1.
Org Biomol Chem
; 11(47): 8162-5, 2013 Dec 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-24170291
RESUMO
Aromatic C-H silylation of neat arenes with 1-hydrosilatrane was found to be efficiently catalyzed by iridium catalysts composed of 1/2[Ir(OMe)(cod)]2 and 2,9-dimethyl-1,10-phenanthroline at 120 °C to afford the corresponding silylated products in high yields. The silylated products can be used for the Hiyama cross-coupling reaction.