1.
J Org Chem
; 64(6): 2096-2102, 1999 Mar 19.
Artigo
em Inglês
| MEDLINE
| ID: mdl-11674305
RESUMO
The steric course of the photocyclization reaction of the title achiral compounds (1) to optically active trans-dihydrofuran derivatives (2) was controlled by carrying out the reaction in inclusion crystals (4) with optically active hosts (3) derived from tartaric acid. The mechanism of the enantioselective reaction of 1 in 4 was studied by X-ray structural analysis of 4. In some cases, the steric course of the photoreaction was different depending on whether 4 was prepared by recrystallization or by mixing of 1 and 3.
2.