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1.
Bioprocess Biosyst Eng ; 46(3): 309-321, 2023 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-35301580

RESUMO

Microplastics (MPs) in environmental studies have revealed that public sewage treatment plants are a common pathway for microplastics to reach local surroundings. Microplastics are becoming more of a worry, posing a danger to both marine wildlife and humans. These plastic items not only contribute to the macrocosmic proliferation of plastics but also the scattering of microplastics and the concentration of other micropollutant-containing objects, increasing the number of pollutants identified. Microplastics' behavior, movement, transformation, and persistence mechanisms, as well as their mode of action in various wastewater effluent treatment procedures, are still unknown. They are making microplastics made from wastewater a big deal. We know that microplastics enter wastewater treatment facilities (WWTPs), that wastewater is released into the atmosphere, and that this wastewater has been considered to represent a threat to habitats and ground character based on our literature assessment. The basic methods of wastewater and sewage sludge, as well as the treatment procedure and early characterization, are covered throughout the dissection of the problematic scientific conceptualization.


Assuntos
Águas Residuárias , Poluentes Químicos da Água , Humanos , Microplásticos , Plásticos , Esgotos , Poluentes Químicos da Água/análise , Monitoramento Ambiental , Eliminação de Resíduos Líquidos
2.
Chemosphere ; 308(Pt 3): 136471, 2022 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-36126738

RESUMO

This article discusses the unique properties and performance of carbon-based molecularly-imprinted polymers (MIPs) for detecting hazardous pollutants in aqueous solutions. Although MIPs have several advantages such as specific recognition sites, selectivity, and stability, they suffer from a series of drawbacks, including loss of conductivity, electrocatalytic activity, and cost, which limit their use in various fields. Carbon-based MIPs, which utilize carbon electrodes, carbon nanoparticles, carbon dots, carbon nanotubes, and graphene substrates, have been the focus of research in recent years to enhance their properties and remove their weaknesses as much as possible. These carbon-based nanomaterials have excellent sensitivity and specificity for molecular identification. As a result, they have been widely used in various applications, such as assessing the environmental, biological, and food samples. This article examines the growth of carbon-based MIPs and their environmental applications.


Assuntos
Poluentes Ambientais , Grafite , Impressão Molecular , Nanotubos de Carbono , Grafite/química , Polímeros Molecularmente Impressos , Nanotubos de Carbono/química , Polímeros/química , Água
3.
Environ Res ; 214(Pt 3): 113993, 2022 11.
Artigo em Inglês | MEDLINE | ID: mdl-35944623

RESUMO

This work investigates the electrochemical oxidation of palm oil mill effluent (POME) treatment using platinum (Pt) as anode and graphite as a cathode. The response surface methodology was used to investigate the relationships between different factors conditions (voltage, electrolysis time and chemical support) and responses of the treatment (chemical oxygen demand reduction, colour removal, and total oil removal). A quadratic mathematical model was chosen for all responses using Box-Behnken Design (BBD) with R2 0.9853 for COD reduction, R2 0.9478 for colour removal and R2 0.9185 for total oil removal. According to Derringer's function desirability, under the optimum condition (Voltage 15, electrolysis time 2 h, and 19.95 mg/L NaCl) of POME treatment, 84% of COD reduction, 98% of colour removal and 99% total oil of removal could be achieved. These results indicate that platinum as an anode material is effective for the electrochemical oxidation treatment of POME.


Assuntos
Eliminação de Resíduos Líquidos , Poluentes Químicos da Água , Análise da Demanda Biológica de Oxigênio , Eletrodos , Resíduos Industriais/análise , Óleo de Palmeira , Platina , Eliminação de Resíduos Líquidos/métodos , Poluentes Químicos da Água/análise
4.
Chemosphere ; 303(Pt 1): 134957, 2022 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-35588885

RESUMO

Biochar is a black carbon sorbent that has the ability to stabilize organic substances in soil and, therefore, the potential to reduce their bio-availability. This sustainable material can be produced from locally-available agro wastes. The present study, for the first time, investigated the effects of biochars produced from oil palm empty fruit bunches (EFB) and rice husk (RH) on the efficiency of imazapic and imazapyr (two polar members of imidazolinone herbicides) as well as Onduty®, a mixture of them. It was executed in a Malaysian paddy field soil during a 30-day greenhouse experiment. The presence of optimized EFB and RH biochars in the heavy soil generally increases weed seeds germination and plants growth due to stabilization of the herbicides. The effect of EFB biochar was found higher than RH biochar having a higher affinity to the herbicides. An increase in the biochars application rates enhanced their effects as a soil modifier. Differences were more significant in the higher herbicides doses. Efficacies of all the herbicides were generally decreased in the biochar-amended soils. In the presence of 0.5% biochar in soil, the GR50 values for all herbicides were almost similar to biochar-free soil. In a 1.0% biochar-soil mixture, GR50 values of the herbicides increased by about 1.5 times. Bio-efficacies of the herbicides decreased by around 2.0 times as the biochar application rate enhanced to 2.0%. The greatest GR50 values were obtained in the presence of 4.0% biochar in the soils and were about 7.0-8.5 folds, indicating the high capability of amended soil in the stabilization of the herbicides. The findings of this study can help to reduce imidazolinones' pollution and, in this way, prevent the threats of their residues to the environment.


Assuntos
Herbicidas , Oryza , Poluentes do Solo , Carvão Vegetal/química , Carvão Vegetal/farmacologia , Herbicidas/química , Oryza/química , Solo/química , Poluentes do Solo/análise , Controle de Plantas Daninhas
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