1.
J Org Chem
; 86(14): 9869-9875, 2021 Jul 16.
Artigo
em Inglês
| MEDLINE
| ID: mdl-34184898
RESUMO
The regioselective sila-acylation and silaformylation of 1,3-dienes was achieved over a copper catalyst using a silylborane as a silyl source. ß,γ-Unsaturated ketones with a (dimethylphenylsilyl)methyl moiety at the α-position were obtained using esters, while ß,γ-unsaturated aldehydes were obtained using formate esters.