1.
Chem Commun (Camb)
; 58(84): 11851-11854, 2022 Oct 20.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36196747
RESUMO
α-Alkylation reactions between amides and alcohols, with dimethylacetamide-stabilized Ru nanoparticles (NPs) as the catalyst, were investigated. The reactions proceeded with low catalyst loadings compared to metal complexes. Characterizations of the Ru NPs were performed by X-ray photoelectron spectroscopy, X-ray absorption fine structure spectroscopy, and various techniques. Control experiments revealed the reaction mechanisms, which proceeded via hydrogen autotransfer with alcohols.