RESUMO
The cyclotriphosphazene-substituted diazoacetate homopolymer (polyPNDA') (PNDA' = hexaphenoxy-substituted phosphazene-containing methylene) and a novel poly(substituted methylene) block copolymer, polyPNDA'-block-poly(hexyloxycarbonylmethylene) (polyPNDA'-b-polyHDA'), were synthesized, and the self-assembly behavior of these polymers was studied in detail. A hexagonally packed aggregated structure was observed in the self-assembled structure of polyPNDA', whereas a lamellar structure was observed in the microphase-separated nanoassembly of polyPNDA'-b-polyHDA'. These results indicate that a hierarchical structure composed of highly regular polyPNDA' nanoaggregates and the long-range microphase-separated polyPNDA' and polyHDA' domains had formed.
