Rhodium-catalysed additive-free carbonylation of benzamides with diethyl dicarbonate as a carbonyl source.

Phthalimides are prevalent in numerous pharmaceuticals, prompting various phthalimide syntheses through C-H activation. Nevertheless, the necessity for stoichiometric additives limits their practicality and versatility. Herein, we introduced diethyl dicarbonate as a carbonyl source for an additive-free carbonylation of benzamides. This transformation signifies an operationally simple and CO-free phthalimide synthesis.