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1.
JACS Au ; 4(3): 1097-1106, 2024 Mar 25.
Artigo em Inglês | MEDLINE | ID: mdl-38559718

RESUMO

Colloidal quantum dots (CQDs) have garnered significant attention in nanoscience and technology, with a particular emphasis on achieving high monodispersity in their synthesis. Recent advances in understanding the chemistry of reaction intermediates such as magic-sized nanoclusters (MSC) have paved the way for innovative synthetic strategies. Notably, monodisperse CQDs of various compositions, including indium phosphide, indium arsenide, and cadmium chalcogenide, have been successfully prepared using nanocluster intermediates as single-source precursors. Still, the early stage conversion chemistry of these nanoclusters preceding CQD formation has not been fully unveiled yet. Herein, we report the first-order conversion of amorphous nanoclusters (AMCs) to InAs MSCs prior to the formation of CQDs. We find that MSC, isolated via gel-permeation chromatography, is more stable than purified AMCs, as demonstrated in various chemical and thermolytic reactions. While the surface of InAs AMCs and MSC is similarly bound with carboxylate ligands, detailed structural analyses employing synchrotron X-ray scattering and X-ray absorption spectroscopy unveil subtle distinctions arising from the distinct surface properties and structural disorder characteristics of InAs nanoclusters. We propose that InAs AMCs undergo a surface reduction and structural ordering process, resulting in the formation of an InAs MSC in a thermodynamically local minimum state. Furthermore, we demonstrate that both types of nanoclusters serve as viable precursors, providing a similar monomer supply rate at elevated temperatures of around 300 °C. This study offers invaluable insights into the interplay of structure and chemical stability in binary nanoclusters, enhancing our ability to design these nanoclusters as precursors for highly monodisperse CQDs.

2.
J Am Chem Soc ; 146(13): 9293-9301, 2024 Apr 03.
Artigo em Inglês | MEDLINE | ID: mdl-38516847

RESUMO

Self-assembly-based structural transition has been explored for various applications, including molecular machines, sensors, and drug delivery. In this study, we developed new redox-active metal-organic frameworks (MOFs) called DGIST-10 series that comprise π-acidic 1,4,5,8-naphthalenediimide (NDI)-based ligands and Ni2+ ions, aiming to boost ligand-self-assembly-driven structural transition and study the involved mechanism. Notably, during the synthesis of the MOFs, a single-crystal-amorphous-single-crystal structural transition occurred within the MOFs upon radical formation, which was ascribed to the fact that radicals prefer spin-pairing or through-space electron delocalization by π-orbital overlap. The radical-formation-induced structural transitions were further confirmed by the postsynthetic solvothermal treatment of isolated nonradical MOF crystals. Notably, the transient amorphous phase without morphological disintegration was clearly observed, contributing to the seminal structural change of the MOF. We believe that this unprecedented structural transition triggered by the ligand self-assembly magnifies the structural flexibility and diversity of MOFs, which is one of the pivotal aspects of MOFs.

3.
Sci Adv ; 8(51): eade1383, 2022 Dec 23.
Artigo em Inglês | MEDLINE | ID: mdl-36563156

RESUMO

Radical-ionic metal-organic frameworks (MOFs) have unique optical, magnetic, and electronic properties. These radical ions, forcibly formed by external stimulus-induced redox processes, are structurally unstable and have short radical lifetimes. Here, we report two naphthalenediimide-based (NDI-based) Ca-MOFs: DGIST-6 and DGIST-7. Neutral DGIST-6, which is generated first during solvothermal synthesis, decomposes and is converted into radical-anionic DGIST-7. Cofacial (NDI)2•- and (NDI)22- dimers are effectively stabilized in DGIST-7 by electron delocalization and spin-pairing as well as dimethylammonium counter cations in their pores. Single-crystal x-ray diffractometry was used to visualize redox-associated structural transformations, such as changes in centroid-to-centroid distance. Moreover, the unusual rapid reduction of oxidized DGIST-7 into the radical anion upon infrared irradiation results in effective and reproducible photothermal conversion. This study successfully illustrated the strategic use of in situ prepared cofacial ligand dimers in MOFs that facilitate the stabilization of radical ions.

4.
J Phys Chem Lett ; 13(25): 5711-5718, 2022 Jun 30.
Artigo em Inglês | MEDLINE | ID: mdl-35713637

RESUMO

Ultrafast charge transfer in van der Waals (vdW) heterostructures enables efficient control of two-dimensional material properties through strong optical absorption and subsequent carrier transfer. Here, using real-time time-dependent density functional theory coupled to molecular dynamics, we investigated the nonequilibrium dynamics of charge-density-wave (CDW) melting in 1T-TaS2 triggered by ultrafast charge transfer in 1T-TaS2/MoSe2 or WSe2 heterostructures. Despite the fast and sufficient charge transfer from the MoSe2 (or WSe2) "electrode" to the 1T-TaS2 layer, the electronic excitation of the vdW heterostructure does not lead to the nonthermal CDW transition of 1T-TaS2. Instead, the TaS2 lattice is heated by carrier-lattice scattering, leading to thermal CDW melting at high ionic temperatures. The lack of nonthermal melting follows from the fact that the time scale of carrier recombination in 1T-TaS2 is similar to or faster than that of charge transfer. These findings provide physical insights into understanding the CDW melting dynamics in vdW heterostructures under nonequilibrium conditions.

5.
Sci Rep ; 8(1): 13940, 2018 Sep 17.
Artigo em Inglês | MEDLINE | ID: mdl-30224827

RESUMO

The origin of the ferromagnetism in metal-free graphitic materials has been a decade-old puzzle. The possibility of long-range magnetic order in graphene has been recently questioned by the experimental findings that point defects in graphene, such as fluorine adatoms and vacancies, lead to defect-induced paramagnetism but no magnetic ordering down to 2 K. It remains controversial whether collective magnetic order in graphene can emerge from point defects at finite temperatures. This work provides a new framework for understanding the ferromagnetism in hydrogenated graphene, highlighting the key contribution of the spin-polarized pseudospin as a "mediator" of long-range magnetic interactions in graphene. Using first-principles calculations of hydrogenated graphene, we found that the unique 'zero-energy' position of H-induced quasilocalized states enables notable spin polarization of the graphene's sublattice pseudospin. The pseudospin-mediated magnetic interactions between the H-induced magnetic moments stabilize the two-dimensional ferromagnetic ordering with Curie temperatures of Tc = nH × 34,000 K for the atom percentage nH of H adatoms. These findings show that atomic-scale control of hydrogen adsorption on graphene can give rise to a robust magnetic order.

6.
Phys Chem Chem Phys ; 19(41): 28098-28104, 2017 Oct 25.
Artigo em Inglês | MEDLINE | ID: mdl-29018863

RESUMO

The binding of nitric oxide (NO) to heme-proteins is an important biochemical process involved in a variety of physiological functions. Here, using hybrid density-functional calculations, we systematically investigate the adsorption of NO to first-transition-row metal centers in metal-ligand complexes. Through the comparative study for different transition metal (TM) centers, we provide a unified understanding of the microscopic interactions of NO with the TM centers and related chemical trends. We found that as the atomic number of the TM center increases, the binding strength of NO is largely reduced from 207 kJ mol-1 to near zero due to the low d-orbital energies for late TM centers. The intermolecular spin coupling between the localized spins at the TM center and the NO molecule is generally antiferromagnetic, except for the case of Sc. The spin-spin coupling is determined in such a way to avoid the energy penalty associated with the electron occupation in the antibonding states of the NO-bound complex. The adsorption strength of NO is generally larger than of CO because the unpaired electron of NO occupies the associated bonding state.

7.
Nanotechnology ; 27(41): 415711, 2016 Oct 14.
Artigo em Inglês | MEDLINE | ID: mdl-27609354

RESUMO

The local modification of intermolecular interactions in nickel-phthalocyanine molecules (NiPCs) is investigated on an Au(111) substrate using scanning tunneling microscopy. When the molecules are physisorbed on the substrate, they repel each other due to induced charge dipole moments. However, when the NiPC is chemisorbed on the substrate through the dehydrogenation of one of its ligands by a bias pulse, we find that a nearby physisorbed NiPC is attracted to the dehydrogenated ligand and trapped. Using our experimental results in combination with density functional theory calculations, we show that the observed attraction can be ascribed to the local charge redistribution around the dehydrogenated ligand of the chemisorbed NiPC. Furthermore, we demonstrate that desorption of the attracted NiPC from the trapped site can be readily controlled by changing the density of NiPCs around the dehydrogenated ligand.

8.
J Phys Chem Lett ; 7(4): 597-602, 2016 Feb 18.
Artigo em Inglês | MEDLINE | ID: mdl-26800573

RESUMO

Many important layered semiconductors, such as hexagonal boron nitride (hBN) and transition-metal dichalcogenides (TMDs), are derived from a hexagonal lattice. A single layer of such hexagonal semiconductors generally has a direct bandgap at the high-symmetry point K, whereas it becomes an indirect, optically inactive semiconductor as the number of layers increases to two or more. Here, taking hBN and MoS2 as examples, we reveal the microscopic origin of the direct-to-indirect bandgap transition of hexagonal layered materials. Our symmetry analysis and first-principles calculations show that the bandgap transition arises from the lack of the interlayer orbital couplings for the band-edge states at K, which are inherently weak because of the crystal symmetries of hexagonal layered materials. Therefore, it is necessary to judiciously break the underlying crystal symmetries to design more optically active, multilayered semiconductors from hBN or TMDs.

9.
Inorg Chem ; 54(13): 6176-83, 2015 Jul 06.
Artigo em Inglês | MEDLINE | ID: mdl-26068376

RESUMO

A set of nickel(III) peroxo complexes bearing tetraazamacrocyclic ligands, [Ni(III)(TBDAP)(O2)](+) (TBDAP = N,N'-di-tert-butyl-2,11-diaza[3.3](2,6)pyridinophane) and [Ni(III)(CHDAP)(O2)](+) (CHDAP = N,N'-dicyclohexyl-2,11-diaza[3.3](2,6)pyridinophane), were prepared by reacting [Ni(II)(TBDAP)(NO3)(H2O)](+) and [Ni(II)(CHDAP)(NO3)](+), respectively, with H2O2 in the presence of triethylamine. The mononuclear nickel(III) peroxo complexes were fully characterized by various physicochemical methods, such as UV-vis, electrospray ionization mass spectrometry, resonance Raman, electron paramagnetic resonance, and X-ray analysis. The spectroscopic and structural characterization clearly shows that the NiO2 cores are almost identical where the peroxo ligand is bound in a side-on fashion. However, the different steric properties of the supporting ligands were confirmed by X-ray crystallography, where the CHDAP ligand gives enough space around the Ni core compared to the TBDAP ligand. The nickel(III) peroxo complexes showed reactivity in the oxidation of aldehydes. In the aldehyde deformylation reaction, the nucleophilic reactivity of the nickel(III) peroxo complexes was highly dependent on the steric properties of the macrocyclic ligands, with a reactivity order of [Ni(III)(TBDAP)(O2)](+) < [Ni(III)(CHDAP)(O2)](+). This result provides fundamental insight into the mechanism of the structure (steric)-reactivity relationship of metal peroxo intermediates.


Assuntos
Níquel/química , Compostos Organometálicos/química , Peróxido de Hidrogênio/química , Compostos Macrocíclicos/química , Modelos Moleculares , Oxirredução , Teoria Quântica
10.
Phys Rev Lett ; 111(21): 216801, 2013 Nov 22.
Artigo em Inglês | MEDLINE | ID: mdl-24313510

RESUMO

Effective control of hydrogenation of graphene is of great scientific and technological importance. However, the reversible control of H density (n(H)) on graphene is difficult due to the irreversible H2 formation of the detached H adatoms. Here we present a novel mechanism for controlling n(H) by using the unique proton transfer reaction between NH3 gas and hydrogenated graphene, which can be tuned by applying perpendicular electric fields. Using first-principles calculations, we show that n(H) can be reversibly tuned by the applied electric fields around the critical density for the Anderson localization in hydrogenated graphene. The proposed field-induced control of H adsorption or desorption on graphene opens a path toward the development of new graphene transistors based on the tunable degree of disorder.

11.
Phys Rev Lett ; 111(5): 055502, 2013 Aug 02.
Artigo em Inglês | MEDLINE | ID: mdl-23952417

RESUMO

Ductile metals such as Ni and Cu can become brittle when certain impurities (e.g., Bi) diffuse and segregate into their grain boundaries (GBs). Using first-principles calculations, we investigate the microscopic origin of the Bi-induced loss of cohesion of Ni and Cu GBs. We find that the Bi bilayer interfacial phase is the most stable impurity phase under the Bi-rich condition, while the Bi monolayer phase is a metastable phase regardless of the value of the Bi chemical potential. Our finding is consistent with the recent experimental observation for Ni GBs [Luo et al. Science 333, 1730 (2011)]. The electric polarization effect of the Bi bilayer substantially enhances the strength of the Bi-metal interfacial bonds, stabilizing the bilayer phase over other phases. The Bi-Bi interlayer bonding is significantly weakened in the GBs, leading to a factor of 20 to 50 decrease in the GB cohesion, which has strong implications for the understanding of Bi-induced intergranular fracture of Ni and Cu polycrystals.

12.
J Chem Phys ; 139(4): 044709, 2013 Jul 28.
Artigo em Inglês | MEDLINE | ID: mdl-23902005

RESUMO

When compressive strain is applied to a single-layered material, the layer generally ripples along the third dimension to release the strain energy. In contrast, such a rippling effect is not favored when it is under tensile strain. Here, using first-principles density-functional calculations, we show that molecular adsorption on boron-doped graphene (BG) can be largely tuned by exploiting the rippling effect of the strained graphene. Under tensile strain, the adsorption energy of K2CO3, NO2, and NH3 on BG, for which the molecular adsorption is a chemisorption characterized by a covalent B-molecule bond, exhibits a superlinear dependence on the applied strain. In contrast, when microscopic ripples are present in the BG under compressive strain, the adsorption strength is significantly enhanced with increasing the strain. Such a nonlinear and asymmetric effect of strain on the molecular adsorption is a characteristic of two-dimensional systems, because a general elastic theory of molecular adsorption on three-dimensional systems gives a linear and symmetric strain effect on the adsorption strength. We provide the underlying mechanism of the anomalous strain effect on the chemical molecular adsorption on BG, in which the microscopic rippling of the graphene and the creation of the π-dangling bond state near the Dirac point play an important role. Our finding can be used to modify chemical reactivity of graphene with a wide range of application.

13.
Phys Rev Lett ; 108(22): 226105, 2012 Jun 01.
Artigo em Inglês | MEDLINE | ID: mdl-23003629

RESUMO

The atomic and electronic structures of the liquid Al/(0001) α-Al(2)O(3) interfaces are investigated by first-principles molecular dynamics simulations. Surprisingly, the formed liquid-solid interface is always atomically abrupt and is characterized by a transitional Al layer that contains a fixed concentration of Al vacancies (~10 at.%). We find that the self-regulation of the defect density in the metal layer is due to the fact that the formation energy of the Al vacancies is readjusted in a way that opposes changes in the defect density. The negative-feedback effect stabilizes the defected transitional layer and maintains the atomic abruptness at the interface. The proposed mechanism is generally applicable to other liquid-metal/metal-oxide systems, and thus of significant importance in understanding the interface structures at high temperature.

14.
Phys Rev Lett ; 108(11): 115901, 2012 Mar 16.
Artigo em Inglês | MEDLINE | ID: mdl-22540487

RESUMO

The development of short-to-medium-range order in atomic arrangements has generally been observed in noncrystalline solid systems such as metallic glasses. Whether such medium-range order (MRO) can exist in materials at well above their melting or glass-transition temperature has been a long-standing important scientific issue. Here, using ab initio molecular dynamics simulations, we show that a novel, persistent MRO exists in liquid Al-Cu alloys near the composition of CuAl3. The correlated atomic motions associated with the MRO give rise to a substantially enhanced viscosity in the vicinity of the composition. The component of the MRO liquid state gradually decreases with increasing temperature, and it disappears above a crossover temperature T(LLC). The continuous liquid-liquid crossover through a percolationlike transition leads to a pronounced heat capacity peak at T(LLC).

15.
J Am Chem Soc ; 132(51): 18287-91, 2010 Dec 29.
Artigo em Inglês | MEDLINE | ID: mdl-21141857

RESUMO

Microscopic understanding of thermal behaviors of metal nanoparticles is important for nanoscale catalysis and thermal energy storage applications. However, it is a challenge to obtain a structural interpretation at the atomic level from measured thermodynamic quantities such as heat capacity. Using first-principles molecular dynamics simulations, we reproduce the size-sensitive heat capacities of Al(N) clusters with N around 55, which exhibit several distinctive shapes associated with diverse melting behaviors of the clusters. We reveal a clear correlation of the diverse melting behaviors with cluster core symmetries. For the Al(N) clusters with N = 51-58 and 64, we identify several competing structures with widely different degree of symmetry. The conceptual link between the degree of symmetry (e.g., T(d), D(2d), and C(s)) and solidity of atomic clusters is quantitatively demonstrated through the analysis of the configuration entropy. The size-dependent, diverse melting behaviors of Al clusters originate from the reduced symmetry (T(d) → D(2d) → C(s)) with increasing the cluster size. In particular, the sudden drop of the melting temperature and appearance of the dip at N = 56 are due to the T(d)-to-D(2d) symmetry change, triggered by the surface saturation of the tetrahedral Al(55) with the T(d) symmetry.

16.
J Am Chem Soc ; 132(5): 1510-1, 2010 Feb 10.
Artigo em Inglês | MEDLINE | ID: mdl-20088523

RESUMO

Understanding gas adsorption confined in nanoscale pores is a fundamental issue with broad applications in catalysis and gas storage. Recently, hysteretic H(2) adsorption was observed in several nanoporous metal-organic frameworks (MOFs). Here, using first-principles calculations and simulated adsorption/desorption isotherms, we present a microscopic theory of the enhanced adsorption hysteresis of H(2) molecules using the MOF Co(1,4-benzenedipyrazolate) [Co(BDP)] as a model system. Using activated H(2) diffusion along the small-pore channels as a dominant equilibration process, we demonstrate that the system shows hysteretic H(2) adsorption under changes of external pressure. For a small increase of temperature, the pressure width of the hysteresis, as well as the adsorption/desorption pressure, dramatically increases. The sensitivity of gas adsorption to temperature changes is explained by the simple thermodynamics of the gas reservoir. Detailed analysis of transient adsorption dynamics reveals that the hysteretic H(2) adsorption is an intrinsic adsorption characteristic in the diffusion-controlled small-pore systems.

17.
ACS Nano ; 4(2): 1092-8, 2010 Feb 23.
Artigo em Inglês | MEDLINE | ID: mdl-20055435

RESUMO

A new dynamic melting state, which has both solid and liquid characteristics, is revealed from first-principles molecular dynamics simulations of Al(55) clusters. In thermal fluctuations near the melting point, the low-energy tetrahedral-like Al(55) survives through rapid, collective surface transformations-such as parity conversions and correlated diffusion of two distant vacancies-without losing its structural orders. The emergence of the collective motions is solely due to efficient thermal excitation of soft phonon modes at nanoscale. A series of spontaneous surface reconfigurations result in a mixture or effective flow of surface atoms as is random color shuffling of a Rubik's cube. This novel flexible solid state (termed as half-solidity) provides useful insights into understanding stability, flexibility, and functionality of nanosystems near or below melting temperatures.

18.
Phys Rev Lett ; 105(23): 236105, 2010 Dec 03.
Artigo em Inglês | MEDLINE | ID: mdl-21231485

RESUMO

The experimentally observed enhancement of hydrogen adsorption in Cu2-tetracarboxylate paddle-wheel frameworks is investigated by ab initio density-functional theory calculations. We reveal that the puzzling enhancement is due to the effective orbital coupling between the occupied H2 σ and the unoccupied Cu 4s-derived states. The nontrivial dihydrogen-metal σ-s interaction is enabled by a strong localization of the Cu 4s orbital after hybridizing with the neighboring oxygen 2p orbitals. Based on this understanding, we predict that the dihydrogen-metal interaction can be further increased by alloying Cu with s-orbital element Zn or Mg.

19.
Phys Chem Chem Phys ; 11(48): 11400-3, 2009 Dec 28.
Artigo em Inglês | MEDLINE | ID: mdl-20024409

RESUMO

Porphyrin is a very important component of natural and artificial catalysis and oxygen delivery in blood. Here, we report that, based on first-principles density-functional calculations, a hydrogen molecule can be adsorbed non-dissociatively onto Ti-, V-, and Fe-porphyrins, similar to oxygen adsorption in heme-containing proteins, with a significant energy gain, greater than 0.3 eV per H(2). The dihydrogen-heme complex will be non-magnetic, as is oxyhemoglobin. In contrast to the backward electron donation of Fe(III)-O(2)(-) in oxyhemoglobin, the dihydrogen binding originates from electron donation from H(2) to the Fe(II). We have identified that the local symmetry of the transition metal center of porphyrins uniquely determines the binding strength, and, thus, one can even manipulate the strength by intentionally and systematically breaking symmetry.


Assuntos
Hidrogênio/química , Porfirinas/química , Elementos de Transição/química , Adsorção , Compostos Férricos/química , Modelos Moleculares , Teoria Quântica , Titânio/química , Compostos de Vanádio/química
20.
J Am Chem Soc ; 131(24): 8522-6, 2009 Jun 24.
Artigo em Inglês | MEDLINE | ID: mdl-19473016

RESUMO

It is a challenge to synthesize clusters having a certain shape associated with a desirable property. In this study, we perform density functional calculations on ligand-protected Al(7) and Al(77) clusters. It is found that small ligands such as NH(2) still prefer the compact structure of bare Al clusters. However, large ligands such as N(SiMe(3))(2) stabilize the experimentally observed shell-like structures due to the steric effect. This is different from the Ga(84) cluster case where small ligands can stabilize the experimental shell-like Ga(84) cluster. Our study suggests that the shape, and thus the properties, of clusters (for instance, C(3v) Al(7) cluster has a finite dipole moment in contrast to the centrosymmetric D(3d) cluster) can be controlled by using ligands with different sizes.

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