Thermodynamic uncertainty relations for steady-state thermodynamics.

A system can be driven out of equilibrium by both time-dependent and nonconservative forces, which gives rise to a decomposition of the dissipation into two nonnegative components, called the excess and housekeeping entropy productions. We derive thermodynamic uncertainty relations for the excess and housekeeping entropy. These can be used as tools to estimate the individual components, which are in general difficult to measure directly. We introduce a decomposition of an arbitrary current into housekeeping and excess parts, which provide lower bounds on the respective entropy production. Furthermore, we also provide a geometric interpretation of the decomposition and show that the uncertainties of the two components are not independent, but rather have to obey a joint uncertainty relation, which also yields a tighter bound on the total entropy production. We apply our results to a paradigmatic example that illustrates the physical interpretation of the components of the current and how to estimate the entropy production.

Higher-order efficiency bound and its application to nonlinear nanothermoelectrics.

Power and efficiency of heat engines are two conflicting objectives. A tight efficiency bound is expected to give insights on the fundamental properties of such a power-efficiency tradeoff. Here, we derive an upper bound on the efficiency of steady-state heat engines, which incorporates higher-order fluctuations of power. In a prototypical model of nonlinear nanostructured thermoelectrics, we show that the obtained bound is tighter than a well-established efficiency bound derived from the thermodynamic uncertainty relation, demonstrating that the higher-order terms have rich information about the thermodynamic efficiency in the nonlinear regime. In particular, we find that the higher-order bound is exactly achieved if the tight coupling condition is satisfied. The obtained bound gives a consistent prediction with an observation that nonlinearity enhances the power-efficiency tradeoff, and would also be useful in a variety of nanoscale engines.