Treatment of polluted river water using potential bioflocculant produced by Klebsiella pneumonia UKD24.

Chemically enhanced primary treatment (CEPT) is a rapid wastewater treatment process involving treating wastewater with two chemical-aided processes, coagulation, and flocculation. In the present study, a natural extracellular polymeric substance flocculant (EPSBF) produced by Klebsiella pneumonia UKD24, a bacterium isolated from the sewage treatment plant, and a synthetic polyacrylamide anionic polymer flocculant (PAM) were evaluated to treat polluted river water. The synthetic PAM showed immediate turbidity reduction after agitation, while the EPSBF expressed a rapid decrease in optical density. After 20 min of the settling period, the EPSBF showed reduced rates of turbidity, optical density, and chemical oxygen demand at 74.14 ± 5.2%, 89.37 ± 0.76%, and 87.21 ± 0.73%, respectively, while PAM showed 67.08 ± 4%, 85.68 ± 2%, and 86.57 ± 2%, respectively. EPSBF treatment significantly improved the water quality parameters in terms of total dissolved solids, total suspended solids, conductivity, and oxidation-reduction potential than PAM treatment. However, the EPSBF has shown a more water-holding capacity and relatively weak flock formation, producing more sludge volume than PAM. Furthermore, though the sludge produced by the EPSBF treatment had a higher moisture content, it showed shorter capillary suction time (CST). In contrast, sludge formed in PAM treatment had lower moisture content, but it exhibited prolonged CST value indicating that PAM treatment sludge showed slow dewaterability.

Removal of Malachite Green using carbonized material derived from disposable facemasks: optimization of removal process through Box-Behnken design.

Water resources are being heavily contaminated due to the huge load of toxic pollutants released by industrial activities. Among various physical and chemical methods, adsorption is considered as a promising method for rapidly removing contaminants from wastewater. In the present study, a novel carbon-based adsorbent was prepared through controlled pyrolysis of disposable facemasks. The properties of carbonized compound (CC) were characterized by FTIR, XRD, SEM and EDX. The pollutant removal efficiency of CC was initially investigated with synthetic dyes Malachite Green (MG) and Congo Red (CR). The peaks observed in FTIR spectra corresponding to C=O and C=C and C-N functional groups on adsorbed CC surface confirm the interaction between dye and CC. The XRD spectra of CC showed strong peaks at 2θ = 26.629, 27.488, 27.810 and 29.404 which correspond to the disordered graphitic plane. The SEM images of CC showed good porosity nature. A quadratic model was developed through response surface methodology by conducting a series of Box-Behnken design experiments. Adequacy of this model variables was ensured by ANOVA tests at P-value <0.05. The lower P-value (<0.0001) and higher F-value (44.54) of the quadratic model showed it was a significant model for dye removal. Finally, the optimal condition to obtain maximum MG removal (rate >99%) was identified by desirability function as CC 1000 and MG 212 mg/L and adsorption time 180 min. Adsorption kinetic study indicates that a pseudo second-order kinetic model showed the best fit with R2 = 0.999.