Monitoring river water and sediments within a changing Ethiopian catchment to support sustainable development.

In many sub-Saharan states, despite governments' awareness campaigns highlighting potential impacts of aquatic pollution, there is a very limited action to protect the riverine systems. Managing the quality of water and sediments needs knowledge of pollutants, agreed standards, and relevant policy framework supporting monitoring and regulation. This study reports metal concentrations in rivers in industrializing Ethiopia. The study also highlights policy and capacity gaps in monitoring of river and sediments. For two sampling periods in 2013 and 2014, chromium (Cr), copper (Cu), zinc (Zn), and lead (Pb) were monitored in water and sediments of the Leyole and Worka rivers in the Kombolcha city, Ethiopia. The sampling results were compared with international guidelines and evaluated against the Ethiopian water protection policies. Chromium was high in the Leyole river water (median 2660 µg/L) and sediments (maximum 740 mg/kg), Cu concentrations in the river water was highest at the midstream part of the Leyole river (median 63 µg/L), but maximum sediment content of 417 mg/kg was found further upstream. Zinc was the highest in the upstream part of the Leyole river water (median 521 µg/L) and sediments (maximum 36,600 mg/kg). Pb concentrations were low in both rivers. For the sediments, relatively higher Pb concentrations (maximum 3640 mg/kg) were found in the upstream of the Leyole river. Except for Pb, the concentrations of all metals surpassed the guidelines for aquatic life, human, livestock, and irrigation water supplies. The median concentrations of all metals exceeded guidelines for sediment quality for aquatic organisms. In Ethiopia, poor technical and financial capabilities restrict monitoring of rivers and sediments and understanding on the effects of pollutants. The guidelines used to protect water quality is based on the World Health Organization standards for drinking water quality, but this is not designed for monitoring ecological health. Further development of water quality standards and locally relevant monitoring framework are needed. Development of monitoring protocols and institutional capacities are important to overcome the policy gaps and support the government's ambition in increasing industrialization and agricultural intensification. Failure to do so presents high risks for the public and the river ecosystem.

Correction to: Impacts and Policy Implications of Metals Effluent Discharge into Rivers within Industrial Zones: A Sub-Saharan Perspective from Ethiopia.

The original version of this article unfortunately contained mistakes in the Tables (1 and 2) caption and article title is updated.

Impacts and Policy Implications of Metals Effluent Discharge into Rivers within Industrial Zones: A Sub-Saharan Perspective from Ethiopia.

Kombolcha, a city in Ethiopia, exemplifies the challenges and problems of the sub-Saharan countries where industrialization is growing fast but monitoring resources are poor and information on pollution unknown. This study monitored metals Cr, Cu, Zn, and Pb concentrations in five factories' effluents, and in the effluent mixing zones of two rivers receiving discharges during the rainy seasons of 2013 and 2014. The results indicate that median concentrations of Cr in the tannery effluents and Zn in the steel processing effluents were as high as 26,600 and 155,750 µg/L, respectively, much exceeding both the USEPA and Ethiopian emission guidelines. Cu concentrations were low in all effluents. Pb concentrations were high in the tannery effluent, but did not exceed emission guidelines. As expected, no metal emission guidelines were exceeded for the brewery, textile and meat processing effluents. Median Cr and Zn concentrations in the Leyole river in the effluent mixing zones downstream of the tannery and steel processing plant increased by factors of 52 (2660 compared with 51 µg Cr/L) and 5 (520 compared with 110 µg Zn/L), respectively, compared with stations further upstream. This poses substantial ecological risks downstream. Comparison with emission guidelines indicates poor environmental management by industries and regulating institutions. Despite appropriate legislation, no clear measures have yet been taken to control industrial discharges, with apparent mismatch between environmental enforcement and investment policies. Effluent management, treatment technologies and operational capacity of environmental institutions were identified as key improvement areas to adopt progressive sustainable development.

Trace metal distributions in the sediments of the Little Akaki River, Addis Ababa, Ethiopia.

The levels and distribution of trace metals (Cr, Mn, Co, Ni, Cu, Zn, Cd and Pb) at eleven water and sediment stations on the Little Akaki River (LAR) in Addis Ababa, Ethiopia, were determined. The binding forms of the metals in various geochemical fractions of the sediments were also quantified. The molar ratio of the sum of the simultaneously extractable metals (∑SEM) and acid-volatile sulphide (AVS)-as a measure for predicting metal-induced toxicity-was estimated. LAR trace levels in water for Cu, Zn, and, particularly Mn were, in most instances, higher than the recommended guidelines for healthy aquatic ecosystems. Total trace metal (TTM) contents in the LAR sediments at certain stations exceeded "threshold effect concentrations" and even "probable effect concentrations", especially in the cases of Zn, Cu, Ni, Pb, and at all stations for Mn. This became more apparent after applying "normalizations" to the relatively lower TTM adsorption capacities of coarse-grained, organic-poor sediments. Sequential extraction of the sediments showed that trace metals generally have a higher affinity for Fe-Mn oxide and organic matter/sulphidic fractions, followed by the residual fraction. Mn was relatively strongly bound to the exchangeable, carbonate bound fractions, whereas a large proportion of Cr was found in the residual fraction. The Σ[SEM]/[AVS] ratio pointed to potential metal-induced toxicity of sediments collected from seven out of the eleven stations. The results indicate that trace metal pollution pose risks to the health of ecosystems, and to human communities that use the river for a range of different purposes.

Sediment dynamics in shallow Lake Markermeer, The Netherlands: field/laboratory surveys and first results for a 3-D suspended solids model.

In 2007/08, a study was undertaken on sediment dynamics in shallow Lake Markermeer, The Netherlands. Firstly, the sediment characteristics median grain size, mud content and loss on ignition showed a spatial as well as water depth related pattern indicating wind-induced sediment transport. Sediment dynamics were investigated in a sediment trap field survey at two stations. Sediment yields, virtually all coming from sediment resuspension, were significantly correlated with wind speeds. Resuspension rates for Lake Markermeer were very high, viz. ca. 1,000 g/m(2)day as an annual average, leading to high suspended solids (SS) contents, due to the large lake area and its shallowness (high 'Dynamic Ratio'). Sediment resuspension behaviour was further investigated in preliminary laboratory experiments using a 'micro-flume', applying increasing water currents onto five Lake Markermeer sediments. Resuspension showed a clear exponential behaviour. Finally, a 3-D model was set up for water quality and SS contents in Lake Markermeer; first results showed a good agreement between modelled and actual SS contents. Construction of artificial islands and dams will reduce wind fetches and may be expected to cause a substantial decrease in lake water turbidity.

Phosphorus budget in the low-income, peri-urban area of Kibera in Nairobi (Kenya).

Kibera, located in Nairobi, Kenya is one of the largest (235,000 inhabitants) low-income areas in East Africa. Surface waters in Kibera show high pollution levels with respect to SRP (soluble reactive phosphorus; range: 2-10 mg P/L), coming from the uncontrolled wastewater discharges in the area. The different P production and consumption values in Kibera were estimated using interviews (155 interviewed) as well as detailed P house-keeping for five representative families. The results show that highest P consumption comes from food, in particular cereals. Highest P production came from urine (55% of the total) and faeces (31%), with relatively lower contributions from grey water and solid wastes. The overall P budget in Kibera amounted to around 9 x 10(3) kg P/month. This is equivalent to 0.47 g P/person yr, both for P production and consumption, with a relative error of 20%. Comparing with the estimated P outflows via the Kibera surface waters, around 65% of the P produced in Kibera will leave the area. In future ECOSAN techniques such as urine separation could well be applied for efficient recycling of these waste sources.

Effect of redox potential on heavy metal binding forms in polluted canal sediments in Delft (The Netherlands).

Heavy metal binding forms for Cu, Zn and Pb were determined at four representative sediment sites in the canals of Delft (The Netherlands), using selective chemical extraction methods. Small differences (on average <5%) were found between duplicate extraction experiments. The dominant Cu binding form was always related to sulphide and organics in the sediment. Zn was mainly bound to iron+manganese (hydr)oxides, whereas Pb was rather evenly distributed over the different labile and non-labile binding fractions. A gradual (over about 1 month) increase in redox potentials of the anaerobic sediments led to a 7-37% sediment release of the above heavy metals; this could mainly be ascribed to oxidation of the heavy metal-sulphide bindings. Part of the released heavy metals was re-adsorbed by the labile binding phases ("exchangeable" and "carbonate bound"). Contrary to expectations, we found a decrease rather than an increase in the Fe+Mn (hydr)oxide binding forms. This can probably be ascribed to non-equilibrium reactions in the time span of the experiments, as well as side reactions such as complexation with humic acids and hindered precipitation reactions due to organic matter coatings.

Water quality assessment of rivers in Mongolia.

A study was made on the water quality of the rivers in Mongolia over the years 1949-1990 for the three river basins in the country. In most of the 72 monitoring stations, the water quality is governed by geological and hydrological characteristics; bicarbonate and calcium are the most abundant major ions. No significant trends were observed between river discharges and total dissolved solids contents. The sediment yields (expressed in the run-off of total suspended solids, TSS) were always low, viz. between 0.02 and 20 x 10(3) kg TSS/km2 yr. In general, the rivers in Mongolia showed low pollution levels for organic pollution, phosphorus, nitrogen, etc., and no time trends were observed in this respect. This does not hold, however, for the northern Tul River, where especially high BOD and ammonium values were found. This can probably be ascribed to the presence of industries and larger cities, as well as agricultural practices. The rivers in Mongolia can generally be classified as "clean" or "of acceptable quality". In contrast, the Tuul River was shown to be "moderately polluted", with a deteriorating trend in water quality over recent years.

The river Rhine as a source of micropollutants in the canal sediments of the city of Delft (The Netherlands).

This paper presents a statistical analysis of the pollution levels for heavy metals and organic micropollutants at 182 sediment stations in the city canals of Delft. High pollution levels were especially observed in the inner city canal sediments, probably related to the import of polluted river Rhine water. In contrast, the more-or-less isolated outer city sites were generally much less polluted. Regression analysis on the database generally showed highly significant correlations between individual heavy metal contents. The heavy metal contents were usually significantly correlated with polycyclic aromatic hydrocarbons (PAHs) as well. This points to one or more common sources for these micropollutants. Factor analysis and the K-means cluster analysis technique were applied on the above database; it showed a large cluster of stations, nearly all located in the outer city of Delft, characterized by relatively low heavy metal and organic micropollutants' contents. Another cluster of 18 stations, mostly located in the inner city of Delft, possessed intermediate pollution levels, directly related with the supply of river Rhine water. Finally, the stations of a third cluster, situated in the inner city as well, were highly polluted, especially by local pollution sources. The above hypotheses were further supported by a more detailed statistical analysis for a number of inner city stations, together with 10-year river Rhine pollution data.

Heavy metal contents in the Delft canal sediments and suspended solids of the River Rhine: multivariate analysis for source tracing.

We have analyzed heavy metal contents in the sediments of three Delft inner city canals (Rietveld, Oude Delft and Zuiderstraat) and compared them with the heavy metal contents in the River Rhine suspended solids. All the data were examined by multivariate analysis in order to explain the behavior and sources of each metal. Correlation coefficient matrices were studied in order to find an internal structure and assist in identification of pollutant sources. The good correlation among almost all the heavy metals (except Pb) indicates that there are common sources or at least one major source for them. Based on the factor analysis technique, principal components score plots were obtained to cluster the data (63 samples from the Delft canals and 10 from the River Rhine) and describe their different characteristics. It was found in the plots that the data from the River Rhine clustered together with 2 out of the 3 Delft stations (Rietveld, Oude Delft). This supports the view that the River Rhine is an important external micropollutant source for the Delft inner city canals. The third station (Zuiderstraat) showed much higher pollution levels than the other Delft canals; apparently it has been influenced not only by the River Rhine but also by internal pollutant inputs such as metal corrosion and paints from local boathouses.