1.
J Org Chem
; 85(6): 4165-4171, 2020 Mar 20.
Artigo
em Inglês
| MEDLINE
| ID: mdl-32141746
RESUMO
The addition-type ozone oxidation of silylalkenes is a highly efficient reaction to provide synthetically versatile α-silylperoxy carbonyl compounds. To gain insight into the reaction mechanism, we performed a computational study, which revealed that the reaction proceeds via [1,2]-Brook rearrangement-type silyl migration of primary ozonide. In sharp contrast to the addition-type reactions, the ozone oxidation of α-alkoxysilylalkenes proceeds in a cleavage-type manner to afford excellent yields of silacarboxylic acid esters via the 1,3-cycloelimination of primary ozonide prior to 1,2-silyl migration.
2.
Angew Chem Int Ed Engl
; 51(51): 12745-8, 2012 Dec 14.
Artigo
em Inglês
| MEDLINE
| ID: mdl-23136024
3.
Angew Chem Int Ed Engl
; 49(4): 728-31, 2010.
Artigo
em Inglês
| MEDLINE
| ID: mdl-20029860