Micro- and nanocelluloses from non-wood waste sources; processes and use in industrial applications.

In addition to renewability and abundance, nanocellulose materials have tremendous (and variable) properties for different applications, ranging from bulk applications, such as paper and packaging reinforcement, to emerging high added-value applications, such as substrates for optoelectronics. Lignocellulosic biomass from agricultural and industrial waste sources is readily available and shows great promise as an inexpensive and sustainable raw material for nanocellulose production. However, the understanding of the potential of using non-wood based biowaste sources is not established and systematic comparisons of versatile agricultural and industrial waste sources can elucidate this complex topic. Here we present an overview of the most studied and most promising sources from agro-industrial waste, the processes to convert them into nanocellulose, some of the established and emerging applications, and discuss the advancements that are still needed for large-scale production. Sugarcane bagasse and oil palm empty fruit bunch have been the most researched waste-based sources for nanocellulose production and demonstrate the most promise due to availability and access. Industrial sources seem to have advantages over agricultural sources in collectability and ease of access. This work gives insight on the potential and the challenges of nanocellulose production from waste sources and discusses how the criteria set for nanocellulose materials in different applications can be met, thus opening new routes for circular economy.

Co-digestion of manure and industrial waste--The effects of trace element addition.

Manure is one of the most common substrates for biogas production. Manure from dairy- and swine animals are often considered to stabilize the biogas process by contributing nutrients and trace elements needed for the biogas process. In this study two lab-scale reactors were used to evaluate the effects of trace element addition during co-digestion of manure from swine- and dairy animals with industrial waste. The substrate used contained high background concentrations of both cobalt and nickel, which are considered to be the most important trace elements. In the reactor receiving additional trace elements, the volatile fatty acids (VFA) concentration was 89% lower than in the control reactor. The lower VFA concentration contributed to a more digested digestate, and thus lower methane emissions in the subsequent storage. Also, the biogas production rate increased with 24% and the biogas production yield with 10%, both as a result of the additional trace elements at high organic loading rates. All in all, even though 50% of the feedstock consisted of manure, trace element addition resulted in multiple positive effects and a more reliable process with stable and high yield.

Polyketide stereotetrads in natural products.

Natural products (or secondary metabolites) remain as the most important source for discovery of new and potential drug molecules. With high resolution data of their structures, and the advancement of synthesis possibilities, analysis of the natural products based on their specific structural features is valuable to those entering the field. In this tutorial review we attempt such an analysis indicating the salient features of the structural classes with examples of the synthesis of each one of them. As the particular class of natural products, we have chosen polyketides.

An enantioselective synthesis of the C(33)-C(37) fragment of Amphotericin B.

An enantioselective synthesis of the C(33)-C(37) tripropionate fragment of Amphotericin B has been developed in only 6 steps.