1.
Dalton Trans
; 45(45): 18259-18266, 2016 Nov 15.
Artigo
em Inglês
| MEDLINE
| ID: mdl-27801456
RESUMO
Hydride attack at a ferric heme-NO to give an Fe-HNO intermediate is a key step in the global N-cycle. We demonstrate differential reactivity when six- and five-coordinate ferric heme-NO models react with hydride. Although Fe-HNO formation is thermodynamically favored from this reaction, Fe-H formation is kinetically favored for the 5C case.