Impact of the Fukushima Accident on 3H and 14C Environmental Levels: A Review of Ten Years of Investigation.

The investigation of the impact of the Fukushima accident is still going on although more than ten years have passed since the disaster. The main goal of this paper was to summarize the results of tritium and radiocarbon determinations in different environmental samples, possibly connected with the Fukushima Dai-ichi Nuclear Power Plant (FDNPP) accident. A document containing compiled data may serve as a solid basis for further research in the selected fields. To accomplish such effort, we went through dozens of relevant published papers, reporting 3H and 14C activity concentrations in precipitations, groundwater, seawater, river systems, tree rings, and, in some more extraordinary samples, such as herbaceous plants or debris from the damaged reactor buildings. As the referenced results would not be obtainable without adequate analytical techniques, the most common methods for routine measurement of tritium and radiocarbon concentrations are discussed as well. We believe that the correct identification of the affected environmental compartments could help quantify the released 3H and 14C activities and track their following fate, which could be especially important for plans to discharge contaminated water from the FDNPP in the upcoming years.

Sequential scavenging and measurement of seawater radiocesium concentrations and plutonium isotopic ratios offshore Fukushima.

The scientific interest in radiocesium and plutonium found in the oceans and seas has increased enormously in the past years as a consequence of the Fukushima Dai-ichi Nuclear Power Plant (FDNPP) accident and is expected to be ongoing due to many unresolved questions. Hence, continuous development of new and verification of old analytical methods should be at the top of the list of the community, working on the topic. In this study, we processed and analyzed several seawater samples, collected in different time frames (2011-2015) from the North Pacific Ocean offshore Fukushima, to determine their radiocesium activities, 134Cs/137Cs activity ratios and 240Pu/239Pu isotopic ratios using the sequential scavenging method, gamma spectrometry and accelerator mass spectrometry (AMS). The observed radiocesium levels in seawater (0.07-0.042 Bq L-1) clearly indicated that the investigated region remained impacted by releases from the damaged power plant even after four years after the accident. Regarding plutonium, its successful separation from large volume seawater samples was confirmed by detection of 240Pu by AMS. However, several problems emerged during the analyzes, which we tried to address with the use of additional methods (e.g., measurements of uranium by ICPMS). The efficiencies of the applied methods and other issues are also discussed.

Distribution of 241Am and Pu isotopes in the Curonian Lagoon and the south-eastern Baltic Sea seawater, suspended particles, sediments and biota.

Distribution trends and temporal variations of 241Am and Pu isotopes in the south-eastern Baltic Sea during the study period of 1999-2001 and 2011-2015 were investigated with the aim to study temporal changes of radionuclide levels in seawater, suspended particles and sediment, to estimate 241Am and 239,240Pu levels in marine biota and to assess the radiation doses received by the biota. The activities of 241Am and 239,240Pu were measured by alpha spectrometry after radiochemical purification. 241Pu was determined radiometrically via the ingrown daughter 241Am after 10-12 years of storage, while the 240Pu/239Pu atom ratio of was measured by accelerator mass spectrometry. The 239,240Pu activities in suspended particles collected in the coastal waters of the Baltic Sea decreased by a factor of ∼3 during the study period, while they decreased about fourfold in the Curonian Lagoon. This could indicate a decrease in the influx of particles containing Pu isotopes into the Baltic Sea. While in the Curonian Lagoon, the 239,240Pu activities in the sediment samples varied insignificantly during the study periods, in the Baltic Sea, the maximum activity decreased by a factor of 6, and the mean/median values decreased by ∼4 times. The assessment tool ERICA was used to calculate the dose rates for biota. The total dose rate from all analysed radionuclides was <0.1 µGy/h, therefore no risk to organisms was identified.

Temporal changes in tritium and radiocarbon concentrations in the western North Pacific Ocean (1993-2012).

The western North Pacific is one of the most studied oceanic basins due to its diverse structure and important role in connection with the adjacent reservoirs. Tritium (3H) and radiocarbon (14C) have been frequently exploited as oceanographic tracers due to their suitable properties; several extensive observation projects, such as GEOSECS, WOCE and WOMARS, used these two radionuclides to investigate different oceanographic processes, pathways, ocean currents and time scales of deep and bottom water formation. Here we evaluate temporal changes in 3H and 14C levels in seawater of the western North Pacific Ocean from 1993 to 2012. When compared to the background levels from 1993, the data from 2012 suggests significant impact of the Fukushima Dai-ichi Nuclear Power Plant (FDNPP) accident on surface and vertical 3H seawater profiles, increasing its water column inventories in the southern part of the 149°E meridian by a factor of 2-7. On the other hand, 14C content in surface seawater has been steadily decreasing from 1993, with the accelerated rate from 2005, probably due to downwelling of bomb-produced radiocarbon and its transport along isopycnal layers. The influence of the Oyashio current on 14C levels in the northern part of the investigated transect and formation of its intrusion was also clearly visible in the collected datasets. Regarding bomb-produced radiocarbon, its water column inventories decreased or remained same from 2005 to 2012 at all stations, except the ones located in the coastal areas of the New Guinea island (3.5°S).

Radiocarbon analysis of carbonaceous aerosols in Bratislava, Slovakia.

Aerosols dispersed in the atmosphere represent important factors influencing not only the environment, but also human health. Carbonaceous aerosols are one of the main components of total atmospheric aerosols, and their sources are of great interest. Radiocarbon analysis provides an excellent way to determine the fraction of fossil and non-fossil aerosols in the atmosphere. Over the period of one year (June 2017-June 2018), we sampled atmospheric aerosols with size greater than 0.3 µm in Bratislava, Slovakia and used the exposed quartz filters for radiocarbon analysis of the elemental carbon (EC) aerosol fraction. The results show that on average the fossil fuel combustion is the dominant source of EC aerosol particles in Bratislava. In summer months, they represent more than half (65-80%) of the total EC aerosols. The relative amount of EC particles derived from biomass burning was 20-35% in summer, which increased to 40-55% in winter months. The dominance of fossil fraction is caused by high degree of industrialization and urbanization of the city. The increase of biomass fraction in winter is probably caused by domestic wood burning in areas surrounding the Bratislava city.

Radiocarbon and 137Cs dating of wines.

Wine dating methods based on anthropogenic 14C and 137Cs, as well as on the cosmogenic 14C were studied with the aim to improve the accuracy and precision of the dating results. While the 14C dating method has proved to be useful for dating young and old wines, the 137Cs has been effective for dating of wines originating around the 137Cs bomb-peak observed in 1963. A new method was developed for simultaneous 14C and 137Cs dating of wines, which helped to distinguish wines originating before or after the bomb peak. The δ13C values also helped to solve the 14C age ambiguity in dating of wines around the 14C bomb peak. While the 14C dating method is always destructive one, the 137Cs method may use a radiochemical separation of cesium from wine samples when better precision of results is required, but it can be also a nondestructive one with direct gamma-spectrometry of wine samples, especially those that are very rare.

Tritium and radiocarbon in the western North Pacific waters: post-Fukushima situation.

Impact of the Fukushima Dai-ichi Nuclear Power Plant (FNPP1) accident on tritium (3H) and radiocarbon (14C) levels in the water column of the western North Pacific Ocean in winter 2012 is evaluated and compared with radiocesium (134,137Cs) data collected for the same region. Tritium concentrations in surface seawater, varying between 0.4 and 2.0 TU (47.2-236 Bq m-3), follow the Fukushima radiocesium trend, however, some differences in the vertical profiles were observed, namely in depths of 50-400 m. No correlation was visible in the case of 14C, whose surface Δ14C levels raised from negative values (about -40‰) in the northern part of transect, to positive values (∼68‰) near the equator. Homogenously mixed 14C levels in the subsurface layers were observed at all stations. Sixteen surface (from 30 in total) and 6 water profile (from 7) stations were affected by the Fukushima tritium. Surface and vertical profile data together with the calculated water column inventories indicate that the total amount of the FNPP1-derived tritium deposited to the western North Pacific Ocean was 0.7 ±â€¯0.3 PBq. No clear impact of the Fukushima accident on 14C levels in the western North Pacific was observed.