Distribution of Trace Metals in Street Dusts and Tree Leaves and Their Source Identification in a Mid-Populated Anatolian City.

Sivas is a central Anatolian city in Turkey with mid-population. Due to its geographical structure high air pollution episodes can be observed in the atmosphere of Sivas. A study with city wide sampling campaign can help to identify the possible sources. Therefore, we aimed to investigate the multi-elemental and multi-point analysis of trace metals in street dusts and tree leaves in Sivas. In the street dusts, Ca concentration was > 10%. Fe, Cl, and K contribution was 2.5%, 1.75%, and 1.1%, respectively. The average S and Ti concentrations were between 1 and 10 mg/g, I, Mn, Sr, Cr, V, Ba, Zn, Ni, Zr, and Cu were between 1 and 0.1 mg/g, and W, Pb, Sn, Th, Rb, Sb, Co, Bi, As, U were between 0.1 and 0.01 mg/g, in the ascending order. The same elements were investigated for vegetation. Ca, K, S, and Cl were the elements with highest contribution.

Environmental radioactivity and high incidence rates of stomach and esophagus cancer in the Van Lake region: a causal relationship?

This study examined the incidence rates of cancer cases (averages for 2006-2010) and relationships with environmental radioactivity levels. Soil and water samples were collected from provincial and district centers of Van city and the outdoor gamma doses were determined using a portable gamma scintillation detector. Gross alpha and beta, (226)Ra, (232)Th, and (40)K activities were measured in both tap water and soil samples. Although high rates of stomach and esophagus cancers have been reported previously in Van the underlying reasons have not hitherto been defined. Incidences of cancers were highest in the Gurpinar (326.0) and Ozalp (377.1) counties (p<0.001). As to the results of the gross alpha and gross beta radioactivity measurements in the drinking water, these two counties also had high beta radionuclide levels: Gurpinar (140 mBq/dm3) and Ozalp (206 mBq/dm3). Even if within the normal range, a relation between the higher rate of the incidence of stomach and esophagus cancers with that of the higher rate of beta radionuclide activity was clear. On Spearman correlation analysis, the relation between higher beta radionuclide levels and cancer incidence was found to be statistically significant (p<0.01). According to the results of the analysis, Van residents receive an average 1.86 mSv/y annual dose from outdoor gamma radiation, ingestion of radionuclides in the drinking water, and indoor 222Rn activity. Moreover, gross alpha and beta activities were found to be extremely high in all of the lakes around the city of Van, Turkey. Further investigations with long-term detailed environmental radiation measurements are needed regarding the relationship between cancer cases and environmental radioactivity in the city of Van.

Quality control of iodine-131-labeled metaiodobenzylguanidine.

AIM/OBJECTIVES/BACKGROUND: Iodine-131-m-iodobenzylguanidine ([(131)I]mIBG) is used worldwide for the diagnosis and therapy of neuroendocrine tumors, particularly adrenal medullae tumors. After the synthesis and preparation of a radioiodinated MIBG drug formulation, quality control testing to determine its radiochemical purity (RCP) should be performed. European Pharmacopoeia 8.0 requires that the quality control include a test for RCP for the determination of [(131)I]mIBG. Previously reported procedures using reversed-phase conditions require long retention times. Our system enables the separation of [(131)I]mIBG within a few minutes. The aim of this work was to carry out RCP testing for [(131)I]mIBG without any type of sample pretreatment. METHODS: RCP testing for ([(131)I]mIBG has been carried out using high-performance liquid chromatography and thin-layer chromatography methods. RESULTS: A simple and rapid reversed-phase isocratic system enables the HPLC investigation of RCP testing for [(131)I]mIBG used for therapy within a few minutes. CONCLUSIONS: From the point of view of radiation protection, this method is safer, especially for therapeutic amounts of [(131)I]mIBG.

Natural radioactivity in bottled mineral and thermal spring waters of Turkey.

Radiological assessment of bottled mineral waters and thermal spring waters collected from various natural sources in Turkey was carried out using gross alpha and gross beta counting techniques. For 40 samples of bottled mineral water, the mean gross alpha activity concentration was determined to be 164 mBq l(-1) (min.:7 mBq l(-1); max.: 3042 mBq l(-1)), whereas the gross beta activity concentration was found to be 555 mBq l(-1) (min.: 21 mBq l(-1); max.: 4845 mBq l(-1)). For 24 samples of thermal spring water, the mean gross alpha activity concentration was obtained to be 663 mBq l(-1) (min.: 18 mBq l(-1); max.: 3070 mBq l(-1)). The gross beta activity concentration for these samples, on the other hand, was determined to be 3314 mBq l(-1) (min.: 79 mBq l(-1); max.: 17955 mBq l(-1)). These values lead to the average annual effective doses of 313 µSv for mineral waters and 1805 µSv for thermal spa waters, which are found to be higher than those recommended for drinking waters by the World Health Organization. It should be noted, however, that one will get less dose from mineral waters since the daily consumption is much lower than 2 l that these calculations assume.

Assessment of natural radioactivity concentrations and gamma dose rate levels in Kayseri, Turkey.

This study assesses the level of background radiation for Kayseri province of Turkey. Natural radionuclide activity concentrations in soil samples were determined using high-resolution gamma spectroscopy. Outdoor gamma dose measurements in air at 1 m above ground level were determined using a portable gamma scintillation detector. The obtained results of uranium and thorium series as well as potassium ((40)K) are discussed. The present data were compared with the data obtained from different areas in Turkey. From the measured gamma-ray spectra, the average activity concentrations were determined for (238)U (range from 3.91 to 794.25 Bq kg(-1)), (232)Th (range from 0.68 to 245.55 Bq kg(-1)) and (40)K (range from 23.68 to 2718.71 Bq kg(-1)). The average activity concentrations of (238)U, (232)Th and (40)K were found to be 35.51, 37.27 and 429.66 Bq kg(-1), respectively, and 11.53 Bq kg(-1) for the fission product (137)Cs. The highest values of (238)U, (232)Th and (40)K concentrations (794.25 Bq kg(-1), 245.55 Bq kg(-1), 2718.71 Bq kg(-1), respectively) were observed in abnormal samples at Hayriye village. The average outdoor gamma dose rate in air at 1 m above the ground was determined as 114.43 nGy h(-1). Using the data obtained in this study, the average annual effective dose for a person living in Kayseri was found to be about 140.34 µSv.

A study of environmental radioactivity measurements for Cankiri, Turkey.

This study is the first to assess the level of background radiation for the Cankiri province of Turkey. Indoor air radon concentrations were determined using Columbia Resin-39 nuclear track detectors and the average (222)Rn activity was found to be 44 Bq m(-3) (equivalent to an annual effective dose of 1.1 mSv). Measurements of gamma doses in outdoor air were performed using a portable plastic scintillation detector and the average gamma absorbed dose rate was found to be 8 µR h(-1) (corresponding to an annual effective dose of 87.7 µSv). Radionuclide activity concentrations in soil samples were measured through gamma-ray spectrometry and the average activities were determined as 17.7, 22.3, 357 and 4.1 Bq kg(-1) for the radionuclides (238)U, (232)Th, (40)K and (137)Cs, respectively. The average annual effective dose from the natural radioactivity sources ((238)U series, (232)Th series and (40)K) was calculated to be 44.4 µSv. Radioactivity levels of drinking water samples were carried out using a low-background proportional counter and the average gross alpha and beta activities were obtained as 0.25 and 0.26 Bq l(-1), respectively (equivalent to an annual effective dose of 184 µSv). The average radon concentrations in indoor air and the average radionuclide activities in soil were found to be lower than most Turkish cities while higher levels of outdoor gamma dose rate and water radioactivity were observed. The results of this study showed that the region's background radioactivity level differs considerably from the reported data for Turkish cities.

A study of background radioactivity level for Canakkale, Turkey.

This study assesses the level of background radiation for Canakkale province of northwestern Turkey. Radon concentrations in indoor air were determined using CR-39 nuclear track detectors and (222)Rn activity was found to be 167 Bq m( - 3) (equivalent to an annual effective dose of 4.2 mSv). Measurements of outdoor gamma radiation (of terrestrial and cosmic origin) in air were performed using plastic scintillators, and the average absorbed gamma dose rate was found to be 66.4 nGy h( - 1) (corresponding to an annual effective dose of 81.4 muSv). The radionuclide activity concentrations in soil samples collected from the study area were measured through gamma-ray spectrometry, and the average activities were determined as 94.55, 110.4, and 1,273 Bq kg( - 1) for the natural radionuclides (238)U, (232)Th, and (40)K, respectively, and 19.39 Bq kg( - 1) for the fission product (137)Cs. The natural radioactivity sources resulted in an annual effective dose of 184 muSv. The radioactivity levels of drinking water samples were measured as 0.0599 Bq l( - 1) for gross-alpha activity and 0.0841 Bq l( - 1) for gross-beta activity using a low-background counting technique (equivalent to an annual effective dose of 12.25 muSv). The results of this study show that the activity levels of radon in air, radionuclides in soil, and alpha activities in drinking water are higher compared to the data available for other Turkish cities and the world averages. On the other hand, the outdoor gamma dose rates in air and beta activities in drinking water are within natural limits.

A study of background radioactivity level for Tekirdag, Turkey.

The level of background radiation for Tekirdag province of north-western Turkey was assessed in this study. Radon concentrations in indoor air were determined using CR-39 nuclear track detectors and the average (222)Rn activity was found to be 86 Bq m(-3) (equivalent to an annual effective dose of 2.2 mSv). Measurements of gamma doses in air were performed using plastic scintillators and the average absorbed gamma dose rates for indoor and outdoor were found to be 5.7 and 5 microR h(-1), respectively, corresponding to an annual effective dose of 300 microSv. The radionuclide activity concentrations in soil samples collected from the study area were measured through gamma-ray spectrometry and the average activities were determined as 29, 39 and 580 Bq kg(-1) for the natural radionuclides (238)U, (232)Th and (40)K, respectively, and 5.2 Bq kg(-1) for the fission product (137)Cs. The natural radioactivity sources resulted in an annual effective dose of 75 microSv. The radioactivity levels of drinking water samples were measured as 0.044 and 0.1 Bq l(-1) for gross alpha and gross beta activities using a low-background counting technique (equivalent to an annual effective dose of 9 microSv). The results of this study showed that the region's background radioactivity level is in agreement with most Turkish cities.

Assessment of background radioactivity level for Gaziantep region of southeastern Turkey.

This study presents the measurement results of environmental radioactivity levels for Gaziantep, an industrial and trade centre in the southeastern part of Turkey. The outdoor gamma absorbed dose was measured as 50.1 nGy h(-1), corresponding to a total gamma radiation level (of terrestrial and cosmic origin) of 61.5 microSv y(-1). The activity concentrations in the surface soil samples collected from the study area were determined as 25.2, 23.7 and 289.2 Bq kg(-1) for the natural radionuclides (238)U, (232)Th and (40)K, respectively, and 8.02 Bq kg(-1) for the fission product (137)Cs. These natural radioactivity sources result in a terrestrial gamma level of 46.9 microSv y(-1). The drinking water samples collected from the region carry an average of 0.0493 Bq l(-1) of gross alpha and 0.1284 Bq l(-1) of gross beta activities, which together cause an annual effective dose of 1.83 microSv. The measurement results obtained in this study indicate that the region has a background radiation level that is within the natural limits and shows no significant departure from the other parts of the country.

Environmental radioactivity measurements in Kastamonu region of northern Turkey.

Located in the north-western part of Turkey, the province of Kastamonu has lately been receiving national attention because of its cultural and touristic attractions. This study assesses the environmental radioactivity levels of the region through measurements of indoor radon concentrations and indoor/outdoor gamma absorbed dose in air and radionuclide activities in surface soil and drinking water. The indoor (222)Rn activity concentration was found to be 98.4 Bq/m(3) equivalent to an annual effective dose of 2.48 mSv. The indoor and outdoor gamma absorbed doses were measured as 54.81 and 48.03 nGy/h, respectively, corresponding to a total gamma radiation level (of terrestrial and cosmic origin) of 0.33 mSv/y. The activity concentrations in the soil samples collected from the study area were determined as 32.93, 27.17, 431.43 Bq/kg for the natural radionuclides (238)U, (232)Th and (40)K, respectively, and 8.02 Bq/kg for the fission product (137)Cs. These natural radioactivity sources result in a terrestrial gamma level of 60 microSv/y. The water samples collected from the region carry an average of 0.0089 Bq/l of gross alpha and 0.271 Bq/l of gross beta activities which together cause an annual effective dose of 1.83 microSv. The measurement results obtained in this study indicate that the region has a background radiation level that is within the natural limits and shows no significant departure from the other parts of the country.