RESUMO
The development of efficient bifunctional electrocatalysts for oxygen evolution reaction (OER) and urea oxidation reaction (UOR) is critical for hydrogen production and wastewater purification. In this work, we propose a facile synthetic method for Co and N dual-doped Ni2P directly grown on Ni foam (Co-Ni2P-N/NF) using hydrothermal and annealing process. Simultaneous Co and N dual-doping into Ni2P not only modifies the surface electronic structure, but also generates a multitude of active sites with high valence states, which are beneficial for improving electrocatalytic kinetics for both OER and UOR. As a result, the Co-Ni2P-N/NF catalyst exhibits a low overpotential of 329 mV to deliver a current density of 100 mA cm-2 for OER in alkaline solution, which is much lower than that of the state-of-the-art RuO2 electrocatalyst. In addition, the urea-assisted water oxidation process exhibits a significant reduction of approximately 163 mV in the required potential at 100 mA cm-2 compared to that of the OER, which highlights the remarkable potential of the prepared Co-Ni2P-N/NF electrocatalyst in facilitating the purification of wastewater and hydrogen production with significantly lower energy consumption.
