RESUMO
A significant magnetocaloric effect (MCE) has been revealed in our investigation on polycrystalline Nd0.5Dy0.5FeO3 below 30 K. Observed magnetization of the system at low temperature is 32% higher than the expected average magnetization of NdFeO3 and DyFeO3. Such an enhancement in the magnetization led to a large change in magnetic entropy (10.4 Jkg-1 K-1) at 4 K. The observed entropy change is remarkable considering the higher natural abundance of Nd compared to that of Dy and negligible MCE seen in case of NdFeO3. Theoretical calculations performed using mean-field approximation and Monte Carlo simulations on an Ising type spin model indicate that the high magnetocaloric effect is caused primarily by the ordering of rare-earth ions in C-type antiferromagnetic state in presence of molecular exchange field created by Fe ions.
