdry biomass-1. Extractions at the UAE optimized conditions, with aqueous solutions of five different 1,2-alkanediols and three glycerol ethers were performed, and compared to water and ethanolic extracts. The biobased solvent solutions presented anthocyanin yields up to 33% higher than water, and were shown to be as efficient as ethanol/water, but generated extracts with higher antioxidant capacity. The anthocyanin-rich extract of juçara, obtained with 1,2-propanediol, was used in the production of a natural soap and incorporated into a cream, showing that the addition of the juçara extract resulted in an antioxidant capacity in both products.

Steel mill waste application in soil: dynamics of potentially toxic elements in rice and health risk perspectives.

Potentially toxic elements (PTEs) are of great concern in steel mill wastes. Therefore, in order to use them as potential fertilizers in soil, risk assessments are needed. Three steel mill wastes were tested as possible amendments for soils at seven different doses (0, 0.5, 1, 2, 4, 8, 16 t ha-1): phosphate mud (PM), metallurgical press residue (MPR), and filter press mud (FPM) during rice cultivation in a pot experiment in a Haplic Gleisol. Analysis on rice tissues, including roots, shoots, husk, and grains, were conducted and contents of Cu, Cd, Ni, Zn, Mn, and Pb were assessed. Translocation and bioaccumulation factors were calculated for each element. In general, PTEs are more accumulated in roots and greater contents of Zn and Mn were found, while the lowest ones were found for Pb, probably due to its lack of functional roles during plants development. Higher translocation was observed for Mn, which is associated to the redox conditions of rice cultivation and the high mobility of this element under this condition. Application of steel mill wastes can increase PTE bioavailability and translocation factors, especially PM, but all of the wastes reveal a high hazard index.

Steel mill waste effects on rice growth: comparison of chemical extractants on lead and zinc availability.

Zinc deficiency is widespread in cultivated soils, limiting the grain crop production and the adequate human nutrition. Several wastes from metallurgical activity can be used as Zn source, but these materials generally also have other potentially toxic elements, such as Pb, that can be highly toxic for plants and humans. This study aimed to evaluate the efficiency of five chemical extractors (water, citric acid, DTPA, Mehlich 1, and USEPA 3051A) in better correlating with the bioavailable contents of Zn and Pb in soils treated with steel mill wastes (metallurgic press residue (MPR), filter press mud (FPM), and phosphate mud (PM)). Rice plants were cultivated in pots with 4 kg of a Haplic Eutrophic Gleisol and steel mill wastes were applied in soil at increasing doses (0, 0.5, 1, 2, 4, 8, and 16 t ha-1). The availability of the potentially toxic elements Zn and Pb was assessed as total contents in rice shoots, grains, husks, and roots. The results showed that the USEPA 3051A method extracted greater contents of Zn and Pb from soil compared with other extractants. Due to their greater natural Pb and Zn contents, MPR and PM promoted higher contents of these elements in soils, respectively. Doses of PM influenced Zn contents in grains. After adding 16 t ha-1 of PM, Zn content in rice grains was 0.1 mg kg-1. However, at doses 0.5, 1, 2, and 4 t ha-1, the average concentration of Zn in the grains was 40 mg kg-1. The wastes MPR and FPM at 16 t ha-1 promoted Zn concentration in grains of 42 and 45 mg kg-1, respectively. The greatest contents of Pb in grains were found after addition of FPM at doses 0.5, 1, and 2 t ha-1: 6.67, 4.96, and 0.45 mg kg-1, respectively, and above 4 t ha-1 (4, 8, and 16 t ha-1); Pb content in grains was less than 0.3 mg kg-1. The content of Pb in roots at 16 t ha-1 of PM, MPR, and FPM was 18, 25, and 155 mg kg-1, respectively, and for Zn, under the same conditions, 100, 255, and 813 mg kg-1 for MPR, FPM, and PM, respectively. USEPA 3051A can be used to assess Pb and Zn available contents, and positive correlations with bioavailable contents of these elements in roots prove its feasibility. Further studies are necessary to state the safety of using steel mill application, including the use of other crop species, but PM is a promising waste for soil Zn fertilization.