Temperature-Controlled Molecular Bonding Hysteresis: Interphase Dynamics of a Nanoparticle-Modified Polymer Network.

This study demonstrates the existence of temperature-induced molecular bonding hysteresis at nanoparticle-polymer interfaces in a highly cross-linked epoxy-based polymer, modified with core-shell rubber nanoparticles. This thermally induced bond hysteresis manifests itself in a hysteresis-like change of the strength of the electrical bond polarization between epoxy molecules and surface molecules of the core-shell nanoparticles. This kind of dynamic bond behavior can be controllably switched from one bond state to the other by a sufficient temperature change. The related optical remanence is evidenced by a refractive index hysteresis independent of the temperature change using the new experimental technique of temperature-modulated optical refractometry (TMOR). From the investigation of quasi-static and dynamic thermal expansion separately, TMOR allows for the conclusion that the observed hysteresis is caused by the specific refractivity and not the dipole number density.

Mechanical and Thermal Properties of Basalt Fibre Reinforced Polymer Lamellas for Renovation of Concrete Structures.

The level of energy consumption in renovation activities of buildings has huge advantages over the demolition of old buildings and the construction of new structures. Such renovation activities are usually associated with the simultaneous strengthening of their elements, such as externally bonded carbon fibre reinforced polymer (CFRP) lamellas or sheets on vertical and horizontal surfaces as structural reinforcements. This means the process of refurbishing a building, as well as the raw materials themselves have a significant impact on CO2 emissions and energy consumption. This research paper demonstrates possibilities of replacing state of the art, highly energy-intensive CFRP lamellas with basalt fibre reinforced plastics as energy-efficient structural reinforcements for building constructions. The mechanical and thermal properties of basalt fibre reinforced polymer (BFRP) composites with variable matrix formulations are investigated. The article considers macro- and microstructures of innovative BFRP. The investigations focus on fibre-matrix interactions with different sizing formulations and their effect on the tensile strength, strain as well as modulus of elasticity.