Lead isotopes of prehistoric copper tools define metallurgical phases in Late Neolithic and Eneolithic Italy.

The diffuse presence of small copper ore deposits in the Alpine area, mostly exploited since Late Medieval times, led most scholars to assume that these deposits may actually be active much earlier and that many of the circulating prehistoric metal objects found in the area were produced with local copper sources. This assumption was recently validated for the Recent Bronze Age through the use of lead isotope tracers, and well supported by the archaeometallurgical evidences found in the South-Eastern Alps. However, the scarcity of available lead isotope data for pre-Bronze Age metals precluded to date the reconstruction of the metal flow through the Late Neolithic and Eneolithic (or Copper Age). Based on 49 new analyses of important archaeological objects from the Alpine region, the Po River Valley and Central Italy, mostly axes dated from the Late Neolithic to the Late Eneolithic, here we show that the diffusion of copper in Northern Italy (approximately 4500-2200 BC) includes three major periods of metal use and/or production, each related to specific ore sources. The South Alpine copper was massively used only starting from the middle of the 3rd millennium BC, in connection or slightly earlier than the Beaker event.

The Iceman's lithic toolkit: Raw material, technology, typology and use.

The Tyrolean Iceman, a 5,300-year-old glacier mummy recovered at the Tisenjoch (South Tyrol, Italy) together with his clothes and personal equipment, represents a unique opportunity for prehistoric research. The present work examines the Iceman's tools which are made from chert or are related to chert working - dagger, two arrowheads, endscraper, borer, small flake and antler retoucher - and considers also the arrowhead still embedded in the shoulder of the mummy. The interdisciplinary results achieved by study of the lithic raw material, technology, use-wear analysis, CT analysis and typology all add new information to Ötzi's individual history and his last days, and allow insights into the way of life of Alpine Copper Age communities. The chert raw material of the small assemblage originates from at least three different areas of provenance in the Southalpine region. One, or possibly two, sources derive from outcrops in the Trentino, specifically the Non Valley. Such variability suggests an extensive provisioning network, not at all limited to the Lessini mountains, which was able to reach the local communities. The Iceman's toolkit displays typological characteristics of the Northern Italian tradition, but also comprises features typical of the Swiss Horgen culture, which will come as no surprise in the toolkit of a man who lived in a territory where transalpine contacts would have been of great importance. Ötzi was not a flintknapper, but he was able to resharpen his tools with a medium to good level of skill. Wear traces reveal that he was a right-hander. Most instruments in the toolkit had reached their final stage of usability, displaying extensive usage, mostly from plant working, resharpenings and breaks. Evidently Ötzi had not had any access to chert for quite some time, which must have been problematic during his last hectic days, preventing him from repairing and integrating his weapons, in particular his arrows. Freshly modified blade tools without any wear suggest planned work which he never carried out, possibly prevented by the events which made him return to the mountains where he was killed by a Southern Alpine archer.

Correction: Long-distance connections in the Copper Age: New evidence from the Alpine Iceman's copper axe.

[This corrects the article DOI: 10.1371/journal.pone.0179263.].

Long-distance connections in the Copper Age: New evidence from the Alpine Iceman's copper axe.

25 years after the discovery in the Ötztal Italian Alps, the 5,300-year-old mummy keeps providing key information on human biological and medical conditions, aspects of everyday life and societal organization in the Copper Age. The hand axe found with the body of the Alpine Iceman is one of the rare copper objects that is firmly dated to the early Copper Age because of the radiocarbon dating of the axe wooden shaft. Here we report the measurement of the lead isotope ratios of the copper blade. The results unambiguously indicate that the source of the metal is the ore-rich area of Southern Tuscany, despite ample evidence that Alpine copper ore sources were known and exploited at the time. The experimental results are discussed within the framework of all the available coeval archaeometallurgical data in Central-Southern Europe: they show that the Alps were a neat cultural barrier separating distinct metal circuits. The direct evidence of raw metal or object movement between Central Italy and the Alps is surprising and provides a new perspective on long-distance relocation of goods and relationships between the early Copper Age cultures in the area. The result is in line with the recent investigations re-evaluating the timing and extent of copper production in Central Italy in the 4th millennium BC.