Effect of Frequency and Ratio of Wet/Dry Stages in Cyclic Corrosion Tests on Localized Corrosion of Complex-Phase High-Strength Steel.

This study delves into the atmospheric corrosion behavior of chromium-free complex-phase (CP) steel, specifically investigating the influence of wet/dry frequency and ratio in cyclic corrosion tests (CCT). The study employs a modified ISO 14993 standard CCT method, which involves salt spray, dry, and wet stages. After 15 and 30 CCT cycles, mass loss, maximum corrosion depth, and corrosion products were analyzed to gain insights into corrosion mechanisms. In general, increasing the frequency and wet/dry stage ratio in CCT extends the time for autocatalytic reactions to occur, leading to accelerated localized CP steel corrosion and increased pitting factors. However, as the rust layer thickens, uniform corrosion may also intensify, so careful considerations are necessary. This study underscores the importance of controlling the frequency and ratio of wet/dry stages in CCT for effectively analyzing localized corrosion behavior in specimens.

Microstructure and Corrosion Behavior of Laser-Welded Al-Mn-Zr Alloy for Heat Exchanger.

In this study, an Al-Mn-Zr alloy was designed and its microstructure and corrosion behavior compared after laser welding to that of AA3003. As the results of immersion and electrochemical tests showed, both alloys had a faster corrosion rate in the fusion zone than in the base metal. Laser welding caused interdendritic segregation, and spread the intermetallic compounds (IMCs) evenly throughout in the fusion zone. This increased the micro-galvanic corrosion sites and destabilized the passive film, thus increasing the corrosion rate of the fusion zone. However, Zr in the Al-Mn alloy reduced the size and number of IMCs, and minimized the micro-galvanic corrosion effect. Consequently, Al-Mn-Zr alloy has higher corrosion resistance than AA3003 even after laser welding.

New Accelerated Corrosion Test Method Simulating Atmospheric Corrosion of Complex Phase Steel Combining Cyclic Corrosion Test and Electrochemically Accelerated Corrosion Test.

The automobile industry commonly uses cyclic corrosion tests (CCTs) to evaluate the durability of materials. However, the extended evaluation period required by CCTs can pose challenges in this fast-paced industry. To address this issue, a new approach that combines a CCT with an electrochemically accelerated corrosion test has been explored, to shorten the evaluation period. This method involves the formation of a corrosion product layer through a CCT, which leads to localized corrosion, followed by applying an electrochemically accelerated corrosion test using an agar gel electrolyte to preserve the corrosion product layer as much as possible. The results indicate that this approach can achieve comparable localized corrosion resistance, with similar localized corrosion area ratios and maximum localized corrosion depths to those obtained through a conventional CCT in half the time.

Derivation of Corrosion Depth Formula According to Corrosion Factors in District Heating Water through Regression Analysis.

In order to predict the corrosion depth of a district heating pipeline, it is necessary to analyze various corrosion factors. In this study, the relationship between corrosion factors such as pH, dissolved oxygen, and operating time and corrosion depth was investigated using the Box-Behnken method within the response surface methodology. To accelerate the corrosion process, galvanostatic tests were conducted in synthetic district heating water. Subsequently, a multiple regression analysis was performed using the measured corrosion depth to derive a formula for predicting the corrosion depth as a function of the corrosion factors. As a result, the following regression formula was derived for predicting the corrosion depth: "corrosion depth (µm) = -133 + 17.1 pH + 0.00072 DO + 125.2 Time - 7.95 pH × Time + 0.002921 DO × Time".

Effect of Sulfide and Chloride Ions on Pitting Corrosion of Type 316 Austenitic Stainless Steel in Groundwater Conditions Using Response Surface Methodology.

This study investigates the corrosion resistance of Type 316 stainless steel as a candidate material for radioactive waste disposal canisters. The viability of stainless steel is examined under groundwater conditions with variations in pH, bisulfide ions (HS-), and chloride ions (Cl-) concentrations. Utilizing response surface methodology, correlations between corrosion factors and two crucial response variables, passive film breakdown potential and protection potential, are established. Cyclic potentiodynamic polarization tests and advanced analytical techniques provide detailed insights into the material's behavior. This research goes beyond, deriving an equation through response surface methodology that elucidates the relationship between the factors and breakdown potential. HS- weakens the passive film and reduces the pitting corrosion resistance of the stainless steel. However, this study highlights the inhibitory effect of HS- on pitting corrosion when Cl- concentrations are below 0.001 M and at equivalent concentrations of HS-. Under these conditions, immediate re-passivation occurs from the destroyed passive film to metal sulfides such as FeS2, MoS2, and MoS3. As a result, no hysteresis loop occurs in the cyclic polarization curve in these conditions. This research contributes to the understanding of Type 316 stainless-steel corrosion behavior, offering implications for the disposal of radioactive waste in geological repositories.

Effect of benzotriazole on the existing pits of copper tube in fire sprinkler system.

In this paper, two leaking tubes were investigated among copper tubes injected with 200 and 400 ppm benzotriazole after 8 years of usage. The electrochemical tests were conducted in simulated pit-out and pit-in environments (i.e., regions outside and inside of the pit) to determine the effect of benzotriazole on the propagation of an existing pit. The electrochemical analysis results showed that 200 and 400 ppm benzotriazole exhibit relatively lower inhibition efficiency in an acidic simulated pit-in environment because of the difficulty of forming a protective film and the benzotriazole cationization.

Machine learning modeling of predictive external corrosion rates of spent nuclear fuel carbon steel canister in soil.

Soil corrosion is always a critical concern to corrosion engineering because of the economic influence of soil infrastructures as has been and has recently been the focus of spent nuclear fuel canisters. Besides corrosion protection, the corrosion prediction of the canister is also important. Advanced knowledge of the corrosion rate of spent nuclear fuel canister material in a particular environment can be extremely helpful in choosing the best protection method. Applying machine learning (ML) to corrosion rate prediction solves all the challenges because of the number of variables affecting soil corrosion. In this study, several algorithms of ML, including series individual, boosting, bagging artificial neural network (ANN), series individual, boosting, bagging Chi-squared automatic interaction detection (CHAID) tree decision, linear regression (LR) and an ensemble learning (EL) merge the best option that collects from 3 algorithm methods above. From the performance of each model to find the model with the highest accuracy is the ensemble stacking method. Mean absolute error performance matrices are shown in Fig. 15. Besides applying ML, the significance of the input variables was also determined through sensitivity analysis using the feature importance criterion, and the carbon steel corrosion rate is the most sensitive to temperature and chloride.

Synthesis and Corrosion Inhibition Potential of Cerium/Tetraethylenepentamine Dithiocarbamate Complex on AA2024-T3 in 3.5% NaCl.

In this work, a cerium/tetraethylenepentamine dithiocarbamate complex was synthesized and evaluated for the corrosion inhibition capability on an AA2024-T3 Al alloy in a 3.5% NaCl medium. The synthesized compounds were characterized via spectroscopic techniques. The corrosion inhibition behaviour of the complex was elucidated by electrochemical measurements and surface analysis techniques. Based on electrochemical test results, the corrosion inhibition efficiency of the complex increases with the immersion time of aluminium alloy in the test solution. The corrosion inhibition reaches 96.80% when the aluminium is immersed in a 3.5% NaCl solution containing a corrosion inhibitor for 120 h. The potentiodynamic polarization test results show that the complex acts as a mixed-type corrosion inhibitor and the passive range is widened. The surface analysis methods reveal that the corrosion inhibition ability of the complex originated from the formation of a protective layer on the Al surface. This film is created from the physisorption and chemisorption of cerium ions and organic parts simultaneously released from the complex molecules.

Comparison of Hydrogen Embrittlement Susceptibility of Different Types of Advanced High-Strength Steels.

This study investigated the hydrogen embrittlement (HE) characteristics of advanced high-strength steels (AHSSs). Two different types of AHSSs with a tensile strength of 1.2 GPa were investigated. Slow strain rate tests (SSRTs) were performed under various applied potentials (Eapp) to identify the mechanism with the greatest effect on the embrittlement of the specimens. The SSRT results revealed that, as the Eapp increased, the elongation tended to increase, even when a potential exceeding the corrosion potential was applied. Both types of AHSSs exhibited embrittled fracture behavior that was dominated by HE. The fractured SSRT specimens were subjected to a thermal desorption spectroscopy analysis, revealing that diffusible hydrogen was trapped mainly at the grain boundaries and dislocations (i.e., reversible hydrogen-trapping sites). The micro-analysis results revealed that the poor HE resistance of the specimens was attributed to the more reversible hydrogen-trapping sites.

Localized Corrosion Occurrence in Low-Carbon Steel Pipe Caused by Microstructural Inhomogeneity.

In this study, the cause of failure of a low-carbon steel pipe meeting standard KS D 3562 (ASTM A135), in a district heating system was investigated. After 6 years of operation, the pipe failed prematurely due to pitting corrosion, which occurred both inside and outside of the pipe. Pitting corrosion occurred more prominently outside the pipe than inside, where water quality is controlled. The analysis indicated that the pipe failure occurred due to aluminum inclusions and the presence of a pearlite inhomogeneous phase fraction. Crevice corrosion occurred in the vicinity around the aluminum inclusions, causing localized corrosion. In the large pearlite fraction region, cementite in the pearlite acted as a cathode to promote dissolution of surrounding ferrite. Therefore, in the groundwater environment outside of the pipe, localized corrosion occurred due to crevice corrosion by aluminum inclusions, and localized corrosion was accelerated by the large fraction of pearlite around the aluminum inclusions, leading to pipe failure.

Electroplated core-shell nanowire network electrodes for highly efficient organic light-emitting diodes.

In this study, we performed metal (Ag, Ni, Cu, or Pd) electroplating of core-shell metallic Ag nanowire (AgNW) networks intended for use as the anode electrode in organic light-emitting diodes (OLEDs) to modify the work function (WF) and conductivity of the AgNW networks. This low-cost and facile electroplating method enabled the precise deposition of metal onto the AgNW surface and at the nanowire (NW) junctions. AgNWs coated onto a transparent glass substrate were immersed in four different metal electroplating baths: those containing AgNO3 for Ag electroplating, NiSO4 for Ni electroplating, Cu2P2O7 for Cu electroplating, and PdCl2 for Pd electroplating. The solvated metal ions (Ag+, Ni2+, Cu2+, and Pd2+) in the respective electroplating baths were reduced to the corresponding metals on the AgNW surface in the galvanostatic mode under a constant electric current achieved by linear sweep voltammetry via an external circuit between the AgNW networks (cathode) and a Pt mesh (anode). The amount of electroplated metal was systematically controlled by varying the electroplating time. Scanning electron microscopy images showed that the four different metals (shells) were successfully electroplated on the AgNWs (core), and the nanosize-controlled electroplating process produced metal NWs with varying diameters, conductivities, optical transmittances, and WFs. The metal-electroplated AgNWs were successfully employed as the anode electrodes of the OLEDs. This facile and low-cost method of metal electroplating of AgNWs to increase their WFs and conductivities is a promising development for the fabrication of next-generation OLEDs.

Method for Mitigating Stray Current Corrosion in Buried Pipelines Using Calcareous Deposits.

Stray current corrosion in buried pipelines can cause serious material damage in a short period of time. However, the available methods for mitigating stray current corrosion are still insufficient. In this study, as a countermeasure against stray current corrosion, calcareous depositions were applied to reduce the total amount of current flowing into pipelines and to prevent corrosion. This study examined the reduction of stray current corrosion via the formation of calcareous deposit layers, composed of Ca, Mg, and mixed Ca and Mg, at the current inflow area. To verify the deposited layers, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD) were performed. The electrochemical tests revealed that all three types of calcareous deposits were able to effectively act as current barriers, and that they decreased the inflow current at the cathodic site. Among the deposits, the CaCO3 layer mitigated the stray current most effectively, as it was not affected by Mg(OH)2, which interferes with the growth of CaCO3. The calcium-based layer was very thick and dense, and it effectively blocked the inflowing stray current, compared with the other layers.

Evaluation of the Influence of the Combination of pH, Chloride, and Sulfate on the Corrosion Behavior of Pipeline Steel in Soil Using Response Surface Methodology.

External damage to buried pipelines is mainly caused by corrosive components in soil solution. The reality that numerous agents are present in the corrosive environment simultaneously makes it troublesome to study. To solve that issue, this study aims to determine the influence of the combination of pH, chloride, and sulfate by using a statistical method according to the design of experiment (DOE). Response surface methodology (RSM) using the Box-Behnken design (BBD) was selected and applied to the design matrix for those three factors. The input corrosion current density was evaluated by electrochemical tests under variable conditions given in the design matrix. The output of this method is an equation that calculates the corrosion current density as a function of pH, chloride, and sulfate concentration. The level of influence of each factor on the corrosion current density was investigated and response surface plots, contour plots of each factor were created in this study.

Spent Coffee Grounds as Eco-Friendly Additives for Aluminum-Air Batteries.

A new approach to the recycling of spent coffee grounds is described in which lignin, a chemical component of spent coffee, is used as an electrolyte additive in aluminum-air batteries. The effect of lignin on the performance of aluminum-air batteries has been investigated by weight loss measurement, galvanostatic discharge test, and electrochemical impedance spectroscopy (EIS). The corrosion inhibition efficiency is improved up to 37.3% and fuel efficiency up to 21.7% at 500 ppm of lignin molecules. The chemisorption of lignin molecules on the aluminum surface improves battery performance. Adsorption of lignin molecules onto the aluminum surface is driven by the electrostatic interaction between the lignin's hydroxyl group and the aluminum surface. The mechanism for the performance improvement is explained by the chemisorption behavior of lignin molecules. The adsorption behavior has been investigated by scanning electronic microscopy with energy-dispersive spectroscopy (SEM-EDS), laser scanning microscopy (LSM), atomic force microscopy (AFM), Freundlich adsorption isotherm, Fourier-transform infrared (FT-IR) spectroscopy, and the computational calculation of adsorption energies based on the density functional theory (DFT).

Effect of Imidazole as Corrosion Inhibitor on Carbon Steel Weldment in District Heating Water.

Many research studies have been conducted on the corrosion inhibition performance of imidazole in acidic environments such as in the piping of a petrochemical plant. However, there has been no study on the effect of imidazole in alkaline conditions such as a local district water heating environment. Therefore, in this study, the effect of imidazole as a corrosion inhibitor on carbon steel weldment was investigated in alkaline district heating water. Inhibition efficiency and electrochemical properties were investigated by potentiodynamic polarization test and electrochemical impedance spectroscopy. As the concentration of imidazole increased up to 500 ppm, inhibition efficiency increased up to 91.7%. At 1000 ppm, inhibition efficiency decreased. Atomic force microscopy showed that surface coverage of imidazole at 1000 ppm is lower than that of imidazole at 500 ppm. X-ray photoelectron spectroscopy showed that with 500 ppm of imidazole, the amount of pyrrole type interaction is 4.8 times larger than pyridine type interaction. At 1000 ppm of imidazole, the amount of pyridine type interaction is 3.49 times larger than pyrrole type interaction. Depending on the concentration of imidazole, the ratio of interaction between carbon steel and imidazole affected inhibition efficiency.

Effect of Benzotriazole on the Localized Corrosion of Copper Covered with Carbonaceous Residue.

Carbonaceous residues on copper pipes during the manufacturing process are known to be one of the main causes of pitting corrosion on copper pipes. This study examined the corrosion-inhibiting effect of benzotriazole (BTA) on C12200 copper pipes with carbonaceous film in synthetic tap water. In the absence of BTA, localized corrosion mechanisms due to galvanic corrosion, crevice corrosion, and oxygen-concentration cell were proposed in the boundary part of the carbonaceous film on the copper through X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) with energy dispersive spectrometer (EDS) analyses. Electrochemical tests showed that BTA inhibits corrosion by forming Cu-BTA complexes on all over the copper surface where carbonaceous film is present. BTA mitigates galvanic corrosion and crevice corrosion at the boundary of the carbonaceous film and suppresses the formation of oxygen-concentration cells through the formation of a Cu-BTA complex.

Effect of Cr on Aqueous and Atmospheric Corrosion of Automotive Carbon Steel.

This study investigated the effect of Cr alloying element on the corrosion properties of automotive carbon steel (0.1C, 0.5Si, 2.5Mn, Fe Bal., composition given in wt.%) in aqueous and atmospheric conditions using electrochemical measurement and cyclic corrosion tests. Three steels with 0, 0.3, and 0.5 wt.% Cr were studied by electrochemical impedance spectroscopy. Polarization resistance (Rp) of 0.3 Cr and 0.5 Cr steels was higher than that of 0 Cr steel, and the Rp also increased as the Cr content increased. Therefore, Cr increases the corrosion resistance of automotive carbon steel immersed in a chloride ion (Cl-)-containing aqueous solution. In the cyclic corrosion test results, Cl- was concentrated at the metal/rust interface in all of the steels regardless of Cr content. The Cl- was uniformly concentrated and distributed on the 0 Cr steel, but locally and non-uniformly concentrated on the Cr-added steels. The inner rust layer consisted of ß-FeOOH containing Cl- and Cr-goethite, while the outer rust layer was composed of amorphous iron oxyhydroxide mixed with various types of rust. FeCl2 and CrCl3 are formed from the Cl- nest developed in the early stage, and the pitting at CrCl3-formed regions are locally accelerated because Cr is strongly hydrolyzed to a very low pH.

Highly Sensitive Electrochemical Aptasensor for Detecting the VEGF165 Tumor Marker with PANI/CNT Nanocomposites.

Sensing targeted tumor markers with high sensitivity provides vital information for the fast diagnosis and treatment of cancer patients. A vascular endothelial growth factor (VEGF165) have recently emerged as a promising biomarker of tumor cells. The electrochemical aptasensor is a promising tool for detecting VEGF165 because of its advantages such as a low cost and quantitative analysis. To produce a sensitive and stable sensor electrode, nanocomposites based on polyaniline (PANI) and carbon nanotube (CNT) have potential, as they provide for easy fabrication, simple synthesis, have a large surface area, and are suitable in biological environments. Here, a label-free electrochemical aptasensor based on nanocomposites of CNT and PANI was prepared for detecting VEGF165 as a tumor marker. The nanocomposite was assembled with immobilized VEGF165 aptamer as a highly sensitive VEGF165 sensor. It exhibited stable and wide linear detection ranges from 0.5 pg/mL to 1 µg/mL, with a limit of detection of 0.4 pg/mL because of the complementary effect of PANI/CNT. The fabricated aptasensor also exhibited good stability in biological conditions, selectivity, and reproducibility after several measurement times after the dissociation process. Thus, it could be applied for the non-invasive determination of VEGF, in biological fluid diagnosis kits, or in an aptamer-based biosensor platform in the near future.

Calibrating the Impressed Anodic Current Density for Accelerated Galvanostatic Testing to Simulate the Long-Term Corrosion Behavior of Buried Pipeline.

Various studies have been conducted to better understand the long-term corrosion mechanism for steels in a soil environment. Here, electrochemical acceleration methods present the most efficient way to simulate long-term corrosion. Among the various methods, galvanostatic testing allows for accelerating the surface corrosion reactions through controlling the impressed anodic current density. However, a large deviation from the equilibrium state can induce different corrosion mechanisms to those in actual service. Therefore, applying a suitable anodic current density is important for shortening the test times and maintaining the stable dissolution of steel. In this paper, to calibrate the anodic current density, galvanostatic tests were performed at four different levels of anodic current density and time to accelerate a one-year corrosion reaction of pipeline steel. To validate the appropriate anodic current density, analysis of the potential vs. time curves, thermodynamic analysis, and analysis of the specimen's cross-sections and products were conducted using a validation algorithm. The results indicated that 0.96 mA/cm2 was the optimal impressed anodic current density in terms of a suitable polarized potential, uniform corrosion, and a valid corrosion product among the evaluated conditions.

Optimizing the Required Cathodic Protection Current for Pre-Buried Pipelines Using Electrochemical Acceleration Methods.

Several corrosion mitigation methods are generally applied to pipelines exposed to corrosive environments. However, in the case of pre-buried pipelines, the only option for corrosion inhibition is cathodic protection (CP). To apply CP, the required current should be defined even though the pipeline is covered with various oxide layers. In this study, an electrochemical acceleration test was used to investigate the synthetic soil corrosion of a pre-buried pipeline. Potentiodynamic polarization experiments were first conducted to ascertain the corrosion current density in the environment, and galvanostatic measurements were performed to accelerate corrosion according to the operating time. In addition, corrosion current density and the properties of the rust layer were investigated via potentiodynamic polarization tests and electrochemical impedance spectroscopy (EIS) tests. The variation in surface corrosion was subsequently analyzed via optical microscopy (OM) and X-ray diffraction (XRD) measurements. Finally, an empirical equation for the optimized CP current requirement, according to the pipeline service time, was derived. This equation can be applied to any corroded pipeline.