1.
ACS Catal
; 12(17): 10841-10848, 2022 Sep 02.
Artigo
em Inglês
| MEDLINE
| ID: mdl-37274599
RESUMO
The synthesis and evaluation of six C4-symmetric bowl-shaped dirhodium tetracarboxylate catalysts are described. These elaborate high symmetry catalysts are readily generated by means of the self-assembly of four C1-symmetric ligands around the dirhodium core. These catalysts are capable of highly site-selective, diastereoselective and enantioselective C-H functionalization reactions by means of donor/acceptor carbene-induced C-H insertions.