5†µm CW Ce3+-doped chalcogenide glass fiber laser with 17% slope efficiency.

Efficient room temperature mid-infrared laser action in a Ce3+-doped chalcogenide fiber was demonstrated. The fiber had a doped selenide glass core in an undoped sulfide glass cladding. The pump source was a CW Fe2+:ZnSe laser emitting at 4.14 µm. The optimized fiber length allowed obtaining up to 7 mW of 5.06 µm output with 17% slope efficiency at room temperature.

Passively Q-switched 5-µm Ce3+-doped selenide glass laser using Fe:CdTe and Fe:CdSe as saturable absorbers.

The first, to the best of our knowledge, mid-infrared Q-switched Ce3+-doped glass laser is demonstrated. As saturable absorbers, Fe2+:CdSe and Fe2+:CdTe are used for the first time. When Q-switched by Fe:CdSe, the laser operates in a multi-pulse regime with an individual pulse width of 110 ns, centered at λ = 5.20 µm. With Fe:CdTe as saturable absorber, 1-3 giant pulses of 30 ns pulse width are generated at λ = 5.13 µm.

Mid-infrared laser performance of Ce3+-doped selenide glass.

An extensive study of a novel room-temperature mid-infrared Ce3+-doped Ge20Sb10Ga5Se65 glass laser is reported. An influence of output-coupler transmission on laser efficiency and emission spectra is investigated. Pumped by a pulsed Fe:ZnSe laser at 4.1 µm, a maximum output energy of 35 mJ is demonstrated at 5.2 µm, with a laser threshold of about 60 mJ and a slope efficiency of 21%. The tuning range of a mid-infrared Ce:glass laser is reported for the first time: with an intracavity prism, the laser is continuously tunable in the spectral range of 4.5-5.6 µm. The internal losses are determined to be below 9% per roundtrip.

Resonantly pumped Ce3+ mid-infrared lasing in selenide glass.

In high purity Ce3+-doped selenide glass pumped by a 4.08 µm Fe:ZnSe laser, 5.1-5.5 µm laser oscillations were observed. This is the first evidence of laser action corresponding to the 2F7/2→2F5/2 transition of Ce3+ ions.

Raman band intensities of tellurite glasses.

Raman spectra of TeO2-based glasses doped with WO3, ZnO, GeO2, TiO2, MoO3, and Sb2O3 are measured. The intensity of bands in the Raman spectra of MoO3-TeO2 and MoO3-WO3-TeO2 glasses is shown to be 80-95 times higher than that for silica glass. It is shown that these glasses can be considered as one of the most promising materials for Raman fiber amplifiers.

UV-irradiation-induced structural transformation in phosphosilicate glass fiber.

The Raman spectra of phosphosilicate core (P(2)O(5)-SiO(2)) fibers were investigated. Significant changes in the spectra were observed after UV irradiation of the fibers. An interpretation of the photostructural changes confirmed by computer simulation of phosphorus-related centers is proposed.

UV-irradiation-induced structural transformation of germanoscilicate glass fiber.

Raman spectra of germanosilicate core fibers before and after UV irradiation were investigated. Significant changes of the Raman spectra after irradiation indicate transformation of the glass structure. A possible interpretation of the observed changes is proposed.