Multifunctional Graphene Sensor Ensemble as a Smart Biomonitoring Fashion Accessory.

Biomonitoring wearable sensors based on two-dimensional nanomaterials have recently elicited keen research interest and potential for a new range of flexible nanoelectronic devices. Practical nanomaterial-based devices suited for real-world service, which exhibit first-rate performance while being an attractive accessory, are still distant. We report a multifunctional flexible wearable sensor fabricated using an ultrathin percolative layer of graphene nanosheets on laser-patterned gold circular interdigitated electrodes for monitoring vital human physiological parameters. This graphene on laser-patterned electrode (GLE) sensor displays an excellent strain resolution of 245 µÎµ (0.024%) and a record high gauge factor of 6.3 × 107, with exceptional stability and repeatability in its operating range. The sensor was tested for human physiological monitoring like measurement of heart rate, breathing rate, body temperature, and hydration level, which are vital health parameters, especially considering the current pandemic scenario. The sensor also served in applications such as a pedometer, limb movement tracker, and control switch for human interaction. The innovative laser-etch process used to pattern gold thin-film electrodes, with the multifunctional incognizable graphene layer, provides a technique for integrating multiple sensors in a wearable band. The reported work marks a giant leap from the conventional banal devices to a highly marketable multifunctional sensor array as a biomonitoring fashion accessory.

Flexible strain sensor with high sensitivity, fast response, and good sensing range for wearable applications.

Flexible strain sensors are emerging rapidly and overcoming the drawbacks of traditional strain sensors. However, many flexible sensors failed to balance the sensitivity, response time, and the desired sensing range. This work proposes a novel and cost-effective strain sensor which simultaneously achieved high sensitivity, fast response, and a good sensing range. It illustrates a prototype strain sensor realized with a nanocomposite constituting reduced graphene oxide and palladium as the primary sensing elements. These sensors were fabricated with manual screen-printing technology. The sensor exhibited an outstanding performance for the different strains ranging from 0.1% to 45%. As a result, a substantially high gauge factor around 1523 at a strain of as high as 45% and a rapid response time of 47 ms was obtained. This work demonstrated potential applications like real-time monitoring of pulse and respiration, and other physical movement detection, which become crucial parameters to be measured continuously during the COVID-19 pandemic.

Laser-Induced Direct Patterning of Free-standing Ti3C2-MXene Films for Skin Conformal Tattoo Sensors.

The discovery of stable two-dimensional (2D) materials has effectuated a rapid evolution of skin conformal sensors for health monitoring via epidermal electronics. Among the newly discovered 2D materials, MXene stands out as a solution-processable 2D material allowing easy fabrication of highly conductive thin films with the potential to realize flexible skin conformal sensors. Here, we present a successful demonstration of a Ti3C2-MXene resistor as an extremely sensitive strain sensor in the form an ultrathin skin mountable temporary tattoo. The skin conformability and form factor afforded by the sensor promises inconspicuous and continuous monitoring of vital health parameters of an individual, like the pulse rate, respiration rate, and surface electromyography. The sensor serves as a single conduit for sensing the respiration rate and pulse, dispensing with the need of mounting multiple sensors. Its remarkably high sensitivity with a gauge factor of ∼7400 has been ascribed to development of nanocracks and their propagation through the film upon application of strain. The fast response and highly repeatable sensor follows easy fabrication steps and can be patterned into any shape and size using a laser.

Electric Spark Induced Instantaneous and Selective Reduction of Graphene Oxide on Textile for Wearable Electronics.

Reduced graphene oxide (rGO) attracts great popularity as an alternative to pristine graphene because of the facile synthesis process of its precursor, graphene oxide (GO). Electrical conduction of GO is tunable, subject to the extent of reduction of oxygen functional groups in it. This work for the first time demonstrates rapid reduction of GO using spark at ambient conditions. A stream of spark generated by applying high electric potential across two electrodes, when passed through a film of GO deposited on a porous substrate, reduces it into rGO. Upon sparking, the electrical resistance of the GO film drops down by an order of six within a second, making the reduction process instantaneous. X-ray photoelectron spectroscopy and Raman spectra of spark-reduced graphene oxide (SrGO) films revealed a high C/O ratio with an increase in the domain of sp2-hybridized carbon. The electromechanical properties of SrGO were practically examined by testing it as a flex sensor by incorporating its films with commercially available gloves. It showed high sensitivity for bending and good repeatability while offering an easy route for textile integration, making an impactful statement about the potential of sparking as a cost-effective method to reduce GO on a large scale.

Highly sensitive, scalable reduced graphene oxide with palladium nano-composite as strain sensor.

We report a novel strain sensor based on reduced graphene oxide (rGO) with palladium (Pd) nano-composite. The sensor was fabricated on the SS304 stainless-steel substrate using a screen-printing method. Graphene oxide was synthesized using a modified Hummer's method and reduced using a chemical route. Field emission-scanning electron microscope, x-ray diffraction and Raman spectroscopy were used to characterize the as-synthesized nano-composite. The as-fabricated strain sensor was tested for tensile strain using Micro-universal Test Machine and the change in resistance for different strains was recorded. The sensor response was observed to be stable and linear within the applied strain range of 0-3000 microstrains, and an average gauge factor of 42.69 was obtained in this range.

High-range noise immune supersensitive graphene-electrolyte capacitive strain sensor for biomedical applications.

This paper presents development and performance assessment of an innovative and a highly potent graphene-electrolyte capacitive sensor (GECS) based on the supercapacitor model. Although graphene has been widely researched and adapted in supercapacitors as electrode material, this combination has not been applied in sensor technology. A low base capacitance, generally the impeding factor in capacitive sensors, is addressed by incorporating electric double layer capacitance in GECS, and a million-fold increase in base capacitance is achieved. The high base capacitance (∼22.0 µF) promises to solve many inherent issues pertaining to capacitive sensors. GECS is fabricated by using thermally reduced microwave exfoliated graphene oxide material to form interdigitated electrodes coated with solid-state electrolyte which forms the double layer capacitance. The capacitance response of GECS on subjecting to strain is examined and an enormous operating range (∼300 nF) is seen, which is the salient feature of this sensor. The GECS showed an impressive device sensitivity of 11.24 nF kPa-1 and good immunity towards noise i.e. lead capacitance and stray capacitance. Two regimes of operation are identified based on the procedure of device fabrication. The device can be applied to varied applications and one such biomedical application of breath pattern monitoring is demonstrated.