Next-generation ultrafiltration membranes: A review of material design, properties, recent progress, and challenges.

Membrane technology utilizing ultrafiltration (UF) processes has emerged as the most widely used and cost-effective simple process in many industrial applications. The industries like textiles and petroleum refining are promptly required membrane based UF processes to alleviate the potential environmental threat caused by the generation of various wastewater. At the same time, major limitations such as material selection as well as fouling behavior challenge the overall performance of UF membranes, particularly in wastewater treatment. Therefore, a complete discussion on material design with structural property relation and separation performance of UF membranes is always exciting. This state-of-the-art review has exclusively focused on the development of UF membranes, the material design, properties, progress in separation processes, and critical challenges. So far, most of the review articles have examined the UF membrane processes through a selected track of paving typical materials and their limited applications. In contrast, in this review, we have exclusively aimed at comprehensive research from material selection and fabrication methods to all the possible applications of UF membranes, giving more attention and theoretical understanding to the complete development of high-performance UF systems. We have discussed the methodical engineering behind the development of UF membranes regardless of their materials and fabrication mechanisms. Identifying the utility of UF membrane systems in various applications, as well as their mode of separation processes, has been well discussed. Overall, the current review conveys the knowledge of the present-day significance of UF membranes together with their future prospective opportunities whilst overcoming known difficulties in many potential applications.

Special wettable Azadirachta indica leaves like microarchitecture mesh filtration membrane produced by galvanic replacement reaction for layered oil/water separation.

The oil/water separation has received significant attention due to its critical environmental impact. The special wettable surfaces are highly desired to deal with the oil/water mixtures. This work demonstrates a simple two-step method to develop a superhydrophobic Azadirachta indica leaves like Ag-decorated electrochemically copper-coated stainless-steel mesh (SH-AIL-Ag-EC-Cu-Mesh) for efficient separation of oil/water mixtures. In the first step, the electrodeposition of the copper took place on the mesh surface at a suitable applied potential. In the second step, the galvanic replacement reaction between the Ag+ and electrodeposited Cu produced the fascinating superhydrophobic Ag leaves on the mesh surface. The SH-AIL-Ag-EC-Cu-Mesh was thoroughly characterized by the X-ray photoelectron spectroscopy (XPS), Energy Dispersive X-Ray Spectroscopy (EDX), elemental mapping, surface wettability analysis, and the contact analyzer. The morphological analysis has shown the unique leafy structures of the reduced Ag on the surface of the mesh. The XPS analysis has confirmed that most of the Ag present on the surface is in zerovalent form. The combination of the electrodeposition and the displacement reaction between the copper and the silver turned the surface superhydrophobic, and the water contact angle was significantly improved from 115° to 158°. The designed SH-AIL-Ag-EC-Cu-Mesh has shown excellent selectivity for oil in oil/water mixtures with a separation efficiency of 99.1% with an exceptionally high flux of 8963 L m-2h-1. The SH-AIL-Ag-EC-Cu-Mesh has shown excellent reusability, and after 15 cycles of separation, no significant decrease in the oil/water separation efficiency was observed.

Designing of nanotextured inorganic-organic hybrid PVDF membrane for efficient separation of the oil-in-water emulsions.

The separation of the emulsified oil/water is one of the critical environmental challenges. The PVDF membranes have been found helpful for separation, but rapid fouling makes them less attractive in treating oil-in-water emulsions. The design of antifouling membranes has become an area of deep interest. Herein, developing a novel modified PVDF ultrafiltration membrane was reported by doping the pyrrole and solidifying it in a ferric-containing coagulation bath, resulting in a unique nanotextured PVDF membrane (CCB-Fe/PPnp-PVDF) to separate the oil/water emulsions. The resultant CCB-Fe/PPnp-PVDF membrane was thoroughly characterized using the FTIR, FE-SEM, EDX, mapping, AFM, and contact analyzer. The hydrophilicity of the CCB-Fe/PPnp-PVDF was substantially improved, and the water contact angle was reduced from 81Ö¯ ± 0.9Ö¯ to 44Ö¯ ± 1.7Ö¯. The CCB-Fe/PPnp-PVDF membrane flux increased by 121% compared to the pristine PVDF membrane, with high separation efficiency of 99%. The hydrophilic nanotextured surface of the CCB-Fe/PPnp-PVDF membrane showed good antifouling behavior, with a flux recovery ratio (FRR) of more than 96%. Irreversible flux was just less than 4%. The high flux recovery ratio indicated that the nanotextured surface produced by the Fe/PPnp had prevented the blockage of the membrane pores and compact cake layer formation, which makes it an excellent membrane for oil/water emulsion separation. This strategy can be adopted for designing advanced membranes for separation applications.

Removal of Oily Contaminants from Water by Using the Hydrophobic Ag Nanoparticles Incorporated Dopamine Modified Cellulose Foam.

The presence of oil-related contaminants in water has emerged as a severe threat to the environment. The separation of these contaminants from water has become a great challenge, and extensive efforts are being made to develop suitable, environmentally friendly materials. Highly hydrophobic materials are effective in the selective separation of oil from water. In this work, silver (Ag)-incorporated, highly hydrophobic dopamine-modified cellulose sponge was prepared by functionalizing with the range of alkyl silanes. The Ag nanoparticle-incorporated dopamine provided the appropriate roughness, whereas the alkyl component provided the low surface energy that made it selective towards oil. It was found that the alkyl groups with a longer chain length were more effective in enhancing the hydrophobicity of the Ag nanoparticle-incorporated, dopamine-modified cellulose. The developed materials were characterized by Fourier transform infrared spectroscopy (FTIR), field emission-scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDX), elemental mapping, and contact angle goniometry. The maximum water contact angle on the functionalized surfaces was observed at 148.4°. The surface of the C18s-Ag-DA-Cell-F showed excellent selectivity towards the oily component that rapidly permeated, and water was rejected wholly. The developed material showed a separation efficiency of 96.2% for the oil/water mixture. The C18s-Ag-DA-Cell-F material showed excellent reusability. Due to their environmentally friendly nature, excellent selectivity, and good separation efficiency, the functionalized cellulose materials can be used to separate oil and water effectively.

Designing Imidazolium Poly(amide-amide) and Poly(amide-imide) Ionenes and Their Interactions with Mono- and Tris(imidazolium) Ionic Liquids.

Here we introduce the synthesis and thermal properties of a series of sophisticated imidazolium ionenes with alternating amide-amide or amide-imide backbone functionality, and investigate the structural effects of mono(imidazolium) and unprecedented tris(imidazolium) ionic liquids (ILs) in these ionenes. The new set of poly(amide-amide) (PAA) and poly(amide-imide) (PAI) ionenes represent the intersection of conventional high-performance polymers with the ionene archetype-presenting polymers with alternating functional and ionic elements precisely sequenced along the backbone. The effects of polymer composition on the thermal properties and morphology were analyzed. Five distinct polymer backbones were synthesized and combined with a stoichiometric equivalent of the IL 1-benzyl-3-methylimidazolium bistriflimide ([Bnmim][Tf2N]), which were studied to probe the self-assembly, structuring, and contributions of intermolecular forces when IL is added. Furthermore, three polyamide (PA) or polyimide (PI) ionenes with simpler xylyl linkages were interfaced with [Bnmim][Tf2N] as well as a novel amide-linked tris(imidazolium) IL, to demonstrate the structural changes imparted by the inclusion of functional, ionic additives dispersed within the ionene matrix. This work highlights the possibilities for utilizing concepts from small molecules which exhibit supramolecular self-assembly to guide creative design and manipulate the structuring of ionenes.

Synthesis and Performance of Aromatic Polyamide Ionenes as Gas Separation Membranes.

Here, we report the synthesis and thermophysical properties of seven primarily aromatic, imidazolium-based polyamide ionenes. The effects of varied para-, meta-, and ortho-connectivity, and spacing of ionic and amide functional groups, on structural and thermophysical properties were analyzed. Suitable, robust derivatives were cast into thin films, neat, or with stoichiometric equivalents of the ionic liquid (IL) 1-benzy-3-methylimidazolium bistriflimide ([Bnmim][Tf2N]), and the gas transport properties of these membranes were measured. Pure gas permeabilities and permselectivities for N2, CH4, and CO2 are reported. Consistent para-connectivity in the backbone was shown to yield the highest CO2 permeability and suitability for casting as a very thin, flexible film. Derivatives containing terephthalamide segments exhibited the highest CO2/CH4 and CO2/N2 selectivities, yet CO2 permeability decreased with further deviation from consistent para-linkages.

Design and Synthesis of Imidazolium-Mediated Tröger's Base-Containing Ionene Polymers for Advanced CO2 Separation Membranes.

It is highly desirable to integrate the CO2 solubility benefits of ionic liquids (ILs) in polymeric membrane systems for effective CO2 separations. Herein, we are exclusively exploring a series of four novel imidazolium-mediated Tröger's base (TB)-containing ionene polymers for enhanced CO2 separation. The two diimidazole-functionalized Tröger's base monomers synthesized from "ortho"- and "para"-substituted imidazole anilines were polymerized with equimolar amounts of two different aromatic and aliphatic comonomers (α,α'-dichloro-p-xylene and 1,10-dibromodecane, respectively) via Menshutkin reactions to obtain four respective ionene polymers ([Im-TB(o&p)-Xy][Cl] and ([Im-TB(o&p)-C10][Br], respectively). The resulting ionene polymers having halide anions were exchanged with [Tf2N]- anions, yielding a novel Tröger's base material [Im-TB(x)-R][Tf2N] or "Im-TB-Ionenes". The structural and physical properties as well as the gas separation behaviors of the copolymers of aromatic and aliphatic Im-TB-Ionenes have been extensively investigated with respect to the regiochemistry of imidazolium groups at the ortho and para positions of the TB unit. The imidazolium-mediated TB-Ionenes showed high CO2 solubility and hence an excellent CO2/CH4 permselectivity of 82.5. The Im-TB-Ionenes also displayed good thermal and mechanical stabilities.

Synthesis and Performance of 6FDA-Based Polyimide-Ionenes and Composites with Ionic Liquids as Gas Separation Membranes.

Three new isomeric 6FDA-based polyimide-ionenes, with imidazolium moieties and varying regiochemistry (para-, meta-, and ortho- connectivity), and composites with three different ionic liquids (ILs) have been developed as gas separation membranes. The structural-property relationships and gas separation behaviors of the newly developed 6FDA polyimide-ionene + IL composites have been extensively studied. All the 6FDA-based polyimide-ionenes exhibited good compatibility with the ILs and produced homogeneous hybrid membranes with the high thermal stability of ~380 °C. Particularly, [6FDA I4A pXy][Tf2N] ionene + IL hybrids having [C4mim][Tf2N] and [Bnmim][Tf2N] ILs offered mechanically stable matrixes with high CO2 affinity. The permeability of CO2 was increased by factors of 2 and 3 for C4mim and Bnmim hybrids (2.15 to 6.32 barrers), respectively, compared to the neat [6FDA I4A pXy][Tf2N] without sacrificing their permselectivity for CO2/CH4 and CO2/N2 gas pairs.