RESUMO
CeIn3, a prototypical antiferromagnet, is an ideal candidate for investigating the relationship between magnetism and superconductivity, as superconductivity is induced as the magnetic transition temperature (T N) is lowered to 0 K by applying pressure. When La is substituted for Ce, T N of CeIn3 decreases to 0 K owing to the Ce dilution effects, thereby providing an alternative route to the zero-temperature quantum phase transition. In this study, we report a combinatorial approach to gain access to the critical point by applying external pressure to 20% La-doped CeIn3. Electrical resistivity measurements of La0.2Ce0.8In3 show that the T N of 8.4 K at 1 bar is gradually suppressed under pressure and can be extrapolated to 0 K at approximately 2.47 GPa, thereby showing a similar pressure dependence of T N as shown by undoped CeIn3. The kink-like feature in resistivity at T N of CeIn3 changed to an obvious jump in the doped compound for pressures higher than 1.64 GPa, indicating depletion in the carrier density due to a gap opening. AC calorimetry measurements under applied pressure show that the size of the specific heat jump at T N decreases with increasing pressure, but any signatures associated with the gap opening are not obvious, suggesting that the pressure-induced kink-to-jump change at T N in the resistivity is not a phase transition, but rather a gradual crossover. The low-temperature specific heat divided by temperature, C/T, does not strongly diverge with decreasing temperature, but is almost saturated near the projected quantum critical point, which can be attributed to a weak enhancement in the effective mass up to 2.6 GPa.
RESUMO
The determination of palladium(II) complexed with alpha-(2-benzimidazolyl)-alpha',alpha''-(N-5-nitro-2-pyridylhydrazone)-Toluene (BINPHT) was investigated by adsorptive cathodic stripping voltammetry using hanging mercury drop electrode. Palladium(II) in the sample solution can be determined in BINPHT and ethylenediaminetetraacetic acid (EDTA). Accumulation is achieved by adsorption of Pd(II)-BINPHT complex on a hanging mercury drop electrode. Optimal conditions were found to be: supporting electrolyte; 0.01 M sodium acetate buffer at pH 5.0, accumulation potential; -590 mV versus Ag/AgCl, accumulation time; 180 s, scan rate; 50 mV s(-1), concentration of BINPHT; 2x10(-5) M. The linear range of Pd(II) was observed over the concentration range 20-100 ng ml(-1) The detection limit (S/N=3) is 2 ng ml(-1). A good reproductivity shows RSD of 2.0% (n=7). This procedure offers high selectivity with the presence of EDTA masking some metallic ions. River water sample spiking with palladium was determined.
